全文获取类型
收费全文 | 138篇 |
免费 | 8篇 |
国内免费 | 9篇 |
专业分类
安全科学 | 5篇 |
废物处理 | 30篇 |
环保管理 | 18篇 |
综合类 | 59篇 |
基础理论 | 18篇 |
污染及防治 | 17篇 |
评价与监测 | 1篇 |
社会与环境 | 5篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 4篇 |
2020年 | 6篇 |
2019年 | 7篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2014年 | 10篇 |
2013年 | 13篇 |
2012年 | 5篇 |
2011年 | 10篇 |
2010年 | 7篇 |
2009年 | 4篇 |
2008年 | 5篇 |
2007年 | 5篇 |
2006年 | 8篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 8篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 5篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1988年 | 1篇 |
排序方式: 共有155条查询结果,搜索用时 15 毫秒
31.
32.
López A de Marco I Caballero BM Adrados A Laresgoiti MF 《Waste management (New York, N.Y.)》2011,31(8):1852-1858
In this work, a study of the regeneration and reuse of ZSM-5 zeolite in the pyrolysis of a plastic mixture has been carried out in a semi-batch reactor at 440 °C. The results have been compared with those obtained with fresh-catalyst and in non-catalytic experiments with the same conditions. The use of fresh catalyst produces a significant change in both the pyrolysis yields and the properties of the liquids and gases obtained. Gases more rich in C3-C4 and H2 are produced, as well as lower quantities of aromatic liquids if compared with those obtained in thermal decomposition. The authors have proved that after one pyrolysis experiment the zeolite loses quite a lot of its activity, which is reflected in both the yields and the products quality; however, this deactivation was found to be reversible since after regeneration heating at 550 °C in oxygen atmosphere, this catalyst recovered its initial activity, generating similar products and in equivalent proportions as those obtained with fresh catalyst. 相似文献
33.
Somrutai Poothong Suwanna Kitpati Boontanon Narin Boontanon 《Journal of environmental science and health. Part. B》2013,48(10):830-835
This research aimed to optimize the extraction method parameters for sample pretreatment and determine the levels of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) contamination in food packaging made of paper. Techniques used were pressurized liquid extraction (PLE) followed by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). Influence parameters of PLE were carefully evaluated for extracted concentration of samples in low level (ng g?1). The study found that the optimal conditions for PLE were 30 min static extraction time with a flush volume of 100% cell volume and one extraction cycle at 80°C and 1,000 psi. The extraction technique validated the absolute recovery from PFOS and PFOA fortified control samples at three different levels (5, 50, and 200 ng g?1), with seven repeats at each fortification level. The average recoveries were 79% or higher, with relative standard deviation (RSD) less than 11%. Optimization of the PLE method was established based on recovery data, accuracy, precision, and repeatability of the method. Using optimal PLE technique, PFOS and PFOA were extracted from 34 food-packaging samples collected in Thailand. PFOS and PFOA were detected in all kinds of collected samples, with average concentrations of 4.89 and 2.87 ng g?1, respectively. The concentrations of PFOS and PFOA were highest in fast-food container samples: 36.99 and 9.99 ng g?1, respectively. 相似文献
34.
35.
J. Aguado D. P. Serrano G. Vicente N. Sánchez 《Journal of Polymers and the Environment》2006,14(4):375-384
The thermal cracking of HDPE in presence of different amounts of decalin was studied and compared with the reaction carried out in the absence of solvent. The decalin favours the mass and heat transfer during the reaction. In addition, it modifies the thermal degradation mechanism, which facilitates the formation of specific products. The use of decalin substantially increases the C5–C32 yield in comparison with the solventless reaction. In all cases, linear hydrocarbons such as n-paraffins, α-olefins and α,ω-dienes were detected. Increasing the decalin/plastic ratio led to enhanced α-olefin and n-paraffins yields, but the increase was more significant in the case of α-olefins, which are valuable compounds useful as raw chemicals. A reaction mechanism was proposed to explain the results obtained in presence of decalin. In these reactions, intramolecular radical transfer, secondary radical β-scission and hydrogen transfer from both decalin to intermediate radicals and from the polymer chain to regenerate the decalin play a significant role in determining the plastic conversion and the relative amounts of each product. 相似文献
36.
