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351.
352.
Shin-ichi Sakai Yukio Noma Akiko Kida 《Journal of Material Cycles and Waste Management》2007,9(2):151-158
The Japanese Government introduced the Law on Recycling of End-of-Life Vehicles (ELV Recycling Law) in 2002. This law requires
manufacturers to retrieve chlorofluorocarbons (CFCs), airbags, and automobile shredder residue (ASR) from ELVs and to properly
recycle the remaining materials. This framework is compared with European ELV directives. Pilot-scale incineration plant testing
has revealed a greater formation of by-product persistent organic pollutants (POPs) during the primary combustion of ASR compared
to normal municipal solid waste. This may be attributed to the abundance of chlorine, Cu, and Fe in ASR, as Cu and Fe have
been found to catalyze the formation of POPs under certain conditions. However, most by-product POPs were destroyed by the
secondary combustion, and almost all were removed after flue gas treatment. The direct melting system is a shaft-type gasification
and melting technology that has proved effective in many municipal solid waste applications. This system can be applied to
ASR recycling for effective decomposition of brominated flame retardants and polybrominated dioxins. 相似文献
353.
354.
N. L. Panwar A. K. Kurchania N. S. Rathore 《Mitigation and Adaptation Strategies for Global Change》2009,14(6):569-578
Greenhouse gases especially CO2 can be reduced with the help of improved biomass cookstoves. This paper deals with the design and development of biomass
stoves (single pot and double pot) with better efficiency for meeting household cooking energy requirement. Thermal performance,
flue gas emission of carbon monoxide (CO) and carbon dioxide (CO2) have been investigated. It was seen from the result that the flue gas emission is within permissible limit as recommended
by World Health Organization. The design of improved biomass stove sent to Palampur (32o10’N,76o30’E) center situated in Himalaya in hilly terrain of India, where the acceptability of double pot stoves (85%) is quite high
compared to single pot stoves (30%). Thermal efficiencies of both single and double pot stove were recorded about 21% and
25% respectively. An improved biomass cookstove can save about 161 kg of CO2 annually. Improved cookstoves was found eco-friendly in nature and suitable for the cooking requirement of hilly areas. 相似文献
355.
对热脱附-气相色谱测定苯系物方法中的几种常用吸附剂进行了选择比较。结果表明,在测定苯、甲苯、乙苯、二甲苯以及苯乙烯时,TenaxTA/Carbograph1TD复合型吸附剂的综合吸附效率最好。TenaxTA/Carbograph1TD复合型吸附剂的检出限、精密度、准确度和保存期都得到了良好的结果,能够满足监测分析的要求。 相似文献
356.
Application of a three-dimensional eutrophication model for the Beijing Guanting Reservoir, China 总被引:1,自引:0,他引:1
The Beijing Guanting Reservoir (BGR) is located northwest of Beijing and has been an important water supply reservoir ever since the construction of a dam near the town of Guanting in 1954. As a result of excessive nutrients and organic carbon loadings from the drainage basin over the last several decades, the BGR suffers from eutrophication as well as other contamination problems and has not been used as a drinking water supply reservoir since 1997. As a management step to restore the reservoir's water quality, a numerical model was developed based on the environmental fluid dynamics code (EFDC) framework. The model simulated three phytoplankton species based on the observed cyanobacteria, green algae, and diatom concentrations in 2004 for the Yongding arm of the reservoir, which is separated from the rest of the reservoir by a sand bar. The model was calibrated with vertical temperature profiles as well as the observed chlorophyll a and nutrients concentrations in the water column. The calibrated model was further applied to investigate management scenarios, which include reduction in external loadings of nutrients with constructed wetlands, biomanipulation, and transferring water from CeTian Reservoir. All three scenarios can reduce the peak chlorophyll a levels in the reservoir. The background nutrients were high, and reducing the external nutrients was effective only after a reduction in background nutrients after phytoplankton growth. The biomanipulation and water transfer scenarios could also delay the occurrence of the peak chlorophyll a. Because the model was developed based on one year of data, the model can only reveal the short-term effects of applying the management scenarios. Future studies will consider the long-term processes, such as diagenesis, when data are available to predict the long-term effects of the scenarios. 相似文献
357.
