混凝—SBR法处理城市垃圾填埋场渗滤液方法的研究

针对城市生活垃圾填埋场渗滤液的特点 ,提出了混凝—SBR法处理工艺。试验结果表明 ,经该工艺处理的垃圾渗滤液各项指标可达国家规定的排放标准     

废弃危险化学品安全填埋处置的主要环节及控制

结合沈阳市在废弃物危险化学品安全填埋处置工作中的有关实际 ,介绍了通过安全填埋技术处置废弃危险化学品的各主要技术环节及各环节的控制要点 ,希望此方面技术得到不断发展和应用     

城市生活垃圾填埋场产气规律研究

研究城市垃圾填埋气体成分及产气规律。方法通过深圳市玉龙坑垃圾填埋场现场抽气试验理论计算。结果场区内填埋气体含量分别为ＣＨ４６２．２％，Ｏ２１．０％，ＣＯ２３４．７％，其余气体２．１％；     

垃圾填埋场渗滤液处理的研究进展

介绍了城市垃圾填埋场渗滤液的不同处理方法(生物处理、物化处理、土地处理)和不同处理工艺的现状。由于渗滤液成分的复杂和多样化,所以常采用组合工艺联合处理,处理工艺流程的选用应符合因地制宜的原则,由填埋场当地的气候特征、周围环境、渗滤液水量、水质特性、处理程度及投资情况决定。最后还指出了渗滤液处理技术的发展趋势。     

防止渗滤液污染的工程控制措施

垃圾卫生填埋是当今世界各国城市垃圾处理的主要方式。工程以马鞍山市生活垃圾卫生填埋为例提出了相应的防止渗滤液污染地下水的控制措施，并根据渗滤液的处理试验，确定了渗滤液处理工程的工艺流程。     

日光/H_2O_2/草酸铁体系对垃圾渗滤液深度处理的试验研究

以草酸铁络合物/H2O2作光氧化剂,利用日光对垃圾渗滤生化出水进行了光氧化降解试验。结果表明,在溶液的初始体系pH=3.0,H2O2投加量为460mg/L,Fe3+质量浓度为20mg/L条件下,反应60min后,CODCr去除率可达80%以上;溶液初始体系的pH、H2O2和Fe3+的投加量及废水的水质对光解过程有显著影响,而且在太阳光照射下,CODCr去除率比紫外光照射下高。研究表明,在一定试验条件下,用日光/H2O2/草酸铁体系对城市垃圾渗滤液处理效果较好,可作为垃圾渗滤液的深度处理。     

垃圾渗滤液中的氨氮对微生物活性的抑制作用

研究了合成废水和垃圾滤渗滤中氨氮对活性污泥微生物活性的抑制作用。当合成废水的氨氮浓度从５０ｍｇ／Ｌ依次成倍递增至８００ｍｇ／Ｌ时,脱氢酶活性由１１．０４μｇＴＦ／ｍｇＭＬＳＳ下降至４．２２,此时ＣＯＤ的去除率相应由９５．１％降低到７９．１％。     

Brominated-chlorinated diphenyl ethers formed by thermolysis of polybrominated diphenyl ethers at low temperatures

Polybrominated diphenyl ethers (PBDEs) are a group of brominated flame retardants (BFRs) used mainly as additives in different kinds of plastic material. Various PBDEs are found in all environmental compartments as well as in tissue and blood serum of animals and humans due to their persistence and tendency to bioaccumulate. Emission of PBDEs into the environment can occur during recycling of PBDE-containing plastic material or during their uncontrolled or insufficient combustion as e.g. in accidental fires or landfill fires. Under these circumstances, PBDEs can also function as precursor molecules for the formation of polybrominated dibenzodioxins (PBDDs) and dibenzofurans (PBDFs). In this study, we qualitatively investigated the reaction of two PBDE congeners, 2,2′,4,4′-tetrabromo diphenyl ether (BDE 47) and 2,2′,4,4′,5,5′-hexabromo diphenyl ether (BDE 153), as well as hexabromobenzene (HBB), a flame retardant used in the past, when exposed to temperatures between 250 °C and 500 °C. The formed reaction products were analysed by high resolution gas chromatography–low resolution mass spectrometry (HRGC-LRMS). Among others brominated–chlorinated diphenyl ethers were formed by chlorodebromination of the PBDEs. In addition, thermolysis of BDE 47 and BDE 153 in the presence of tetrachloromethane as model substance for an organic chlorine source was studied. Thermal treatment of HBB resulted in the formation of brominated–chlorinated benzenes.     

Valuation of externalities of selected waste management alternatives: A comparative review and analysis

Accessible and transparent data on the social costs of externalities is crucial to waste management researchers, decision-makers, and managers, if waste management strategies are to be successfully analyzed and implemented. The primary objective of this study, which is based on a thorough review of existing literature and research, was to assist the abovementioned in their decision-making with reliable recent data, by mapping, gathering, analyzing, and comparing different valuation results of external costs associated with various types of pollution and disamenities related to landfilling and incineration of solid waste.The second objective was to assess the suitability and reliability of various valuation methods and techniques that were implemented in the reviewed valuation studies, as well as the transferability of valuations across sites.The paper focuses on studies conducted since 1990, because in dynamic fields such as the waste sector, externalities, and valuation, it is essential to stay current with the most recent information and valuations.We discuss the issues and the limits of the valuation techniques and analyze the estimates of all the studies, presenting the results in the form of intervals and averages of damage costs. In spite of the inconsistencies evident in the variability in the results we reviewed, the outcome of this first comprehensive critical analysis is significant and the valuations obtained in this study provide estimates of orders of magnitude of external costs that can be used by decision makers in the waste sector to address important policy questions associated with social welfare.     

Washing treatment of automotive shredder residue (ASR)

Worldwide, the amount of end-of-life vehicles (ELVs) reaches 50 million units per year. Once the ELV has been processed, it may then be shredded and sorted to recover valuable metals that are recycled in iron and steelmaking processes. The residual fraction, called automotive shredder residue (ASR), represents 25% of the ELV and is usually landfilled. In order to deal with the leachable fraction of ASR that poses a potential threat to the environment, a washing treatment before landfilling was applied. To assess the potential for full-scale application of washing treatment, tests were carried out in different conditions (L/S = 3 and 5 L/kg_TS; t = 3 and 6 h). Moreover, to understand whether the grain size of waste could affect the washing efficiency, the treatment was applied to ground (<4 mm) and not-ground samples. The findings obtained revealed that, on average, washing treatment achieved removal rates of more than 60% for dissolved organic carbon (DOC), chemical oxygen demand (COD) and total Kjeldahl nitrogen (TKN). With regard to metals and chlorides, sulphates and fluoride leachable fraction, a removal efficiency of approximately 60% was obtained, as confirmed also by EC values. The comparison between the results for ground and not-ground samples did not highlight significant differences.