电子环保循环经济方案分析

根据我国电子废物回收处理的现状,分析存在的问题,并提出相关对策。通过对北京海淀区“电子环保.循环经济”方案,从管理和技术的角度突出了政府推动和市场拉动相结合的方法在建立完善电子废物回收处理链及逐步构建完整IT产业链的重要作用,其思路和做法具有推广价值。     

水循环周期对生态床内氮形态转化过程的影响

构建复合生态床修复北方景观水体,通过控制出水循环周期,研究不同循环速率下水体氮在系统内的转换及不同转换过程之间的关系,深入分析复合基质生态床修复景观水的过程及作用机理.结果表明,当循环周期为1 h和1.5 h时,溶解氧经首次循环由7提高至11左右,并始终保持较高水平;C/N由进水时4～6提高至出水时6～10,C/N的升高说明系统中N的相对去除率高于C,循环促进了氮及有机物的去除.出水循环提高了NH⁺₄-Ｎ、NO^-₂-Ｎ及TN的去除率, 且循环速率的提高使得硝化作用进行得更加迅速和彻底,补充了氮从系统中去除的好氧反硝化途径.当循环周期为1.5 h和1 h时,NH⁺₄-Ｎ与NO^-₂-Ｎ去除过程间的相关系数值分别为0.885 3和0.968 5;NO^-₂-Ｎ与TN去除过程间的相关系数随循环速率加快而增加,最高为0.942 4.当循环速率加快,NH⁺₄-Ｎ的氧化与NO^-₂-Ｎ的氧化2个过程间的传递更加迅速, 缩短了氮在系统中的转化途径,且循环速率越快,整个转化越迅速.     

WASTE MANAGEMENT AND SUSTAINABLE DEVELOPMENT IN SOUTH AFRICA

Waste management is emerging as a key sector for sustainable development in South Africa with opportunities for enhancing investments in carbon credits that target reduction of methane from landfills and moveable assets in relation to environmentally sound equipment required for effective waste management. In the past, the waste management sector was dominated by private sector with selective operations in what makes business sense through recycling of saleable products. Materials mostly recycled included paper and hard board, plastics, glass, tinplate and aluminum. The rest of the waste materials estimated at 10.2 million tons of both general and hazardous end up in landfills. This trend is now getting reversed as development agencies such as Deutsche Gesellschaft für Technische Zusammenarbeit Gmbh (GTZ), Danish International Development Agency (DANIDA), Danish Co-operation for Environment and Development (DANCED) and Development Bank of Southern Africa (DBSA) are identifying opportunities in the sector for sustainable development purposes. Two key areas for investments include capturing methane emissions from landfills for trading in carbon markets and financing both physical and moveable assets to enhance sustainable development. However, the challenges for cost-effectiveness, efficiency and sustainability in the sector prevail in relation to lack of sound knowledge to design and implement integrated programmes that incorporate environment, development and sustainability. Also, inadequate capacity at municipal levels to administer waste management programmes and inability to collect rates and taxes for effective management of landfills constraint effectiveness and efficiency of the sector. Overall, financial resources are imperative to waste management and sustainable development as the sector requires capital investments for necessary infrastructure.     

发展资源再生产业是中国资源战略的一场革命

中国已经成为资源消耗大国，实施再生型资源战略，发展循环经济是我国的必然选择。资源再生产业与“循环经济”取代“线性经济”、经济全球化形成“国际大分工”和“国际大循环”的发展趋势同步，是解决资源和环境问题的根本出路。资源再生产业是一座“富矿”，没有“资源再生”就没有中国的“环境保护”。中国资源再生产业的发展为什么步履艰难？它和进口渠道不畅。国民对资源短缺认识不足、传统的“线性思维方式”的影响，来自国内外“利益集团”的阻力，以及政策不刭位等因素密切相关。因此，提出中国发展资源再生产业的对策和建议：①在经济相对滞后、交通便利的地区建立“资源再生加工区”；②建立畅通的全球物质回收“绿色通道”；③建立“国际再生资源交易市场”；④成立“国际资源再生促进会”；⑤改变“线性经济”背景下的传统观念。     

水处理技术发展对电力工业水循环利用的经济性影响

讨论了一些为提高生产力和降低成本而发展起来的废水零排放或水回收循环利用前沿技术,并将这些技术的经济性与原有的水循环利用系统进行比较.     

