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21.
电导滴定法快速测定不同水中硫酸根的含量 总被引:3,自引:0,他引:3
采用电导法,用氯化钡标准溶液滴定水样中硫酸根的含量对测定结果的影响因素进行了探讨,本方法测定的回收率在98 ̄102%之间,装置简单,试样测定时间仅需几分钟,准确度较高,适用范围广,如海水,卤水,自来水、深井水、雨水和部分工业废水等硫酸根含量的测定。 相似文献
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石灰—硫酸亚铁法处理高浓度砷和氟酸性废水试验研究 总被引:7,自引:0,他引:7
采用二级石灰-硫酸亚铁法处理砷和氟浓度分别高达110mg/L和650mg/L以上的酸性废水。当一、二级控制条件分别为pH9.5和9.0、Fe/As比为2.5和15时,一级砷和氟去除率分别可达99.5%和94%,二级出口砷和氟残余浓度分别可低至0.1mg/L和13.8mg/L,Cu、Zn和Pb等重金属离子均达检不出水平。 相似文献
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Mineral dust particles play an important role in the formation of secondary inorganic aerosols, which largely contribute to haze pollution in China.During this study, a haze episode(haze days) and a typical haze process mixed with sandstorm(sandy haze days)were observed in Zhengzhou with a series of high-time-resolution monitoring instruments from November 22 to December 8, 2018.Concentrations of PM_(10) and crustal elements clearly increased in the sandy haze days.Concentrations of gaseous pollutants, metallic elements emitted from anthropogenic sources, nitrate, and ammonium during sandy haze days were slightly lower than those during the haze days but still obviously higher than those during the non-haze days.The sulfate concentrations, the sulfate fractions in PM_(2.5),and the sulfur oxidation ratios significantly increased in the sandy haze days.Heterogeneous reactions dominated the conversion of SO_2 during the haze and sandy haze days.Enhanced SO_2 conversion during the sandy haze days may be attributed to the high concentrations of transition metal ions from the sandstorm when the values of relative humidity(RH) were in 30%–70%, and high O_3 at certain time points.Gas-phase NO_2 oxidation reactions were the main pathways for nitrate formation.In the sandy haze days,higher nitrogen oxidation ratio(NOR) at daytime may be associated with higher RH and lower temperature than those in the haze days, which facilitate the gas-to-particle partitioning of nitrate; higher NOR values at night may be attributed to the higher O_3 concentrations, which promoted the formation of N_2O_5. 相似文献
26.
Permeable reactive barriers (PRBs) are an alternative technology to treat mine drainage containing sulfate and heavy metals. Two column experiments were conducted to assess the suitability of an organic carbon (OC) based reactive mixture and an Fe0-bearing organic carbon (FeOC) based reactive mixture, under controlled groundwater flow conditions. The organic carbon mixture contains about 30% (volume) organic carbon (composted leaf mulch) and 70% (volume) sand and gravel. The Fe0-bearing organic carbon mixture contains 10% (volume) zero-valent iron, 20% (volume) organic carbon, 10% (volume) limestone, and 60% (volume) sand and gravel. Simulated groundwater containing 380 ppm sulfate, 5 ppm As, and 0.5 ppm Sb was passed through the columns at flow rates of 64 (the OC column) and 62 (the FeOC column) ml d− 1, which are equivalent to 0.79 (the OC column) and 0.78 (the FeOC column) pore volumes (PVs) per week or 0.046 m d− 1 for both columns. The OC column showed an initial sulfate reduction rate of 0.4 µmol g (OC)− 1 d− 1 and exhausted its capacity to promote sulfate reduction after 30 PVs, or 9 months of flow. The FeOC column sustained a relatively constant sulfate reduction rate of 0.9 µmol g (OC)− 1 d− 1 for at least 65 PVs (17 months). In the FeOC column, the δ34S values increase with the decreasing sulfate concentration. The δ34S fractionation follows a Rayleigh fractionation model with an enrichment factor of 21.6‰. The performance decline of the OC column was caused by the depletion of substrate or electron donor. The cathodic production of H2 by anaerobic corrosion of Fe probably sustained a higher level of SRB activity in the FeOC column. These results suggest that zero-valent iron can be used to provide an electron donor in sulfate reducing PRBs. A sharp increase in the δ13C value of the dissolved inorganic carbon and a decrease in the concentration of HCO3− indicate that hydrogenotrophic methanogenesis is occurring in the first 15 cm of the FeOC column. 相似文献
27.
TUNLAWIT SATAPANAJARU PATANA ANURAKPONGSATORN PATTHRA PENGTHAMKEERATI 《Journal of environmental science and health. Part. B》2013,48(8):1291-1303
The objective of this study was to quantify the effectiveness of different pretreated iron byproducts from the automotive industry to degrade DDT [(1,1,1-trichloro-2,2-bis(4-chlorophenyl) ethane] in aqueous solutions and soil slurry. Iron byproducts from automotive manufacturing were pretreated by three different methods (heating, solvent and 0.5N HCl acid washing) prior to experimentation. All pretreated irons were used at 5% (wt v? 1) to treat 0.014 mM (5 mgL? 1) of DDT in aqueous solution. Among the pretreated irons, acid pretreated iron results in the fastest destruction rates, with a pseudo first-order degradation rate of 0.364 d? 1. By lowering the pH of the DDT aqueous solution from 9 to 3, destruction kinetic rates increase more than 20%. In addition, when DDT-contaminated soil slurry (3.54 mg kg? 1) was incubated with 5% (wt v? 1) acid-pretreated iron, more than 90% destruction of DDT was observed within 8 weeks. Moreover, DDT destruction kinetics were enhanced when Fe(II), Fe(III) or Al(III) sulfate salts were added to the soil slurry, with the following order of destruction kinetics: Al(III) sulfate > Fe(III) sulfate > Fe(II) sulfate. These results provide proof-of concept that inexpensive iron byproducts of the automotive industry can be used to remediate DDT-contaminated water and soil. 相似文献
28.
