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Methyl ten-butyl ether (MTBE), a gasoline additive, possesses serious problems to the environmental health. In the present study, a bacterial culture named A-3 which could effectively degrade MTBE was isolated from the MTBE contaminated soil. The isolate was identified as Chryseobacterium sp., a new species capable of degrading MTBE. In order to enhance its degradation ability, selected environment factors were investigated. The results showed that the optimal temperature was in the range of 25-30℃, the pH was 7.0, the inoculum size was 2 × 10^8 CFU/ml and the optimal concentration of MTBE was from 50 to 100 mg/L. The maximum MTBE utilization rate (Vmax) was 102 nmol MTBE/(mg cell protein.h). Furthermore, it was found that the isolate could also degrade tert-butyl alcohol (TBA). The degradation rates of TBA were much faster than those of MTBE. The additional TBA would lead to the decrease of the initial MTBE degradation rate and the inhibitory effect of TBA increased with the increase of TBA concentration. Similar protein profiles at least seven peptides were demonstrated after SDS-PAGE analysis of crude extracts obtained from the cells growing in MTBE and TBA culture. 相似文献
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代森锰锌及其代谢产物在荔枝与土壤中的残留动态 总被引:1,自引:0,他引:1
采用田间试验方法,研究了代森锰锌及其代谢物乙撑硫脲(ETU)在荔枝及土壤中的残留动态。结果表明,质量分数为80%的代森锰锌可湿粉剂在荔枝树上喷施后,主要残留在荔枝果皮中,且消解速度较快,其中母体消解半衰期为4. 02~5. 14d; ETU消解半衰期为2. 52~3. 24d;代森锰锌及ETU在土壤中消解较快,半衰期分别为5. 63~9. 88d和4. 95~14. 2d。施药1 600mg·L-1,使用4次,末次施药距收获间隔10、20和30d,荔枝果肉中代森锰锌残留量均小于1mg·kg-1,代谢产物ETU均小于0. 02mg·kg-1。该药为易消解农药(t1 /2 <30d),按推荐剂量使用是安全的。 相似文献
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以明胶和硫脲为原料,戊二醛为交联剂,采用反相悬浮聚合得到了明胶固化硫脲微粒(TIGM),研究了其对水溶液中Ag+的静态吸附分离及热力学性质。结果表明,TIGM对Ag+吸附平衡数据符合Langmuir和Freundlich吸附等温方程,且Ag+在微粒吸附过程中表现为优惠吸附。Freundlich吸附等温线和热力学研究表明,在283~323K条件下,Ag+吸附量为0.07~0.10mmol/g时,反应的吸附焓变为28.42~31.73kJ/mol,表明该吸附反应是吸热过程,升高温度有利于反应的进行;吸附自由能变为负值,表明常温下该吸附是自发的过程;吸附熵变为111.14~129.70J/mol·K,表明该吸附是个熵增的过程。 相似文献
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树脂吸附法处理硫化促进剂CA生产废水的研究 总被引:2,自引:0,他引:2
采用特种吸附树脂处理促进剂CA生产废水,系统地研究了废水的pH值、吸附温度及吸附流量等因素对树脂吸附性能的影响,以及以稀硫酸为脱附剂,其配比、流量、温度等对树脂脱附性能的影响。实验结果表明,特种吸附树脂对该废水具有良好的吸附,脱附效果,废水经吸附处理后,CODCr浓度由20000mg/L左右降至300mg/L以下,CODCr去除率达98%以上。该工艺简单,运行稳定,操作简便,可望实现工业化。 相似文献