沉淀法回收聚苯乙烯泡沫塑料的工艺研究

研究沉淀法回收聚苯乙烯泡沫塑料(EPS)的工艺,利用石油裂解副产物为溶剂回收废旧聚苯乙烯泡沫塑料,以废治废,回收利用。溶剂低毒,对聚苯乙烯泡沫塑料溶解速度快,溶解量大,价廉易得。采用转式间歇投料并附加溶剂挥发分回收装置的工艺,溶剂回收率高,无二次污染,可循环使用。聚苯乙烯塑料(PS)回收率可达99%。     

PM2.5 chemical source profiles for vehicle exhaust, vegetative burning, geological material, and coal burning in Northwestern Colorado during 1995

PM_2.5 (particles with aerodynamic diameters less than 2.5 μm) chemical source profiles applicable to speciated emissions inventories and receptor model source apportionment are reported for geological material, motor vehicle exhaust, residential coal (RCC) and wood combustion (RWC), forest fires, geothermal hot springs; and coal-fired power generation units from northwestern Colorado during 1995. Fuels and combustion conditions are similar to those of other communities of the inland western US. Coal-fired power station profiles differed substantially between different units using similar coals, with the major difference being lack of selenium in emissions from the only unit that was equipped with a dry limestone sulfur dioxide (SO₂) scrubber. SO₂ abundances relative to fine particle mass emissions in power plant emissions were seven to nine times higher than hydrogen sulfide (H₂S) abundances from geothermal springs, and one to two orders of magnitude higher than SO₂ abundances in RCC emissions, implying that the SO₂ abundance is an important marker for primary particle contributions of non-aged coal-fired power station contributions. The sum of organic and elemental carbon ranged from 1% to 10% of fine particle mass in coal-fired power plant emissions, from 5% to 10% in geological material, >50% in forest fire emissions, >60% in RWC emissions, and >95% in RCC and vehicle exhaust emissions. Water-soluble potassium (K⁺) was most abundant in vegetative burning profiles. K⁺/K ratios ranged from 0.1 in geological material profiles to 0.9 in vegetative burning emissions, confirming previous observations that soluble potassium is a good marker for vegetative burning.     

A comparison of chemical MSW compositional data between China and Denmark

Chemical waste compositions are important for municipal solid waste management, as they determine the pollution potentials from different waste strategies. A representative dataset for chemical characteristics of individual waste fractions is frequently required to assess chemical waste composition, but it is usually reported in developed countries and not in developing countries. In this study, a dataset for Chinese waste was established through careful data screening and assessment, named as CN dataset. Meanwhile, a dataset for Danish waste (DK dataset) was also summarized based on previous studies. In order to quantitatively evaluate the reliabilities of CN and DK datasets, the chemical waste compositions in four Chinese cities were estimated by utilizing both of them, respectively. It is indicated that the usage of CN datasets led to significantly lower discrepancies from the actual values based on laboratory analysis in most cases. Within the datasets, the moisture contents of food waste, paper, textiles, and plastics, the carbon content of food waste, as well as the oxygen content of plastics would induce significant divergences, which should be paid special attention when gathering the information. In addition, the fractional waste compositions in China showed similar features with other developing countries but differ significantly with developed countries. Thus the above-mentioned conclusions could also be true in other developing countries.     

我国纸包装废物产生特性和回收状况研究

纸包装被广泛应用于各个领域,消费量巨大,废物的产生量也巨大,但我国对其产生特性和回收体系研究较少。首先分析纸包装的生产量、消费量、废物产生量和回收量,指出我国纸包装废物回收率,远高于废纸的统计回收率;其次,综合分析纸包装废物的回收特性和回收体系状况,指出纸包装废物主要流向和关键环节;然后,对纸包装消费趋势进行预测,最后,提出纸包装废物回收存在的问题和对策措施。     

