Assessment of polychlorinated dibenzo-p-dioxin and dibenzofuran emissions from a hazardous waste incineration plant using long-term sampling equipment

The aim of this work is to evaluate the performance of a continuous monitoring system for the analysis of the mass concentration of PCDD/Fs from stationary sources. Data was acquired from a modern, state of the art, hazardous waste thermal treatment plant for a period of more than 2 years using a commercial available continuous monitoring system. The study consisted of a total of 16 samples, collected in periods from 1 week to 2 months resulting in an average of 360 m³ sampled flue gas per sample. The study showed the system was able to confirm that for a period of more than 2 years the plant was complying with the limit of 0.1 ng I-TEQ/Nm³. In addition, the data showed the typical fingerprint of such installations which is useful for example in impact studies. Long-term samples were compared to five short-term samples (6 h) collected every 6 months during the study period. Principal component analysis was applied to PCDD/Fs obtained data as useful statistical tool to find out trends and similarities between different samples. Improvement in terms of representativeness of data was achieved through continuous assessment since the starts of the project. The obtained data was further used to determine the emission factor for this activity and the total annual PCDD/Fs release to the atmosphere.     

Statistical uncertainty in hazardous terrestrial concentrations estimated with aquatic ecotoxicity data

Since chemicals’ ecotoxic effects depend for most soil species on the dissolved concentration in pore water, the equilibrium partitioning (EP) method is generally used to estimate hazardous concentrations (HC50) in the soil from aquatic toxicity tests. The present study analyzes the statistical uncertainty in terrestrial HC50s derived by the EP-method. For 47 organic chemicals, we compared freshwater HC50s derived from standard aquatic ecotoxicity tests with porewater HC50s derived from terrestrial ecotoxicity tests. Statistical uncertainty in the HC50s due to limited species sample size and in organic carbon–water partitioning coefficients due to predictive error was treated with probability distributions propagated by Monte Carlo simulations. Particularly for specifically acting chemicals, it is very important to base the HC50 on a representative sample of species, composed of both target and non-target species. For most chemical groups, porewater HC50 values were approximately a factor of 3 higher than freshwater HC50 values. The ratio of the porewater HC50/freshwater HC50 was typically 3.0 for narcotic chemicals (2.8 for nonpolar and 3.4 for polar narcotics), 0.8 for reactive chemicals, 2.9 for neurotoxic chemicals (4.3 for AChE agents and 0.1 for the cyclodiene type), and 2.5 for herbicides–fungicides. However, the statistical uncertainty associated with this ratio was large (typically 2.3 orders of magnitude). For 81% of the organic chemicals studied, there was no statistical difference between the hazardous concentration of aquatic and terrestrial species. We conclude that possible systematic deviations between the HC50s of aquatic and terrestrial species appear to be less prominent than the overall statistical uncertainty.     

Development of Tools for Integrated Monitoring and Assessment of Hazardous Substances and Their Biological Effects in the Baltic Sea

The need to develop biological effects monitoring to facilitate a reliable assessment of hazardous substances has been emphasized in the Baltic Sea Action Plan of the Helsinki Commission. An integrated chemical–biological approach is vitally important for the understanding and proper assessment of anthropogenic pressures and their effects on the Baltic Sea. Such an approach is also necessary for prudent management aiming at safeguarding the sustainable use of ecosystem goods and Services. The BEAST project (Biological Effects of Anthropogenic Chemical Stress: Tools for the Assessment of Ecosystem Health) set out to address this topic within the BONUS Programme. BEAST generated a large amount of quality-assured data on several biological effects parameters (biomarkers) in various marine species in different sub-regions of the Baltic Sea. New indicators (biological response measurement methods) and management tools (integrated indices) with regard to the integrated monitoring approach were suggested.     

Sequential photochemical-biological degradation of chlorophenols

UV/TiO₂/H₂O₂, UV/TiO₂ and UV/H₂O₂ were compared as pre-treatment processes for the detoxification of mixtures of 4-chlorophenol (4CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP) and pentachlorophenol (PCP) prior to their biological treatment. When each chlorophenol was initially supplied at 50 mg l⁻¹, UV/TiO₂/H₂O₂ treatment supported the highest pollutant removal, COD removal, and dechlorination efficiencies followed by UV/TiO₂ and UV/H₂O₂. The remaining toxicity to Lipedium sativum was similar after all pre-treatments. Chlorophenol photodegradation was always well described by a first order model kinetic (r² > 0.94) and the shortest 4CP, DCP, TCP and PCP half-lives of 8.7, 7.1, 4.5 and 3.3 h, respectively, were achieved during UV/TiO₂/H₂O₂ treatment. No pollutant removal was observed in the controls conducted with H₂O₂ or TiO₂ only. Inoculation of all the photochemically pre-treated mixtures with activated sludge microflora was followed by complete removal of the remaining pollutants. Combined UV/TiO₂/H₂O₂-biological supported the highest detoxification, dechlorination (99%) and COD removal (88%) efficiencies. Similar results were achieved when each chlorophenol was supplied at 100 mg l⁻¹. COD and Cl mass balances indicated UV, UV/H₂O₂, and UV/TiO₂ treatments lead to the formation of recalcitrant photoproducts, some of which were chlorinated.     