Analysis of Products Generated from the Thermal and Catalytic Degradation of Pure and Waste Polyolefins using Py-GC/MS

The possibility of transforming waste plastics into valuable hydrocarbons via catalytic cracking and reforming is attracting increasing interest. Pyrolysis coupled with Gas Chromatographic separation and Mass Spectrometry detection (Py-GC/MS) has been used in this work to study the product selectivity of various catalysts in the conversion of pure and residual polyethylene samples into hydrocarbon products. Five acid solids of comparable aluminium contents but different textural and acid properties were tested as catalysts, including three zeolites (standard ZSM-5, nanocrystalline n-ZSM-5 and Beta) and two mesostructured solids (Al-MCM-41 and Al-SBA-15). Thermal cracking of the pure and residual polymers generated a similar range of products to each other, with a high proportion of linear paraffins and olefins of varying lengths. The presence of zeolitic materials resulted in complete elimination of heavy linear products, an increase in the light hydrocarbon fraction and a marked selectivity towards the formation of single-ring aromatic species, particularly benzene, toluene and xylene. Aromatic formation was particularly notable with the small crystal size n-ZSM-5 (aromatic selectivity up to 53.9%) and less marked in the case of standard ZSM-5 (up to 36.4%) and Beta zeolite (up to 35.0%). Mesostructured catalysts like Al-MCM-41 and Al-SBA-15 favoured the production of light C₂–C₅ hydrocarbons (up to 57.9%) while the formation of aromatic products was significantly lower than with zeolitic materials. The paper examines the extent and the causes for this product selectivity and discusses its connection with the acid and textural properties of each catalyst. It was also observed that, under the experimental conditions employed, the products generated were not significantly affected by the nature and origin of the polymers employed.     

Effect of Decalin Solvent on the Thermal Degradation of HDPE

The thermal cracking of HDPE in presence of different amounts of decalin was studied and compared with the reaction carried out in the absence of solvent. The decalin favours the mass and heat transfer during the reaction. In addition, it modifies the thermal degradation mechanism, which facilitates the formation of specific products. The use of decalin substantially increases the C₅–C₃₂ yield in comparison with the solventless reaction. In all cases, linear hydrocarbons such as n-paraffins, α-olefins and α,ω-dienes were detected. Increasing the decalin/plastic ratio led to enhanced α-olefin and n-paraffins yields, but the increase was more significant in the case of α-olefins, which are valuable compounds useful as raw chemicals. A reaction mechanism was proposed to explain the results obtained in presence of decalin. In these reactions, intramolecular radical transfer, secondary radical β-scission and hydrogen transfer from both decalin to intermediate radicals and from the polymer chain to regenerate the decalin play a significant role in determining the plastic conversion and the relative amounts of each product.     

Improvement of Waste Recycling in PET Fiber Production

Production of polyethylene teraphtalate (PET) fiber in the world is increasing every year and reached to an amount of about 20 million tons a year in 2001. The wastes occur in the production of PET fiber in the amount of about 3–5% of total production. The PET does not degrade for a long time in nature. Since PET is a derivative of petroleum, the wastes of PET are valuable and must be recycled. One of the recycling method of PET wastes is re-melting. Thus, various properties of the PET wastes were improved using the re-melting method by employing an extruder manufactured for the work. Degradation during re-melting decreases the properties of the final product. The results indicate that the properties of recycled PET wastes can be monitored by designing the parameters of the extruder. Also, the further degradation of the material can be prevented and the recycling costs are minimized.     

世界废弃印刷电路板的机械处理技术现状

电子废弃物中废印刷电路板的处置 ,一直是相当复杂的问题。根据废电路板中各种组分的结合方式 ,采用机械方法进行材料的分离 ,是经济适用并与环境相协调的处理手段。本文介绍了废电路板再利用技术中采用的各种机械设备 ,并总结了国外机械处置方法的实践进展。     

日本畜禽产业排泄物处理与循环利用的现状与技术

20世纪40年代后,日本畜禽产业结构向大型集约化方向发展,年畜禽粪便排放总量7600万t左右。同时,由于畜禽产业等中小规模企业排出含有高氮磷等污染物的废水,致使湖泊、海域的富营养化问题日益严重。日本《水质污浊防止法》规定:饲养规模在50m2以上的养猪场和200m2以上的养牛场的排泄物排放标准为:总氮<120mg/L,总磷<16mg/L。牲畜粪便处理技术的研究和开发,一方面着重于高效脱氮除磷技术,另一方面,从资源的有效利用角度考虑,建立各种排水与废弃物处置的自立型循环共生系统。本文介绍了当前日本畜产业排泄物的处理与循环利用的现状与技术,特别是复合回收型处理系统及远程自动控制等技术的应用,推进了生物量循环的循环型社会的形成,同时,实现环境改善与资源的再利用。