融入循环经济体系的滨海湿地资源开发思路探讨

滨海湿地是湿地的重要类型之一,其资源、生态、旅游、文化、教育、科研等多方面的潜在功能对社会、经济发展均有极其重要的作用。而中国滨海湿地遭受破坏的情况较为严重。当前,如何基于科学发展观,将滨海湿地纳入循环经济系统之中,更加合理地进行开发、保护,已成为关系到中国经济可持续发展的重要问题之一。文章基于对山东滨州地区典型滨海湿地资源开发实践的研究,结合中国其他地区湿地开发保护的经验教训,以循环经济理论为指导进而探讨适合中国国情的滨海湿地资源开发思路、模式,并在此基础上提出一些建议,以期能够对中国“十一五”时期的湿地开发、保护工作以及部分地区区域经济发展起到一定借鉴、推进作用。     

香料生产废水的生化处理研究

某合成洋茉莉醛香料厂的生产废水中含有香料、香料副产品、降解物以及原辅材料,具有CODcr浓度高、水质波动大以及水中污染物成分复杂等特点,属于典型的高浓度难降解有机废水,而该厂现有的废水处理工艺不仅流程长、费用高且出水难以达到GB8978—1996一级排放标准。本文采用活性污泥法及MBR工艺研究了洋茉莉醛香料废水的处理效果及其影响因素,并结合GC—MS对降解产物进行了分析。试验结果表明：采用本文方法对洋茉莉醛香料废水有较好的降解作用,可经较少的步骤处理实现达标排放。     

废纸造纸废水处理工程的设计与运行

文章针对废纸造纸生产中废水产生量大,SS、COD浓度较高的问题,将废纸造纸废水处理工程实践中的污水作为对象,研究一套废纸造纸废水回收利用的污水处理方法,减少再生纸造纸工业对环境的污染。实验结果和工程实践证明:利用混凝沉淀—活性污泥相结合工艺处理废纸造纸废水,达到一部分经物理处理后回收利用,一部分经生化处理后达标排放。采用该工艺处理效果好,SS去除率达99.7%、COD去除率达98.4%,且运行稳定,成本和一次性投资均较低,其排放废水水质满足《造纸工业水污染物排放标准》(GB3544-2001)中的排放要求。     

化学法除磷的试验研究

探讨了含磷废水在添加不同药剂、不同试验条件下的的处理效率;研究表明:石灰法除磷在〔Ca2+/TP〕(摩尔比)为2:1时,pH值控制在10.0左右,TP的去除率达到96%以上;三氯化铁除磷时控制〔Fe3+/TP〕为2:1,pH值为7.0,TP的去除率能达到96%;硫酸亚铁与活性污泥协同除磷效果优于三氯化铁。     

基于物料衡算法的复杂化工过程产排污量核算软件的开发及应用

物料衡算法是污染源普查技术规定的污染物排放量核算的一种重要方法,但对于复杂的化工过程,物料衡算法的难度和计算工作量均很大,难以为基层环境监察人员掌握和运用,同时运用物料衡算进行污染物排放量核算的可靠性,也很难保证。结合排污量核定实践,综合进行物料衡算的技巧和一般方法,科学地模化物质转化转移过程,以此为基础,应用Visual Basic高级计算机语言编制了针对复杂化工过程的物料衡算计算软件,并以沈阳某制药有限公司的脑复康生产过程为原型,利用实测资料对计算模型进行了验证,应用该软件计算某制药厂VC生产线等4条生产线的产排污量核算。该软件应用简便,可以方便快捷地进行复杂化工过程的物料衡算,并可以分析生产过程中的主要产污环节,为提高清洁生产水平提供科学依据。     

天津滨海新区再生资源产业发展对策

天津滨海新区再生资源产业以废弃物流通、加工利用为主营内容,具有补链特征与技术先进性,主要为滨海新区提供生产性服务。为了适应滨海新区发展所提出的要求,再生资源产业应不断提高资源供给能力,扩展服务对象,提高资源流通和集散能力,并挖掘向再制造产业延伸的潜力。建议尽快制定滨海新区再生资源产业发展规划和实施指导方案,实行优先采购制度,并鼓励再生资源企业参与社会回收体系的建立,完善再生资源产业运输和物流系统,不断提高产业的升级能力。