土壤中短链氯化石蜡的气相色谱-电子捕获负化学电离-质谱分析方法

通过考察层析柱对测定短链氯化石蜡(SCCPs)干扰物去除效果的影响,结合实际土壤样品的净化需求,建立了一套适合分析土壤中SCCPs的前处理方法.土壤样品使用索氏抽提,采用硅胶复合柱和弗罗里硅土柱净化,运用气相色谱-质谱(ECNI源)检测SCCPs.SCCPs的仪器定量限为100—600 pg.μL-1.空白加标和基质加标中SCCPs的回收率分别为130%±8.50%和108%±17.8%(SD,n=3).利用该方法分析了采自广州市郊区的6个土壤样品,其SCCPs的含量范围为12.9—34.5 ng.g-1,平均值为26.1 ng.g-1.     

基于HCNAM-BN的化工过程爆炸事故致因链分析

为了从源头上预防化工过程爆炸事故,依据风险耦合理论,探讨了各风险因子非线性耦合演化为爆炸事故的机理,构建了层次耦合网络分析模型（HCNAM）;从多因素风险耦合角度分析了国内外44起典型化工过程爆炸事故,统计了各风险因子之间的耦合概率并进行了耦合致因重要度分级;采用耦合概率与二态分布相结合的条件概率分布,将层次耦合网络分析模型转化为贝叶斯网络,并对氯乙烯单体槽爆炸性混合气体爆炸事故进行了应用研究。结果表明:91种双因子耦合风险状态中,47种呈现弱耦合致因特性;7种因子双耦合形成风险的概率较大;基于HCNAM-BN模型分析事故,可有效辨识事故最可能致因因素,获取各事故致因链的发生概率并确定事故网络关键节点。     

钢铁企业含锌尘泥资源化利用途径分析评价

通过分析锌元素进入钢铁制造流程的渠道,明确了钢铁企业含锌尘泥的来源与循环路径。根据含锌尘泥的循环途径,综合分析比较国内外含锌尘泥的不同利用方式和工艺——改变循环路径、物理选矿法、火法工艺以及湿法工艺。本着钢铁工业与锌冶炼之间形成工业化生态链的思路,提出了钢铁企业含锌尘泥的处理原则和资源化利用模式。     

全氟化合物的生物富集效应研究进展

研究污染物的生物富集效应,对于预测污染物在生物体内的含量、建立环境标准以及评估污染物的生态风险具有重要的意义。结合近年来国内外报道的有关全氟化合物（PFCs）的生物浓缩因子（BCF）、生物富集因子（BAF）、生物放大因子（BMF）和营养级放大因子（TMF）等参数,对PFCs的生物富集效应及其影响因素进行了综述。研究结果表明,氟代碳原子数高于7的PFCs一般在生物体或食物链（网）上具有生物富集效应,而氟代碳原子数低于7的PFCs的生物富集效应较低。PFCs的理化性质（碳链长度、碳链末端基团类型和是否含有支链等）、生物的种类及其生理生化参数（体长、体重和性别等）和环境条件（生态系统的组成、水温和污染物含量等）等都影响PFCs在生物体内或食物链（网）上的富集。综观当前研究成果,PFCs在食物链（网）上生物放大效应研究主要集中于极地地区海洋食物网,应加强其他区域（特别是典型污染区域）、各种类型食物网（如淡水食物网和陆生食物网）上PFCs的生物富集效应及其影响因素研究,为全面评估PFCs的生态风险提供基础数据。     

宜兴煤矿安全经济护巷煤柱宽度的研究确定

为节省资源,留最窄护巷煤柱,在借用FLAC3D模拟软件掌握不同护巷煤柱宽度下巷道围岩应力应变后,结合模拟的结果和实验室试验新材料GRT-201加固后的煤岩体强度指标,最终确定煤柱留设宽度为2m,较正常煤柱宽度留设减小了20多米.现场操作后巷道的变形率控制在5％以内,大大降低留设煤柱宽度的同时保证了工作面的正常接替和安全回采.     

