一起钢质无缝气瓶爆炸事故技术分析

文章简要描述了一起消防气体灭火钢质气瓶爆炸事故,对爆炸气瓶进行了断口分析、金相试验和理化试验,并分析了事故的原因,提醒制造厂家规范制造工艺,对预防类似事故的发生具有一定的参考意义。     

Limiting explosible concentration of hydrogen–oxygen–helium mixtures related to the practical operational case

This paper presents data on the limiting (minimum) concentrations of hydrogen in oxygen, in the presence of added helium, at elevated temperature and pressure related to the practical operational case. A 5 L explosion vessel, an ignition sub-system and a transient pressure measurement sub-system were used. Through a series of experiments carried out using this system, the limiting concentrations of hydrogen in oxygen and helium at different initial pressures and temperatures for the practical operational case were studied, and the influence of ignition energy and initial temperature on the limiting concentration of hydrogen in oxygen and helium was analyzed and discussed. The variation of ignition energy within the studied range is found to have a significant effect on the limiting concentration of hydrogen in oxygen and helium at lower initial temperature. However, when the ignition energy is higher than 32 mJ, the limiting hydrogen concentration remains almost changeless as the initial temperature increases from 21 °C to 90 °C. The limiting explosible concentration of hydrogen–oxygen–helium mixture decreases as the ignition energy increases when the initial temperature is lower. When the initial temperature is higher, the ignition energy has little effect on the limiting hydrogen concentration of hydrogen–oxygen–helium mixtures. When the initial temperature reaches 90 °C, the limiting hydrogen concentration remains almost changeless with an increase in ignition energy. The limiting explosible concentration of hydrogen in the mixtures, at the initial temperature of 21 °C and the ignition energy of 0.5 mJ, is 8.5% and that of oxygen is 11.25%.     

Dynamic behavior of direct spring loaded pressure relief valves in gas service: Model development,measurements and instability mechanisms

A synthesis of previous literature is used to derive a model of an in-service direct-spring pressure relief valve. The model couples low-order rigid body mechanics for the valve to one-dimensional gas dynamics within the pipe. Detailed laboratory experiments are also presented for three different commercially available values, for varying mass flow rates and length of inlet pipe. In each case, violent oscillation is found to occur beyond a critical pipe length, which may be triggered either on valve opening or closing. The test results compare favorably to the simulations using the model. In particular, the model reveals that the mechanism of instability is a Hopf bifurcation (flutter instability) involving the fundamental, quarter-wave pipe mode. Furthermore, the concept of the effective area of the valve as a function of valve lift is shown to be useful in explaining sudden jumps observed in the test data. It is argued that these instabilities are not alleviated by the 3% inlet line loss criterion that has recently been proposed as an industry standard.     

Optimization of HSE in maintenance activities by integration of continuous improvement cycle and fuzzy multivariate approach: A gas refinery

Gas refineries have been continuously focusing on Health, Safety and Environment programs to improve maintenance activities. Several researches have studied on this area with different analysis methods. This study presents an integrated approach for optimization of factors contributing to the implementation of Health, Safety and Environment (HSE) in maintenance activities. HSE managers in each sector answered standard questionnaire whit respect to HES. The methodology is based on fuzzy data envelopment analysis (FDEA) and Deming's continuous improvement cycle. Also, this method is used to rank the relevant performance efficiencies in certain and uncertain conditions of each HSE sectors whit considering HSE in maintenance activities. It corresponds and integrates its registered HSE-MS with OHSAS 18001:2007 and ISO 14001:2004 to evaluate multiple inputs and outputs of over 36 subsidiary HSE divisions with parallel mission and objectives simultaneously. Also, it determines efficient target indices and could assure continuous improvement in the organization. This is the first study that introduces an integrated approach to improve HSE management programs in a gas refinery by a robust and continuous improvement approach.     

Thermodynamic investigation and hydrate inhibition of real gas flow through orifice during depressurization

A thermodynamic procedure has been proposed which can be used to predict the gas pressure, temperature and flow rate through orifice upon chock flow condition, using equation of state (EOS). The procedure applied for emergency depressurization operation incorporating the Peng-Robinson EOS and validated by comparing flow rates of a multi-component hydrocarbon gas mixture for thirteen experimental cases. The average absolute deviations of the predicted flow rates for orifice discharge coefficients of 0.85 and 0.9, are 7.36% and 2.03%, respectively. The corresponding error for API 520 (American Petroleum Institute Recommendation Practice 520) method is 6.91%. In this work, the hydrate formation temperature and hydrate inhibitor type and its required weight fraction for preventing the hydrate formation upon orifice and its upstream conditions are evaluated by the EZ-Thermo software using the Moshfeghian–Maddox method. The results qualitatively show that the hydrate prevention is essential for the safety of the operation due to low temperature condition.     

加强发证检验工作确保海上石油生产安全

针对国家关于海上石油天然气生产设施检验和石油作业安全管理的相关规定,结合胜利油田开展发证检验工作的实际情况。对当前海上石油生产设施发证检验过程中存在的问题进行了探究,并提出了相应的对策建议。     

Worst-case identification of gas dispersion for gas detector mapping using dispersion modeling

To quickly and accurately quantify the material release in process units, gas detectors may be placed according to the results of gas dispersion modeling. DNV's PHAST software is one of the most useful and reliable tools for material dispersion modeling. In this software, fluid dispersion is modeled based on the process conditions, the weather conditions and the specifications of the material release point. However, varying weather conditions throughout the year and the exact determination of the release point on the plot plan and the release elevation are problematic; these issues cause the results to be non-exact and non-integrated. Choosing the most appropriate conditions is challenging. In this paper, a scheme was provided to select the most appropriate conditions for gas dispersion modeling. This scheme approaches modeling based on the worst-case scenario (the situation in which the dispersed gas reaches the detector later in comparison to the other cases). Therefore, different weather conditions, release elevations and release points on the plot plan were modeled for an absorber tower of the Gonbadli Dehydration Unit of the Khangiran Refinery. The worst case of each release condition was then chosen. Finally, gas detectors were placed using the gas dispersion modeling results based on the worst-case scenario.     

水中阿特拉津的气相色谱法测定

采用正已烷液液萃取方法,萃取液经320m石英弹性毛细管柱分离,用电子捕获检测器(ECD)检测水中阿特拉津,得到了良好的分离效果和较高的灵敏度及精密度,达到GB3838—2003《地面水环境质量标准》中的要求。     

电厂烟气脱硫机组改造取消GGH可行性研究分析

介绍了石灰石一石膏湿法烟气脱硫工艺及烟气换热器（简称GGH）在烟气脱硫（简称FGD）工程中的作用,指出安装GGH产生的烟囱腐蚀和增加系统故障等问题。实践证明烟气脱硫工程取消GGH对大气环境无明显影响,并且能产生较大的经济效益。