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采用喷淋工艺处理PVC塑料生产废气,将专利的吸收液与改型的喷淋塔相结合,在中试成功的基础上进行了实际工业化应用。应用结果表明:采用该工艺处理某PVC塑料生产企业的生产废气,吸收液在喷淋塔循环液中所占体积分数为15%时,废气中各污染物指标的去除率达85%以上,对于难处理的苯系物也能较好地去除;处理后废气中各污染物指标的含量满足GB 14554—1993《恶臭污染物排放标准》和DB 44/27—2001《大气污染物排放限值》的要求;该工艺装置运行费用较低,仅为电费和少量药剂费用,吸收液可循环使用,设备保养及维护简单,可满足市场需求。 相似文献
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Gholamreza Asadollahfardi Azadeh Panahandeh Ebrahim Inanlo Moghadam Shima Masoumi Mojtaba Tayebi Jebeli 《环境质量管理》2023,32(3):97-110
With the onset of social life, humans have considered waste disposal as essential, and they have been able to repel it through brick and clay channels. Checking sewage pipes for energy consumption and a longer lifetime than other sewage system components is important. Climate change and exploitation of industrial resources have made environmental impacts, which are important factors in decision making. The purpose of this study was to introduce the most suitable type of sewage pipe considering environmental protection. Therefore, we applied the environmental life cycle assessment (LCA) method, using Sima Pro 8.2.3 software for the one-kilometer length of concrete pipes (300 mm in diameter), Polyvinyl chloride (PVC), and polyethylene (PE) (315 mm in diameter). Also, the BEES method and sensitivity analysis were used to validate the results. The comparison between three types of municipal wastewater pipes indicated that PE pipes are a more environmentally friendly option than PVC, and concrete pipes in pipe recycling, reducing extraction from untapped resources, and inefficient extraction of resources. Electricity, diesel fuel, and sulfate resistance cement consumption for concrete production are the most pollution elements in the LCA of concrete pipes. Usage of PVC granular, sanitary landfill of PVC pipes, and using hydraulic drill in LCA of PVC pipes are the most elements of generating pollution. The usage of PE granules, PE pipes landfilling, hydraulic excavator, and electricity consumption in the LCA of the PE pipes are the greatest polluting parameters. 相似文献
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Optimization of the recovery of plastics for recycling by density media separation cyclones 总被引:1,自引:0,他引:1
Gent Malcolm Richard Menendez MarioToraño Javier Torno Susana 《Resources, Conservation and Recycling》2011,55(4):472-482
Material recovery processes are presented as the optimum option for recycling plastic wastes as a means of recovering hydrocarbon resources. There exist a large variety of automated material recovery processes for recycling of such wastes but each with significant limitations. Of these, the separation based on differences in densities is advocated as the optimum process either for producing recycled products or preparing wastes for subsequent recovery processing.Density separation processes based on cyclone type density media separation (DMS) is presented as an important, potential method for increasing plastics recycling process capacities. It is demonstrated to have the capacity to separate a significantly larger range of particle sizes than those presently processed industrially. The mathematical relationship for the prediction of quality of typical LARCODEMS type density media separations by particle size and density as expressed by the Ecart Probable is presented.A proposed device configuration is presented for density media separation to optimize the recovery and purity of both density fractions produced. It is also suggested that to be economically viable, a large scale of operation is required for industrial plastics recycling operations recovering and producing a number of different plastics with a purity to be used as a substitute for virgin material. 相似文献
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利用微型燃烧量热计(MCC)、热重分析(TGA)、实时红外光谱(RTFTIR)以及热重-红外联用技术(TG-FT-IR)研究了PVC电缆料老化前后火灾危险性的变化。MCC结果表明,老化后的PVC的最大热释放速率增加了56.3%,总热释放量从10.6kJ/g增加到16.8kJ/g,点燃温度也由302℃提前到282℃。TG-FTIR和RTFTIR的分析结果显示,PVC的主要降解产物有水、碳氢化合物、二氧化碳和一氧化碳。PVC达到最大降解速率的温度约为240℃,与MCC、TG的结果相符合。PVC的裂解气体中包含CO2和CO,还有剧毒气体HCl。这些实验数据说明PVC材料在使用过程中火灾危险性加大,为老城区电气线路和设备的改造提供了理论依据和实验基础。 相似文献
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Ronnen Levinson Paul Berdahl Asmeret Asefaw Berhe Hashem Akbari 《Atmospheric environment (Oxford, England : 1994)》2005,39(40):7807-7824
A roof with high solar reflectance and high thermal emittance (e.g., a white roof) stays cool in the sun, reducing cooling power demand in a conditioned building and increasing summertime comfort in an unconditioned building. The high initial solar reflectance of a white membrane roof (circa 0.8) can be lowered by deposition of soot, dust, and/or biomass (e.g., fungi or algae) to about 0.6; degraded solar reflectances range from 0.3 to 0.8, depending on exposure. We investigate the effects of soiling and cleaning on the solar spectral reflectances and solar absorptances of 15 initially white or light-gray polyvinyl chloride membrane samples taken from roofs across the United States. Black carbon and organic carbon were the two identifiable strongly absorbing contaminants on the membranes. Wiping was effective at removing black carbon, and less so at removing organic carbon. Rinsing and/or washing removed nearly all of the remaining soil layer, with the exception of (a) thin layers of organic carbon and (b) isolated dark spots of biomass. Bleach was required to clear these last two features. At the most soiled location on each membrane, the ratio of solar reflectance to unsoiled solar reflectance (a measure of cleanliness) ranged from 0.41 to 0.89 for the soiled samples; 0.53 to 0.95 for the wiped samples; 0.74 to 0.98 for the rinsed samples; 0.79 to 1.00 for the washed samples; and 0.94 to 1.02 for the bleached samples. However, the influences of membrane soiling and cleaning on roof heat gain are better gauged by fractional variations in solar absorptance. Solar absorptance ratios (indicating solar heat gain relative to that of an unsoiled membrane) ranged from 1.4 to 3.5 for the soiled samples; 1.1 to 3.1 for the wiped samples; 1.0 to 2.0 for the rinsed samples; 1.0 to 1.9 for the washed samples; and 0.9 to 1.3 for the bleached samples. 相似文献
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G. Yuan D. Chen L. Yin Z. Wang L. Zhao J.Y. Wang 《Waste management (New York, N.Y.)》2014,34(6):1045-1050
In this research a gas–liquid fluidized bed reactor was developed for removing chlorine (Cl) from polyvinyl chloride (PVC) to favor its pyrolysis treatment. In order to efficiently remove Cl within a limited time before extensive generation of hydrocarbon products, the gas–liquid fluidized bed reactor was running at 280–320 °C, where hot N2 was used as fluidizing gas to fluidize the molten polymer, letting the molten polymer contact well with N2 to release Cl in form of HCl. Experimental results showed that dechlorination efficiency is mainly temperature dependent and 300 °C is a proper reaction temperature for efficient dechlorination within a limited time duration and for prevention of extensive pyrolysis; under this temperature 99.5% of Cl removal efficiency can be obtained within reaction time around 1 min after melting is completed as the flow rate of N2 gas was set around 0.47–0.85 Nm3 kg?1 for the molten PVC. Larger N2 flow rate and additives in PVC would enhance HCl release but did not change the final dechlorination efficiency; and excessive N2 flow rate should be avoided for prevention of polymer entrainment. HCl is emitted from PVC granules or scraps at the mean time they started to melt and the melting stage should be taken into consideration when design the gas–liquid fluidized bed reactor for dechlorination. 相似文献