辽西易旱区集雨灌溉山地大棚技术

通过雨水径流的集蓄储存可解决水源问题，发展山地蔬菜大棚。结果表明：一个70m^3的水窖集水在配以渗灌技术的条件下可以满足333m^2的大棚生育期用水需求，与传统畦灌相比节水53.4%，且效益可观，达20万元／hm^2，使干旱贫瘠的山地一跃成为发展高效农业的园田，为辽西易旱区坡地高效利用开辟了一条新途径。     

Diffusion mechanism of chloride ions in sodium montmorillonite

For safety assessment of geological disposal of HLW, it is necessary to understand the diffusion mechanism of radionuclides in compacted bentonite. In this study, the diffusion behavior of chloride ions in compacted montmorillonite was studied from the viewpoints of the activation energy for apparent diffusion and the basal spacing of the compacted montmorillonite. A unique change in the activation energy as a function of the dry density of the montmorillonite was found. The activation energy decreased from 17.4 to 13.5 kJ mol-1 as the dry density increased from 0.7 to 1.0 Mg m-3 and increased to 25.1 kJ mol-1 at dry densities above 1.0 Mg m-3. The basal spacing of 1.88 nm, corresponding to the three-water layer hydrate state, was not observed by X-ray diffraction (XRD) until the dry density increased to 1.0 Mg m-3, where the minimum activation energy was obtained. On the other hand, a basal spacing of 1.56 nm, corresponding to the two-water layer hydrate state, was observed at the dry densities of 1.4 Mg m-3 and above, where the activation energies were more than 22 kJ mol-1. These experimental results suggest that there are at least two additional diffusion processes that can raise or reduce the activation energy and are affected by water in the region adjacent to the montmorillonite surfaces. If the "Grahame model" can be introduced to describe the electrical double layer, surface diffusion will be considered the possible predominant diffusion process, even for anions like chloride ions.     

Analysis of the chosen thermal and flammability parameters of dried sewage dust

The hazardous sludge disposal process in the form of landfills requires the determination inter alia of the flammable and explosion properties of dried sewage sludge dust, which has the ability to ignite and spontaneously combust when stored in silos. At a constant furnace surface temperature, the minimum ignition temperature of the sludge dust layer with a layer thickness of 5 mm is 270 °C, and for a layer thickness of 12.5 mm it is 250 °C. Two selected fire extinguishing powders for Class A, B, C and D fires were used in the study to determine the possibility of reducing the susceptibility of dried wastewater to ignition from heated surface, self-ignition and explosion parameters. The most effective extinguishing powder was ABC Favorit, which increased the value of the minimum ignition temperature of the layer (5 mm thick) to 360 °C and the spontaneous ignition temperature of the sludge with this powder increased by 22 °C at 169.6 cm³ in comparison to the sludge without extinguishing powder, respectively. The lowest self-ignition temperature of 136 °C was recorded for the largest tested volume (169.6 cm³) for dried sewage dust without any fire extinguishing powders. The biggest values of p_max and (dp/dt)_max dried sewage dust were recorded 4.8 bar and 113 bar/s respectively. By analysing the obtained test results, it can be assumed that dried sewage dust is a combustible material with properties similar to biomass.     

Evidence for changing the critical level for ammonia

The current critical level for ammonia (CLE_NH3) in Europe is set at 8 μg NH₃ m⁻³ as an annual average concentration. Recent evidence has shown specific effects of ammonia (NH₃) on plant community composition (a true ecological effect) at much smaller concentrations. The methods used in setting a CLE_NH3 are reviewed, and the available evidence collated, in proposing a new CLE_NH3 for different types of vegetation. For lichens and bryophytes, we propose a new CLE_NH3 of 1 μg NH₃ m⁻³ as a long-term (several year) average concentration; for higher plants, there is less evidence, but we propose a CLE_NH3 of 3 ± 1 μg NH₃ m⁻³ for herbaceous species. There is insufficient evidence to provide a separate CLE_NH3 for forest trees, but the value of 3 ± 1 μg NH₃ m⁻³ is likely to exceed the empirical critical load for N deposition for most forest ecosystems.     

Butyltin Compounds in Sediments of the Bahía Blanca Estuary, Argentina

Systematic measurements of both Tributyltin (TBT) and Dibutyltin (DBT) in sediments along different locations in the inner zone of Bahía Blanca estuary were done. Two samples were taken near the main dry dock facility, at Puerto Belgrano naval base, in Argentina. TBT concentrations from non-detected to 170.3 ng Sn g⁻¹ were measured in the inner region of the estuary, and higher one of 3,288 ng Sn g⁻¹ near the dry dock at Puerto Belgrano. DBT values ranging between non-detected and 75.2 ng Sn g⁻¹ were obtained along the principal channel, but extreme concentration of 1,645 ng Sn g⁻¹ was measured at Puerto Belgrano. These values show that this estuary is affected by organotin pollution, mainly in areas of heavy shipyard activities.     