Role of behavioural factors in green supply chain management implementation in Indian mining industries

Green supply chain management (GSCM) integrates ecological concepts with those of supply chain management in order to minimize energy and material usage and to reduce adverse impacts of supply chain activities on the environment. GSCM implementation in mining industries depends largely upon certain factors which are influenced by human behaviours. Human behaviour is dynamic in nature and the relationships between them continuously evolve and change. In this ever-changing context, therefore, identifying and ranking the behavioural factors that affect GSCM implementation becomes essential. This can be taken as a reference by the decision makers while deciding the hierarchy of action necessary for effective implementation of green practices in mining supply chains. The present research attempts to explore various behavioural factors affecting GCSM practices and their interactions which help to attain green-enabled needs. Interpretive structural modelling (ISM) is employed in this research to extract the interrelationships among the identified behavioural factors.     

Corporate environmental responsibility in the supply chain

A continuing trend in outsourcing increases the complexity of supply chains. Global supply chains extend over numerous echelons of countless companies. In parallel, the company-internal view on corporate environmental responsibility is being challenged as customers and legislation alike broaden a company's environmental responsibility to include organisations' upstream as well as downstream in the supply chain. Therefore, the aim of this study was to examine corporate environmental responsibility beyond corporate boundaries, i.e. in the supply chain. A cross-industrial study based on 16 case studies in Finnish trans-national corporations sheds light on various dimensions of corporate environmental responsibility upstream and downstream of product and process supply chains. Conclusions were drawn for corporate environmental responsibility as well as for the role of supply chain management in extending environmental demand over several echelons and diverse industries.     

Linking supply chain strength to sustainable development: a country-level analysis

Several global corporations have been severely criticized by different lobbying groups for the impact of their operations on the natural environment and on the local communities. Because corporate operations cannot be studied in isolation but rather as a part of a large network often referred to as a supply chain, this paper investigates the potential link between supply chain characteristics and sustainable development at the country level. In particular, the linkage between supply chain strength, generally defined as the number and quality of the suppliers and customers in a country, and the three dimensions of sustainable development namely environmental performance, corporate environmental practices, and social sustainability is assessed. Using archival data from The Global Competitiveness Report (2004–2005) and the 2005 Environmental Sustainability Index, a statistical assessment of the linkage was conducted. The results indicate that supply chain strength is positively linked to all three dimensions of sustainable development.     

Does copper reduce cadmium uptake by different rice genotypes？

A hydroponics experiment was conducted to investigate the effect of copper （Cu） on cadmium （Cd）, calcium （Ca）, iron （Fe）, and zinc （Zn） uptake by several rice genotypes. The experiment was carried out as a 2×2×4 factorial with four rice genotypes and two levels of Cu and Cd in nutrient solution. Plants were grown in a growth chamber with controlled environment. The results showed a significant difference between the biomass of different rice genotypes （P 〈 0.001）. The Cd and Cu concentration in the solution had no significant effect on the biomass. The addition of Cu significantly decreased Cd uptake by shoots and roots of rice （P 〈 0.001）. The Cd concentration did not significantly influence Ca uptake by plants, whereas the Cu concentration did （P = 0.034）. There was a significant influence of Cd on Fe uptake by shoots and roots （P 〈 0.001, P = 0.003, respectively）. Zn uptake decreased significantly as the addition of Cd and Cu increased in shoots. We concluded that Cu had significant influence on Cd uptake. The possible mechanisms were discussed.     

城市间空气污染控制的马氏链模型

根据城市间空气污染物相互扩散和无后效性的特点,应用马尔可夫随机过程理论,先建立各城市污染物浓度状态转移方程,再由城市间污染物浓度状态形成一个吸收链。建立城市间污染物排放控制的马氏链模型。通过模型求解,得出了城市间空气污染物浓度达到国家排放标准的条件,最后应用数值计算软件MAT-LAB,编写了一个城市间空气污染控制的通用程序,它能在保证城市空气质量的前提下,快速准确地计算出控制区内各污染源污染物的最大允许排放量,这对环保部门进行城市空气污染物排放量控制工作具有实际意义。