A novel coupled system using Co–Ti O2 was successfully designed which combined two different heterogeneous advanced oxidation processes, sulfate radical based Fenton-like reaction(SR-Fenton) and visible light photocatalysis(Vis-Photo), for degradation of organic contaminants. The synergistic effect of SR-Fenton and Vis-Photo was observed through comparative tests of 50 mg/L Rhodamine B(Rh B) degradation and TOC removal. The Rhodamine B degradation rate and TOC removal were 100% and 68.1% using the SR-Fenton/Vis-Photo combined process under ambient conditions, respectively. Moreover, based on XRD, XPS and UV-DRS characterization, it can be deduced that tricobalt tetroxide located on the surface of the catalyst is the SR-Fenton active site, and cobalt ion implanted in the Ti O2 lattice is the reason for the visible light photocatalytic activity of Co–Ti O2. Finally, the effects of the calcination temperature and cobalt concentration on the synergistic performance were also investigated and a possible mechanism for the synergistic system was proposed. This coupled system exhibited excellent catalytic stability and reusability,and almost no dissolution of Co2+was found. 相似文献
29.
Natural attenuation of contaminants in groundwater depends on an adequate supply of electron acceptors to stimulate biodegradation. In an alluvial aquifer contaminated with leachate from an unlined municipal landfill, the mechanism of recharge infiltration was investigated as a source of electron acceptors. Water samples were collected monthly at closely spaced intervals in the top 2 m of the saturated zone from a leachate-contaminated well and an uncontaminated well, and analyzed for delta(18)O, delta(2)H, non-volatile dissolved organic carbon (NVDOC), SO(4)(2-), NO(3)(-) and Cl(-). Monthly recharge amounts were quantified using the offset of the delta(18)O or delta(2)H from the local meteoric water line as a parameter to distinguish water types, as evaporation and methanogenesis caused isotopic enrichment in waters from different sources. Presence of dissolved SO(4)(2-) in the top 1 to 2 m of the saturated zone was associated with recharge; SO(4)(2-) averaged 2.2 mM, with maximum concentrations of 15 mM. Nitrate was observed near the water table at the contaminated site at concentrations up to 4.6 mM. Temporal monitoring of delta(2)H and SO(4)(2-) showed that vertical transport of recharge carried SO(4)(2-) to depths up to 1.75 m below the water table, supplying an additional electron acceptor to the predominantly methanogenic leachate plume. Measurements of delta(34)S in SO(4)(2-) indicated both SO(4)(2-) reduction and sulfide oxidation were occurring in the aquifer. Depth-integrated net SO(4)(2-) reduction rates, calculated using the natural Cl(-) gradient as a conservative tracer, ranged from 7.5x10(-3) to 0.61 mM.d(-1) (over various depth intervals from 0.45 to 1.75 m). Sulfate reduction occurred at both the contaminated and uncontaminated sites; however, median SO(4)(2-) reduction rates were higher at the contaminated site. Although estimated SO(4)(2-) reduction rates are relatively high, significant decreases in NVDOC were not observed at the contaminated site. Organic compounds more labile than the leachate NVDOC may be present in the root zone, and SO(4)(2-) reduction may be coupled to methane oxidation. The results show that sulfur (and possibly nitrogen) redox processes within the top 2 m of the aquifer are directly related to recharge timing and seasonal water level changes in the aquifer. The results suggest that SO(4)(2-) reduction associated with the infiltration of recharge may be a significant factor affecting natural attenuation of contaminants in alluvial aquifers. 相似文献
30.
George R. Holdren Jr. Timothy C. Strickland Bernard J. Cosby David Marmorek David Bernard Robert Santore Charles T. Driscoll Linda Pardo Carolyn Hunsaker Robert S. Turner John Aber 《Environmental management》1993,17(3):355-363
The critical loads approach is emerging as an attractive means for evaluating the effects of atmospheric deposition on sensitive
terrestrial and aquatic ecosystems. Various approaches are available for modeling ecosystem responses to deposition and for
estimating critical load values. These approaches include empirical and statistical relationships, steady-state and simple
process models, and integrated-effects models. For any given ecosystem, the most technically sophisticated approach will not
necessarily be the most appropriate for all applications; identification of the most useful approach depends upon the degree
of accuracy needed and upon data and computational requirements, biogeochemical processes being modeled, approaches used for
representing model results on regional bases, and desired degree of spatial and temporal resolution. Different approaches
are characterized by different levels of uncertainty. If the limitations of individual approaches are known, the user can
determine whether an approach provides a reasonable basis for decision making. Several options, including point maps, grid
maps, and ecoregional maps, are available for presenting model results in a regional context. These are discussed using hypothetical
examples for choosing populations and damage limits.
The research described in this article has been funded by the US Environmental Protection Agency. This document has been prepared
at the EPA Environmental Research Laboratory in Corvallis, Oregon, through contract #68-C8-0006 with ManTech Environmental
Technology, Inc., and Interagency Agreement #1824-B014-A7 with the U.S. Department of Energy and at Oak Ridge National Laboratory
managed by Martin Marietta Energy Systems, Inc., under Contract DE-AC05-84OR21400 with the US Department of Energy. Environmental
Sciences Division Publication No. 3904. It has been subjected to the agency’s peer and administrative review and approved
for publication. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. 相似文献