以脱水污泥为原料,分别采用恒温热干化和微波干化2种不同的方法考察脱水污泥的干化情况;对不同干化阶段的污泥进行显微观察,分析干化过程;并对2种干化过程的机理进行了探讨。实验结果表明随着加热温度的升高,污泥中水分脱除速度加快。加热温度低于100℃时,在120 min以内,热干化无法达到较高的脱水率。加热温度在140℃以上,加热时间120 min时,脱水污泥的脱水率可达到98.26%。微波干化法在功率为500~900 W,5~10 min内可使脱水污泥的脱水率到达99.20%以上。机理分析表明热干化传质与传热方向相反,微传热和传质的方向相同,因此微波干化具有更快速、高效的特点。 相似文献
358.
Philippe Gillard Baptiste Longuet 《Journal of Loss Prevention in the Process Industries》2013,26(6):1506-1514
In this work, a new modelling of interactions between components of aluminium/ammonium perchlorate/HTPB propellant during slow heating is presented. The phenomenon was previously described by experimental approaches performed in the laboratory. Heat and mass balance will be considered both in the solid and gas phases. The interaction of the decomposition products of both ammonium perchlorate and HTPB binder is shown thanks to previous experiments and a specific numerical model allows us to reproduce this trend. Mass and heat transfers are taken into account in each particle of ammonium perchlorate and inside the matrix of the HTPB binder. The chemical reaction in the gas phase is in interaction with the adsorption desorption of several species with regard to the surface grains. The whole set of equations is solved thanks to Comsol multiphysic solver and the numerical results are compared with mass loss measurements by means of a thermogravimetric device. 相似文献
359.
In this paper, we have proposed a thermal cycle with the integration of chemical-looping combustion and solar thermal energy with the temperature of about 500-600°C. Chemical-looping combustion may be carried out in two successive reactions between a reduction of hydrocarbon fuel with metal oxides and a reduced metal with oxygen in the air. This loop of chemical reactions is substituted for conventional combustion of fuel. Methane as a fuel and nickel oxides as an oxygen carrier were employed in this cycle. Collected high-temperature solar thermal energy is provided for the endothermic reduction reaction. The feature of the proposed cycle is investigated through Energy-Utilization Diagram methodology. As a result, at the turbine inlet temperature of 1200°C, the exergy efficiency of the proposed cycle would be expected to be about 4 percentage points higher than that of a conventional gas turbine combined cycle. Compared to the previous study of chemical-looping combustion energy systems, the proposed cycle with the integration of green energy and traditional hydrocarbon fuels will offer the possibility of both greenhouse gas mitigation, with green energy, and a new approach to the efficient use of solar energy. 相似文献
360.
Thermal safety and risk of accidents are still challenging topics in the case of batch reactors carrying exothermic reactions. In the present paper, the authors develop an integrated framework focusing on defining the governing parameters for the thermal runaway and evaluating the subsequent risk of accident. A relevant set of criteria are identified in order to find the prior conditions for a thermal runaway: failure of the cooling system, critical temperature threshold, successive derivatives of the temperature (first and second namely) vs. time and no detection in due time (reaction time) of the runaway initiation. For illustrative purposes, the synthesis of peracetic acid (PAA) with hydrogen peroxide (HP) and acetic acid (AA) is considered as case study. The critical and threshold values for the runaway accident are identified for selected sets of input data. Under the conditional probability of prior cooling system failure, Monte Carlo simulations are performed in order to estimate the risk of thermal runaway accident in batch reactors. It becomes then possible to predict the ratio of reactors, within an industrial plant, potentially subject to thermal runaway accident. 相似文献