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51.
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Pyrolysis for the simultaneous generation of oils and gases can be convenient to obtain hydrocarbons and even to recover crude petrochemicals or to generate energy from waste plastics. A Gray–King apparatus has been used to pyrolyze waste polyethylene (PE), polystyrene (PS), both separately and with different compositions. Thermogravimetric analysis of waste plastics indicated the critical temperatures, which should be effective for pyrolysis. The chosen heating rate was low in order to achieve higher liquid yields. The results showed that waste PS yielded higher liquid, and waste PE yielded higher gaseous products. The dominant liquid product of PS waste was styrene whereas for waste PE, prophenylbenzene was the dominant pyrolysis product. 相似文献
53.
Flame-retardant plastics, such as desktop and laptop personal computer bodies, could be completely liquefied by carbon materials-catalyzed
hydroliquefaction in tetralin without using H2 as a hydrogen source. Active carbons with larger surface areas (1450–3450 m2/g) acted as superior catalysts in transferring tetralin hydrogens to plastics. On the other hand, carbon blacks and fullerene-rich
soot were less active catalysts. Graphite and mesocarbon microbeads did not show any catalytic effects. Benzene, toluene,
and ethylbenzene were obtained as recyclable hydrocarbons; their total amounts varied from 4 wt% to 12 wt% depending on the
types of plastics and the carbon materials used. Organic bromides such as polybromodioxins were not contained in the gases
and oils of the product.
Received: July 19, 2000 / Accepted: September 17, 2000 相似文献
54.
目的 研究特种工程塑料聚醚醚酮(PEEK)在紫外光照射实验室加速条件下的老化行为。方法 对PEEK塑料采取紫外线光老化方式进行试验,对老化前后的样品进行外观变化、力学性能、热性能、微观结构表征与分析,明确紫外环境因素对材料的性能影响,进而确定PEEK塑料在紫外光条件下的老化行为。结果 随着紫外光老化时间的增加,PEEK样品表面变黄,颜色加深,出现鼓包与裂纹等宏观与微观损伤。样品内部力学性能、热性能、红外特征吸收峰、元素含量与价态没有明显变化,样品表面热性能下降,傅里叶变换衰减全反射红外光谱(ATR-FTIR)特征吸收峰变化明显。结论 PEEK塑料表面对紫外光比较敏感,在紫外光的照射下容易发生表层的分解,短时间内不会引起材料整体热性能及力学性能的明显变化。 相似文献
55.
Annually 2.7 million tonnes of plastics containing Flame Retardants (FRs) are globally discarded in Waste Electrical and Electronic Equipment (WEEE). Little is known on the feasibility of closing material loops for FR plastics. Therefore, series of experiments were set up to analyze the feasibility of separating plastics containing FRs from one specific product category, namely End-of-Life (EoL) Liquid Crystal Display (LCD) TVs. The characterization of the housings of this waste stream indicated a concentration of 18 wt% Bromine based (Br) FRs and 31 wt% Phosphor based (P) FRs, the remainder not containing FRs. With practical tests it was demonstrated that, after disassembly and plastic identification, the co-polymer poly-carbonate (PC)/acrylonitrile-butadiene-styrene (ABS) containing PFR can be recycled in a closed loop system. Based on the determined plastic density distributions and separation efficiencies of optical sorters, a purity of 82% was calculated for PFR PC/ABS separated from EoL LCD TVs after size-reduction (shredding). Performed miscibility tests indicated that for this fraction at least a factor 10 dilution with virgin material is required. In addition, higher waste volumes are required for a size-reduction based treatment to become economically viable and technical challenges still need to be faced, whereas closed loop recycling of PFR PC/ABS from the current waste stream of EoL LCD TVs of different brands in a disassembly based treatment is found to be technically feasible and economically viable under European boundary conditions. 相似文献
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This paper describes the quantitative determination of F, Cl, Br, Cd and Pb in plastic materials. The concentration of the elements Cl, Br, Cd and Pb is first semiquantitatively measured by X‐ray fluorescence spectrometry (XRF) directly in the solid sample with a detection limit of approximately 10 μg/g. Afterwards, F and any of the other elements which exceed the limit values for materials which are disposable without special precautions are measured after the digestion of the material. The samples are digested either under pressure in an oxygen atmosphere for F, Cl and Br or under pressure with nitric acid for Cd and Pb. The digestion converts the halides to the anions which are measured potentiometrically (F‐, Br‐) or with ion chromatography (Cl‐). Cd and Pb are measured by graphite furnace atomic absorption spectrometry (GF‐AAS). The determination limits achieved are 20 μg/g for F and Br, 250 μg/g for Cl, 0.01 μg/g for Cd and 0.2 μg/g for Pb, all below the limit values set by current regulations in Switzerland. 相似文献
59.
为了研究玻璃钢管道在原油输送过程中的结垢问题,通过搅拌实验的方法对玻璃钢管道内的结垢情况进行了模拟实验,并运用Origin8.0绘图软件拟合得到了基于油品温度、流量以及流动距离的玻璃钢管道原油输送结垢计算公式;采用VB6.0编程语言,对所研究的内容及公式进行编程,通过与新疆HK玻璃钢管线现场清管运行参数对比,对结垢计算公式进行了修正。结果表明:由该程序计算所得玻璃钢管线结垢量情况以及不同位置在不同流量下的结构速率与实验结果吻合,因此,所编程序计算结果能够有效地为玻璃钢管线现场清管周期的确定提供理论依据。 相似文献
60.
在分析废旧塑料再生利用工艺过程的基础上,确定了废塑料综合利用工艺的产污节点,并通过物流平衡和水平衡计算,得出了总的产排污量,为环境保护措施提供重要依据,以实现保护环境和资源合理再生利用。 相似文献