气升式内循环蜂窝陶瓷反应器降解2,4-二氯酚的研究

从以2,4-二氯酚(2,4-DCP)长期驯化的好氧活性污泥中分离出一株以2,4-DCP为唯一碳源的菌种,将这种菌固定在气升式内循环蜂窝陶瓷反应器内,研究了此反应器在半连续流运行时,对2,4-DCP单基质及其与苯酚共基质时对污染物的降解情况及降解动力学.结果表明,2,4-DCP单基质时,反应器对氯酚的去除效果随着实验次数的增加而加快;2,4-DCP与苯酚共基质时,苯酚的降解速率随着半连续流实验次数的增加而加快,而氯酚的降解速率则表现出下降的趋势.此外,还研究了此反应器在连续流运行时对2,4-DCP的降解,水     

机动车尾气催化净化装置技术进展

对汽车尾气催化净化器载体的研究进展进行了综述,多孔陶瓷由于其结构独特和性能优异得到了广泛的使用。对新研发的有关多孔陶瓷的载体也进行了重点介绍,且还指出了其存在的问题和对其未来怎样发展提出了建议。     

含表面应力集中超高温陶瓷材料热冲击可靠性的研究

目的研究含表面应力集中的超高温陶瓷材料在热冲击环境下的可靠性。方法针对超高温陶瓷材料,研究了其威布尔分布规律和含不同切口半径的材料可靠性,并建立了其在热冲击载荷作用下的可靠性评价方法。结果对于切口不完全敏感的材料,切口件的可靠性并不是随着切口半径的减小而单调增大,对于研究的三种切口半径试样(r=0.1、0.25、0.5 mm),r=0.1 mm的试样存活率最小,r=0.25 mm的试样存活率最大。淬火初期阶段,表面含切口的材料存活率在0.04 s内急剧降低至0,0.04～0.1 s时存活率维持在0,0.1 s后存活率迅速上升,约0.28s后存活率增大为1。结论建立的评价方法可以作为超高温陶瓷材料在热冲击环境下应用可靠性的有效评估手段,对其进一步被广泛应用具有重要意义。     

舵面结构热模态试验方法研究

目的 探究高温对舵面结构模态试验结果的影响.方法 以导弹舵面为研究对象,开展高温环境下结构模态试验方法研究.基于石英灯热辐射高温加热系统和模态测试系统搭建热模态试验测试平台,采用带水冷装置的耐高温加长激振杆实现激励的施加,设计耐高温陶瓷引伸杆进行振动信号的测试,通过有限元仿真分析与试验数据对比,验证所提热模态试验方案的可行性.结果 当激振杆的正弦扫频试验在20～1000 Hz范围内,其传递函数值接近于1,说明激振杆传递性能良好.陶瓷引伸杆对试验件前四阶模态频率及振型影响较小,验证了陶瓷引伸杆设计的有效性.试验数据表明,试验件材料的刚度随着环境温度的升高逐渐降低,导致各阶模态的频率呈逐渐降低的趋势.结论 高温会使舵面结构的模态参数降低,该研究为后续型号产品的热模态试验提供了的试验手段和技术支持.     

陶瓷电镀废水的三级处理工艺

以色度、浊度、悬浮物浓度、电导率及金属离子浓度为检测指标,研究进水pH、混凝剂种类与投量、沉降时间及重金属捕捉剂对陶瓷电镀废水的处理效果,探讨陶瓷电镀废水处理的适宜操作条件及工艺组合。实验表明,陶瓷电镀废水的组合处理工艺:调整废水pH为一级处理,投加PAC的混凝沉降法为二级处理,投加重金属捕捉剂为三级处理;先调节废水pH至9,投加50 mg/L的PAC,再投加20 mg/L重金属捕捉剂,此时废水的色度降至10倍,浊度降至16 NTU,悬浮物浓度降至210 mg/L去除率达到95.1%,各金属离子浓度也明显降低,处理出水的悬浮物达到《污水综合排放标准》(GB8978-1996)的三级标准,其他各指标均达到《电镀污染物排放标准》(GB21900-2008)。     

Using a biological aerated filter to treat mixed water-borne volatile organic compounds and assessing its emissions

A biological aerated filter (BAF) was evaluated as a fixed-biofilm process to remove water-borne volatile organic compounds (VOCs) from a multiple layer ceramic capacitor (MLCC) manufacturing plant in southern Taiwan. The components of VOC were identified to be toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, bromodichloromethane and isopropanol (IPA). The full-scale BAF was constructed of two separate reactors in series, respectively, using 10- and 15-cm diameter polypropylene balls as the packing materials and a successful preliminary bench-scale experiment was performed to feasibility. Experimental results show that the BAF removed over 90% chemical oxygen demand (COD) from the influent with (1188 605) mg/L of COD. A total organic loading of 2.76 kg biochemical oxygen demand (BOD)/(m3 packing d) was determined for the packed bed, in which the flow pattern approached that of a mixed flow. A limited VOC concentration of (0.97 0.29) ppmv (as methane) was emitted from the BAF system. Moreover, the emission rate of VOC was calculated using the proposed formula, based on an air-water mass equilibrium relationship, and compared to the simulated results obtained using the Water 9 model. Both estimation approaches of calculation and model simulation revealed that 0.1% IPA (0.0031–0.0037 kg/d) were aerated into a gaseous phase, and 30% to 40% (0.006–0.008 kg/d) of the toluene were aerated.