Atmospheric mercury pollution at an urban site in central Taiwan: mercury emission sources at ground level

Total gaseous mercury (Hg) (TGM), gaseous oxidized Hg (GOM), and particulate-bound Hg (PBM) concentrations and dry depositions were measured at an urban site in central Taiwan. The concentrations were 6.14 ± 3.91 ng m⁻³, 332 ± 153, and 71.1 ± 46.1 pg m⁻³, respectively. These results demonstrate high Hg pollution at the ground level in Taiwan. A back trajectory plot shows the sources of the high TGM concentration were in the low atmosphere (<500 m) and approximately 50% of the air masses coming from upper troposphere (>500 m) were associated with low TGM concentrations. This finding implies that Hg is trapped in the low atmosphere and comes from local Hg emission sources. The conditional probability function (CPF) reveals that the plumes of high TGM concentrations come from the south and northwest of the site. The plume from the south comes from two municipal solid waste incinerators (MSWIs). However, no significant Hg point source is located to the northwest of the site; therefore, the plumes from the northwest are hypothesized to be related to the combustion of agricultural waste. Dry deposition fluxes of Hg measured at this site considerably exceeded those measured in North America. Overall, this area is regarded as a highly Hg contaminated area because of local Hg emission sources.     

丽水市大气环境中的城市干、湿岛效应初探

利用丽水城区中心及其近郊2个站点的逐时水汽压资料,定义了干(湿)岛强度指数及干(湿)岛强度等级,并发现了丽水小城区干(湿)岛变化强度、频次及时空分布规律,研究发现城区中心的干岛现象与热岛现象之间存在着正相关.湿岛的形成与露、雾、结冰、霜、雨等天气现象有关.     

CO2 transportation for carbon capture and storage: Sublimation of carbon dioxide from a dry ice bank

Climate change is being caused by greenhouse gases such as carbon dioxide (CO₂). Carbon capture and storage (CCS) is of interest to the scientific community as one way of achieving significant global reductions of atmospheric CO₂ emissions in the medium term. CO₂ would be captured from large stationary sources such as power plants and transported via pipelines under high pressure conditions to underground storage. If a downward leakage from a surface transportation system module occurs, the CO₂ would undergo a large temperature reduction and form a bank of “dry ice” on the ground surface; the sublimation of the gas from this bank represents an area source term for subsequent atmospheric dispersion, with an emission rate dependent on the energy balance at the bank surface. Gaseous CO₂ is denser than air and tends to remain close to the surface; it is an asphyxiant, a cerebral vasodilator and at high concentrations causes rapid circulatory insufficiency leading to coma and death. Hence a subliming bank of dry ice represents safety hazard. A model is presented for evaluating the energy balance and sublimation rate at the surface of a solid frozen CO₂ bank under different environmental conditions. The results suggest that subliming gas behaves as a proper dense gas (i.e. it remains close to the ground surface) only for low ambient wind speeds.     

Water resources issues of small island developing states

The water resources of most small island developing states (SIDS) are often very limited and require special consideration to ensure that they are developed and managed in a sustainable manner. Many small islands, typically located in the humid tropics, have no surface water resources and rely on limited groundwater resources in the form of thin freshwater lenses. The exposed location of small islands makes them particularly vulnerable to natural disasters such as cyclones, floods and droughts. Pollution from population centres and from agricultural and other activities is an increasing problem. This article provides an overview of the water resources of small islands, and the main problems and issues related to water resources. Some suggested solutions, based on practical experiences, are offered for water resource assessment and monitoring programmes, and water resource development. Water resource policy, planning and management issues are also addressed, and suggested approaches for resolving some of the major water resource problems presented.     

Private sector participation in urban water and sanitation: Realising social and environmental objectives in developing countries

There has been a large increase in private sector participation (PSP) in the urban water supply and sanitation (WSS) sector in recent years. However, even with increased PSP, public authorities will still have to: ensure that the service providers do not use their market power to exploit customers; internalise public health and environmental externalities; provide mechanisms whereby water consumption is sustainable and allocated efficiently between alternative uses; and stand as a guarantor of a level of service provision that is consistent with a basic standard of living. While there is considerable literature addressing the first of these four issues, the latter three are rather less adequately addressed. Through a review of a number of case studies (Abidjan, Buenos Aires/Cordoba, Mexico City and Manila), this paper provides an overview of the issues involved and some of the mechanisms available to the authorities responsible for the regulation of the sector.