排序方式: 共有53条查询结果,搜索用时 15 毫秒
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蒽醌染料的电解处理研究 总被引:18,自引:0,他引:18
用复极性固定床电解槽(BPBC)对蒽醌染料进行电解处理研究.结果表明BPBC可以破坏染料分子结构中的发色共轭体系,色度和CODcr的去出率分别达到98%和85%以上,对总氮的去除率也达到60%以上 相似文献
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就复级性固定床电解槽(BPBC)对水溶性染料的电解脱色进行了实验研究,结果表明,BPBC通过电氧化还原作用可以破坏偶氮,蒽醌,三芳甲烷,杂蒽类,酞菁和金属络合类染料分子结构中的发色共轭体系使染料降解脱色。BPBC电解可使酞菁染料和金属络合物染料分子结构中的配价链离解并去除螯合态重金属(铜或铬)还具有脱氮作用,同时染料的分子结构及其空间构型对其电解行为的有影响 相似文献
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应用电除尘与静电凝聚技术相结合,净化自焙阳极铝电解槽生产过程中所产生的有害气体和烟尘,有关部门测试认定,其沥青烟,氟化物和粉尘的排放量均低于国家排放标准。 相似文献
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铝电解槽大修渣的无害化处理 总被引:1,自引:0,他引:1
从多个方面分析了电解槽大修渣的危害性,对大修渣进行了分类,总结了大修渣中阴极碳块的利用途径,在作最终处理时,将石灰渣与大修渣混合堆存,可有效防止废渣中可溶性氟随雨水向下渗透,减轻对土地及地下水的污染,复土后的渣场可还林(耕),实现大修渣无害化堆存。 相似文献
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Dawei LIANG Yanyan LIU Sikan PENG Fei LAN Shanfu LU Yan XIANG 《Frontiers of Environmental Science & Engineering》2014,8(4):624-630
A biocathode with microbial catalyst in place of a noble metal was successfully developed for hydrogen evolution in a microbial electrolysis cell (MEC). The strategy for fast biocathode cultivation was demonstrated. An exoelectrogenic reaction was initially extended with an H2-full atmosphere to enrich Ha-utilizing bacteria in a MEC bioanode. This bioanode was then inversely polarized with an applied voltage in a half-cell to enrich the hydrogen-evolving biocathode. The electrocatalytic hydrogen evolution reaction (HER) kinetics of the biocathode MEC could be enhanced by increasing the bicarbonate buffer concentration from 0.05 mol·L-1 to 0.5 mol· L-1 and/or by decreasing the cathode potential from -0.9 V to - 1.3 V vs. a saturated calomel electrode (SCE). Within the tested potential region in this study, the HER rate of the biocathode MEC was primarily influenced by the microbial catalytic capability. In addition, increasing bicarbonate concentration enhances the electric migration rate of proton carriers. As a consequence, more mass H+ can be released to accelerate the biocathode-catalyzed HER rate. A hydrogen production rate of 8.44 m3. m 3. d1 with a current density of 951.6 A. m-3 was obtained using the biocathode MEC under a cathode potential of - 1.3 V vs. SCE and 0.4 mol· L-1 bicarbonate. This study provided information on the optimization of hydrogen production in biocathode MEC and expanded the practical applications thereof. 相似文献