DNAPL distribution in the source zone: effect of soil structure and uncertainty reduction with increased sampling density

This paper focuses on parameters describing the distribution of dense nonaqueous phase liquid (DNAPL) contaminants and investigates the variability of these parameters that results from soil heterogeneity. In addition, it quantifies the uncertainty reduction that can be achieved with increased density of soil sampling. Numerical simulations of DNAPL releases were performed using stochastic realizations of hydraulic conductivity fields generated with the same geostatistical parameters and conditioning data at two sampling densities, thus generating two simulation ensembles of low and high density (three-fold increase) of soil sampling. The results showed that DNAPL plumes in aquifers identical in a statistical sense exhibit qualitatively different patterns, ranging from compact to finger-like. The corresponding quantitative differences were expressed by defining several alternative measures that describe the DNAPL plume and computing these measures for each simulation of the two ensembles. The uncertainty in the plume features under study was affected to different degrees by the variability of the soil, with coefficients of variation ranging from about 20% to 90%, for the low-density sampling. Meanwhile, the increased soil sampling frequency resulted in reductions of uncertainty varying from 7% to 69%, for low- and high-uncertainty variables, respectively. In view of the varying uncertainty in the characteristics of a DNAPL plume, remedial designs that require estimates of the less uncertain features of the plume may be preferred over others that need a more detailed characterization of the source zone architecture.     

基于浏览器/服务器的危险废物管理区域决策支持信息系统的研究与开发

讨论了危险废物管理区域决策支持系统的体系结构、开发方法、应用环境、逻辑和功能结构、安全性设计以及系统实现方法 .该区域决策支持系统的设计方法和结构框架对其他环境信息系统开发与设计具有借鉴意义 .     

美国危险废物的管理与处理处置

以危险废物的全过程管理为主线 ,阐述了美国现阶段危险废物管理的特点 ;通过介绍美国危险废物管理的重要法典《RCRA》,对美国危险废物管理体系进行全面分析 ;重点分析了对我国建立危险废物管理体系有借鉴意义的豁免制度、贮备金制度     

合成树脂行业固体废物产生节点及环境管理分析

2020年9月1日修订实施的《中华人民共和国固体废物污染环境防治法》在工业固体废物管理中强化了企业自主管理,并提出全过程管理要求。合成树脂行业在我国工业领域中占有重要位置,从事生产的企业以大型石化企业为主,其有能力也有责任科学管理固体废物,以实现固体废物无害化、减量化、资源化。阐述了合成树脂行业中聚乙烯、聚丙烯和聚氯乙烯的生产工艺过程和生产环节特点,详细介绍了固体废物的产生节点、废物属性及管理措施,对所产生的固体废物进行分类梳理,总结企业固体废物处理处置措施,并针对合成树脂行业固体废物产生现状提出管理建议,以期为我国危险废物环境管理及《国家危险废物名录》动态修订提供科学依据,也为企业自主管理方式提供指导方向。     

四川省危险废物管理现状分析及评价

随着城市化进程的加快,危险废物的产生量快速增加,数量多、分布广、危害大、潜在利用价值高,管理处理难度大,因此带来了巨大的环境安全隐患。本文利用相关调查统计数据,分析了四川省危险废物产生特性及污染特性,指出危险废物管理过程中出现的问题已成为阻碍四川省循环经济发展及生态省建设的壁垒,针对出现的问题,提出了相关对策和建议。     

Risk informed optimization of a hazardous material multi-periodic transportation model

This paper presents a systematic framework toward the development of a Transportation Model for Hazardous Materials (HazMat). In practice, the proposed modeling framework is realized through an appropriate generalization of the traditional transportation network problem in the presence of safety constraints that need to be satisfied. The objective is to minimize transportation cost while reducing risks at the desired levels.In particular, the present research study identifies and evaluates different risk factors that influence the HazMat transportation network. Next, the transportation model is depicted graphically using nodes and arcs and optimal conditions are identified by solving the associated minimum cost flow network problem. The results show safety levels that help making informed decisions on choosing the optimal transportation configuration for hazardous material shipments.Within the proposed methodological context, appropriately parameterized simulation studies elucidate the effects of occurrence probabilities of the different risk events on transportation cost. Furthermore, as the appropriate management decisions must consider the effect of actions in one time period on future periods, the proposed model is structured as a multi-periodic model.Finally, the proposed methodological approach is employed to demonstrate the utility of proper analytical tools in decision making and particularly in ensuring that scientifically informed safety procedures are in place while transporting goods that can be potentially proven dangerous to the public and the surroundings.