介绍了采用温湿度仪连续监测的方法测定复合材料包装容器的透湿度,对缩短试验时间,减小测试误差具有参考意义。提出对于复合材料包装容器部分为金属材料的情况,透湿面积的计算方式。 相似文献
37.
微波催化燃烧技术将微波辐照与吸波型催化剂相结合,可用于对挥发性有机化合物(VOCs)进行催化燃烧处置。研制了Pt/CuMnCeOx/堇青石和Pt/CuMnCeOx/纳米陶瓷整体式蜂窝状催化剂,并开发了微波催化燃烧VOCs的装置,将其应用于印刷包装行业的VOCs治理。通过操作条件的优化,考察了微波催化燃烧技术对VOCs的实际处理效果。同时,对催化剂表面形貌、比表面积和晶体结构等进行了测试分析。结果表明:Mn3O4/Mn2O3、CeO2/Ce2O3、CuMn2O4和PtO等尖晶石的存在降低了反应温度、提高了储氧释氧能力和催化剂活性;催化剂的介孔结构和较大的比表面积有利于VOCs在孔隙内部的扩散,并可延长VOCs在催化剂上的停留时间。在催化剂床层体积330 L、微波功率13.6 kW、进气质量浓度1 520 mg·m-3和进气量440 m3·h−1的条件下,床层温度可达到420 ℃,此时催化剂床层温度及VOCs去除率保持稳定。当进气质量浓度分别为约4 500 mg·m−3和2 800 mg·m−3时,VOCs的去除率分别为90%和96%。考察燃烧热量发现,大气量的VOCs在催化剂表面的停留时间短且带走热量多,从而导致VOCs去除率下降;高浓度VOCs在燃烧时会因释放出更多热量,从而提高床层温度和VOCs去除率。在确保催化剂表面活性位点充足的条件下,微波催化燃烧工艺适合处理中高浓度的印刷包装行业VOCs。同时,利用VOCs燃烧释放的热量来保持床层高温,还可达到节能降耗的目的。本研究可为印刷包装行业的VOCs治理提供参考。 相似文献
38.
国内外枪械自然环境试验概况 总被引:3,自引:0,他引:3
简要介绍国内外的枪械环境试验管理及枪械的自然环境试验情况,建议将环境工程的概念纳入到枪械设计制造中,努力提高枪械环境适应性,打造我国的世界名枪。 相似文献
39.
Charles A. Ambrose Richard Hooper Anthony K. Potter M. Margaret Singh 《Resources, Conservation and Recycling》2002,36(4)
Mechanical recycling of 100% post-consumer plastic waste into high-quality products has been performed. The chemical and physical properties of these recycled materials have been compared with similar products manufactured from virgin resins. The properties of a blow-moulded bottle prepared from 100% post-consumer high-density polyethylene (HDPE) showed that this recycled polymer exceeded the materials specifications for virgin plastic designs. Similarly, a sample of thermoplastic polyolefin (TPO, 100% polypropylene), obtained entirely from shredder residue (SR) displayed sufficient material strength for future separation and reprocessing. 相似文献
40.
S. Martínez-Lera J. Torrico J. Pallarés A. Gil 《Waste management (New York, N.Y.)》2013,33(7):1640-1647
The use of plastic bags and film packaging is very frequent in manifold sectors and film waste is usually present in different sources of municipal and industrial wastes. A significant part of it is not suitable for mechanical recycling but could be safely transformed into a valuable gas by means of thermal valorization. In this research, the gasification of film wastes has been experimentally investigated through experiments in a fluidized bed reactor of two reference polymers, polyethylene and polypropylene, and actual post-consumer film waste. After a complete experimental characterization of the three materials, several gasification experiments have been performed to analyze the influence of the fuel and of equivalence ratio on gas production and composition, on tar generation and on efficiency. The experiments prove that film waste and analogue polymer derived wastes can be successfully gasified in a fluidized bed reactor, yielding a gas with a higher heating value in a range from 3.6 to 5.6 MJ/m3 and cold gas efficiencies up to 60%. 相似文献