气相色谱法测定水质中的内吸磷

优化了气相色谱法测定水质中的内吸磷,当取样量为100 m L时,内吸磷-O方法检出限为0. 30μg/L,测定下限为1. 20μg/L;内吸磷-S方法检出限为0. 80μg/L,测定下限为3. 20μg/L。内吸磷-O和内吸磷-S标准曲线线性良好,相关系数分别为0. 999 2和0. 999 8。不同水质中内吸磷-O的加标回收率为90. 3%～104%,相对标准偏差为3. 6%～9. 2%;内吸磷-S的加标回收率为92. 1%～94. 9%,相对标准偏差为4. 6%～8. 7%。该方法灵敏度高,能有效分离内吸磷-O和内吸磷-S,同时能将内吸磷-O、内吸磷-S与其他有机磷农药类干扰物分离。     

城市垃圾污染防治对策探讨

从城市拉圾产生的机制入手，分析了城市垃圾污染产生的原因，并对目前所采取的主要处理方法人季简要评述，在此基础提出了实现城市垃圾最小量化，推动垃圾资源化产业、提高垃圾无害化处理水平，中化监督管理等几点城市垃圾污染防治的对策。     

1000t/d含油废水旋流分离技术及设备研究

将实验室研制的 HL 型旋流器用压力容器式方式并联起来 ,建立 10 0 0 t/ d规模的示范装置 ,并进行试验。示范装置的试验结果表明 ,与工业测试比较 ,HL型旋流器并没有因为规模的放大而造成性能下降 ,它能取代石化行业目前采用的“一隔二浮”流程中的大部分装置 ,具有明显的经济效益和广阔的应用前景     

隔油沉淀-预曝调节-接触氧化-气浮工艺处理屠宰加工废水

对屠宰加工过程中产生的中高浓度有机废水采用预曝调节-接触氧化-气浮工艺进行处理。当进水COD浓度为980~1200mg/L时,出水COD浓度可降至76.1~104mg/L,优于国家《肉类加工工业水污染物排放标准》(GB13457-92)二级标准,此工艺的抗冲击负荷能力较强,适应于间歇性生产和季节性生产的屠宰加工企业。     

无机纳米材料吸附分离放射性核素的研究进展

介绍了无机纳米材料特殊的理化性质,综述了纳米氧化物、纳米含氧酸盐和碳纳米管等无机纳米材料在放射性核素吸附分离中的研究进展。提出应对纳米材料进行负载、修饰或功能化研究,制备高性能的复合纳米材料,提高其稳定性和选择性;寻求更经济可行的制备方法,降低纳米材料的生产成本,逐步实现产业化;深入研究纳米材料对放射性核素的吸附机理;在辐射效应对纳米吸附剂的结构稳定性影响方面开展研究,并与现有方法作比较,评价其应用的有效性和可靠性。     

清洁的胡椒基T醚生产工艺的研究I,5-丙基-1,3-苯并二氧杂茂的氯甲基化废水的处理

报道了胡椒基丁醚生产中５－丙基－１，３－苯并二氧杂茂的氯甲基化的废水处理，该废水经蒸馏可回收９４％的盐酸，此酸吸收氯化氢后浓度在３６％以上，可再用于氯甲基化反应。蒸馏残液经分油、Ｆｅｎｔｏｎ试剂处理和五次生炭柱吸附后ＣＯＤＣｒ等项指标均可国家二类污染物的一级排放标准。     

Acceleration of floc-water separation and floc reduction with magnetic nanoparticles during demulsification of complex waste cutting emulsions

Waste cutting emulsions are difficult to treat efficiently owing to their complex composition and stable emulsified structure.As an important treatment method for emulsions,chemical demulsification is faced with challenges such as low flocs-water separation rates and high sludge production.Hence,in this study,Fe₃O₄ magnetic nanoparticles(MNPs)were used to enhance chemical demulsification performance for treating waste cutting emulsions under a magnetic field.The addition of...     

Analytical methods and environmental processes of nanoplastics

The degradation of plastic debris may result in the generation of nanoplastics(NPs). Their high specific surface area for the sorption of organic pollutions and toxic heavy metals and possible transfer between organisms at different nutrient levels make the study of NPs an urgent priority. However, there is very limited understanding on the occurrence, distribution, abundant, and fate of NPs in the environment, partially due to the lack of suitable techniques for the separation and identificatio...     

Carbon nanotubes as sorbents in the analysis of pesticides

With increasing public concerns for agrochemicals and their potential movement in the ecosystem, very sensitive, selective and precise methods for the analysis of pesticides are needed. Because these substances are present usually at trace levels, the extraction and preconcentration steps are so far essential for their detection. Discoveries of novel nanomaterials with unique properties have significant impact on their use also in extraction techniques. This overview reports the recent application of carbon nanotubes in the analysis of pesticides. The largest numbers of reported applications of carbon nanotubes concern their role as a sorbent materials in solid-phase extraction and microextraction techniques.     

Toward separation at source: Evolution of Municipal Solid Waste management in China

Municipal Solid Waste (MSW) management in China has been transitioning from a mixed collection and treatment system to a separated collection and treatment system. The continuous rise of MSW treatment capacity and the optimization of technology structure provided basic facility support for China to promote MSW separation at source. China preferred a four-type separation system. Regulated recycling should be enhanced to improve the efficiency and sustainability of recycling industry. As food waste is the main composition of MSW in China, 20%–30% of the food waste diversion and land application could maximize the comprehensive environmental performance. Incineration is to be the pillar technology in MSW separated treatment system in China.