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271.
本文介绍了超临界直流电站锅炉检验中发现的水冷壁开裂、变形,调风器鳍片烧损变形,集箱管接头角焊缝裂纹,刚性梁固定耳板处拉裂、变形等问题。对产生这些问题的原因进行了分析和研究,认为各水冷壁管子内水汽温度不均匀是造成拉裂、变形的主要原因。针对产生问题的原因,提出要预防此类问题发生就必须控制水冷壁超温和降低水冷壁各管子间温度差。并详细地论述了控制水冷壁超温和降低水冷壁各管子间温度差的八项具体改进措施。 相似文献
272.
本文笔者根据积累的经验,并结合具体案例,分析了三类承压部件(锅炉水冷壁、汽水管道、联箱角焊缝)因膨胀不畅引发的失效特征和原因,并提出了相应的防范和整改措施。对火力发电厂承压部件防止膨胀拉裂引起的失效有一定的参考和借鉴意义。 相似文献
273.
Gaoyang Cui Xiao-Dong Li Siqi Li Shiyuan Ding Qinkai Li Mengdi Yang Hong Lv Yiyao Wang 《环境科学学报(英文版)》2022,34(1):208-219
Reservoirs are regarded as hotspots of nitrogen transformation and potential sources of nitrous oxide(N2O). However, it remains unclear how the hydrological conditions due to dam construction control the processes of nitrogen transformation in reservoir waters. To address this issue, we examined the spatial-temporal characteristics of nitrate concentrations, δ15N-NO3-, δ18O-NO3-, δ18O-H2O, relative... 相似文献
274.
275.
热污染的危害及管理建议 总被引:4,自引:0,他引:4
首先对热污染危害进行分析,其次对相关标准进行了研究,针对标准中存在的问题,提出了进一步丰富标准内容的建议。 相似文献
276.
Christiane D. Vitzthum von Eckstaedt Marisa Ioppolo-ArmaniosDavid Kelly Mark Gibberd 《Chemosphere》2012,89(11):1407-1413
This study presents carbon (δ13C) and hydrogen (δD) isotope values of volatile organic compounds (VOCs) in various emission sources using thermal desorption-gas chromatography-isotope ratio mass spectrometry (TD-GC-irMS). The investigated VOCs ranged from C6 to C10. Samples were taken from (i) car exhaust emissions as well as from plant combustion experiments of (ii) various C3 and (iii) various C4 plants. We found significant differences in δ values of analysed VOCs between these sources, e.g. δ13C of benzene ranged between (i) −21.7 ± 0.2‰, (ii) −27.6 ± 1.6‰ and (iii) −16.3 ± 2.2‰, respectively and δD of benzene ranged between (i) −73 ± 13‰, (ii) −111 ± 10‰ and (iii) −70 ± 24‰, respectively. Results of VOCs present in investigated emission sources were compared to values from the literature (aluminium refinery emission). All source groups could be clearly distinguished using the dual approach of δ13C and δD analysis. The results of this study indicate that the correlation of compound specific carbon and hydrogen isotope analysis provides the potential for future research to trace the fate and to determine the origin of VOCs in the atmosphere using thermal desorption compound specific isotope analysis. 相似文献
277.
Vinay K. Khatiwala Nilanshu Shekhar Saroj Aggarwal U. K. Mandal 《Journal of Polymers and the Environment》2008,16(1):61-67
The biodegradation behavior of PCL film with high molecular weight (80,000 Da) in presence of bacterium Alcaligenes faecalis and the analysis of degraded polymer film have been carried out. Thin Films of PCL were prepared by means of solution casting
method and the bacterial degradation behavior was carried in basal medium, in presence of bacteria with time variation after
UV treatment. It was observed that after UV treatment the degradation of polymer film was increased and the degradation rate
followed a three steps degradation mechanism. The degraded polymer film was analyzed by means of Differential Scanning Calorimeter
(DSC), Thermo Gravimetric Analyzer (TGA) and Fourier Transform Infrared Spectroscope (FTIR). DSC results revealed that at
the initial stages of the degradation up to 15–20 days, the bacterium preferentially degrades the amorphous parts of the polymer
film over the crystalline zone. Thermo gravimetric analysis highlighted the low temperature stability of degraded films with
extent of degradation. FTIR results showed the chain scission mechanism of the polymer chains and also supported the preferential
degradation of amorphous phase over crystalline phase in the initial stages of the degradation. 相似文献
278.
为全面、客观掌握工业生产热排放对大气污染的影响,利用遥感手段分析了2018—2019年秋冬季京津冀工业生产热排放及其同比变化。结果显示:2018—2019年秋冬季,京津冀地区工业热异常点数量及秋冬热异常点辐射功率(FRP秋冬)较上年同期明显增加,工业生产活动规模及强度同比有所扩大,区域PM2. 5浓度呈增长趋势。根据FRP秋冬分布特点可将京津冀工业生产分为3类,密集型、分散型和稀少型。工业生产密集型城市FRP秋冬通常 1 500 MW,较为典型的城市如唐山、邯郸,FRP秋冬可达2 000 MW以上甚至上万MW,这些城市的空气质量也相对较差;保定是工业生产分散型城市,该城市热异常点增长显著,FRP秋冬也可达2 000 MW以上,但空间分布分散;工业生产稀少型城市热异常点较少且空气质量相对较好。 相似文献
279.
Henry’s law constants for 12 chlorinated volatile organic compounds (CVOCs) were measured as a function of temperature ranging from 8 to 93 °C, using the modified equilibrium partitioning in closed system (EPICS) method. The chlorinated compounds include tetrachloroethylene, trichloroethylene, cis-1,2-dichloroethylene, vinyl chloride, 1,1,1-trichloroethane, 1,1-dichloroethane, 1,2-dichloroethane, chloroethane, carbon tetrachloride, chloroform, dichloromethane, and chloromethane. The variation in Henry’s constants for these compounds as a function of temperature ranged from around 3-fold (chloroethane) to 30-fold (1,2-dichloroethane). Aqueous solubilities of the pure compounds were measured over the temperature range of 8-75 °C. The temperature dependence of Henry’s constant was predicted using the ratio of pure vapor pressure to aqueous solubility, both of which are functions of temperature. The calculated Henry’s constants are in a reasonable agreement with the measured results. With the improved data on Henry’s law constants at high temperatures measured in this study, it will be possible to more accurately model subsurface remediation processes that operate near the boiling point of water. 相似文献
280.
本文探索了一种适用于DB 50/577-2015附录C、DB 50/660-2016附录B、DB 50/757-2017附录B、DB 50/758-2017附录C等检测技术导则的气质联用检测方法,能够满足简单、快速、灵敏度高、检出限低等要求。 相似文献