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41.
膨润土与PAM联用处理含重金属离子废水 总被引:10,自引:1,他引:10
本文以酸性膨润土与PAM联用处理含重金属离子废水,探讨了去除Cu^2+、Zn^2+、Ni^2+的适宜条件。处理实际废水,达到国家排放标准。 相似文献
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Katrin Wendt-Potthoff René Frömmichen Peter Herzsprung Matthias Koschorreck 《Water, Air, & Soil Pollution: Focus》2002,2(3):81-96
To elucidate the role of Fe(III) reduction in mining lake sediments amended with organic substrates, we performed a large (10 m diameter) enclosure experiment in which sediments were amended with Carbokalk, a waste product from sugar industry containing organic carbon and lime. Fe(III) reduction rates were determined monthly by measuring the accumulation of Fe(II) in the sediments in the field. Fe(III) reduction rates were also determined by incubating sediment samples with synthetic Fe(III) oxyhydroxide under in situ temperature in the laboratory. Sulfate reduction was selectively inhibited in the Fe(III) reduction experiments by addition of sodium molybdate. Sulfate reduction was measured by accumulation of reduced inorganic sulfides in the field and by 35S radiotracer using a core injection technique. Sediment incubation and determination of sulfate reduction rates with radiotracer showed that sulfate reduction and direct microbial Fe(III) reduction occured simultaneously in the upper centimeters of the sediments and that both processes contributed to alkalinity generation. However, Fe(III) reduction was the initial process and rates were at least 3.5 fold higher than sulfate reduction rates. The results indicate that the presence of suitable anions for Fe(II) precipitation as carbonate or sulfide is needed in order to prevent loss of potential alkalinity by Fe(II) diffusion and reoxidation in the water column. 相似文献
43.
膜电解法从模拟酸性蚀刻废液中回收铜粉 总被引:1,自引:0,他引:1
酸性蚀刻废液是一种印制电路板制作过程中产生的强酸、高铜的工业废水,对其回收利用具有较高的经济价值。采用膜电解法处理模拟酸性蚀刻废液,在阴极区回收铜粉。研究了铜粉的形成条件,考察了阴极液铜浓度、温度和电流密度对阴极电流效率的影响。结果表明,阴极液的铜浓度在20~25 g/L,温度为45~50℃,电流密度在11~12 A/dm2,阴极的电流效率最高。随着阴极液酸度的增加,铜粉的纯度提高,但阴极电效会降低。为保证较高的铜粉纯度及阴极电效,阴极液的酸度在0.32~0.36 mol/L为宜。 相似文献
44.
以马尾松为指示植物,对韶关的土壤进行了长期淋溶模拟并记录其化学状态。结果发现,土壤溶液的pH值下降到4.0,Bs值下降到几乎为零,有较大量的A1离子溶出。最后选取土壤溶液pn〉4.0、KS〉10%和[Al^3+]〈0.1mmol/L为临界化学指标,参考国内外应用广泛的MAGIC模型和SMART模型,确定韶关酸沉降临界负荷(S的临界负荷)为14.1keq/hm^2.a。 相似文献
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Xiuzhen Hao Dongmei Zhou Deqian Huang Hailin Zhang Yujun Wang 《Journal of environmental science and health. Part. B》2013,48(8):905-912
In a pot experiment, pig manure (PM) and chicken manure (CM) were applied to an acidic soil at application rates of 2%, 4% and 8% (W/W) to evaluate their effects on the growth, Cu and Zn uptake and transfer of five cultivars of pakchoi (Brassica chinesis L.). The results showed that alkaline manures significantly increased the biomass of pakchois, and also pH and electrical conductivity of the soil. Both 0.01 M CaCl2 and 1.0 M NH4NO3 salt solutions predict the Zn transfer from soil to pakchois well, but not for Cu. For the cultivar Siyueman, the transfer factors of Cu (or Zn) in the PM treatments were higher than that in the CM treatments. In our experiment the Cu and Zn concentrations in pakchois did not exceed the Chinese Food Hygiene Standard, but more attention should be paid to heavy metals risk on pakchois at lower soil pH and salt impairment by manures application. 相似文献
47.
Renyong Shi Jiuyu Li Jun Jiang Khalid Mehmoo Yuan Liu Renkou Xu Wei Qian 《环境科学学报(英文版)》2017,29(5):294-302
The chemical characteristics, element contents, mineral compositions, and the ameliorative effects on acid soils of five biomass ashes from different materials were analyzed. The chemical properties of the ashes varied depending on the source biomass material. An increase in the concrete shuttering contents in the biomass materials led to higher alkalinity, and higher Ca and Mg levels in biomass ashes, which made them particularly good at ameliorating effects on soil acidity. However, heavy metal contents, such as Cr, Cu, and Zn in the ashes, were relatively high. The incorporation of all ashes increased soil pH, exchangeable base cations, and available phosphorus, but decreased soil exchangeable acidity. The application of the ashes from biomass materials with a high concrete shuttering content increased the soil available heavy metal contents. Therefore, the biomass ashes from wood and crop residues with low concrete contents were the better acid soil amendments. 相似文献
48.
T J. Sullivan D. L. Kugler M. J. Small C. B. Johnson D. H. Landers B. J. Rosenbaum W.S. Overton W. A. Kretser J. Gallagher 《Journal of the American Water Resources Association》1990,26(1):167-176
ABSTRACT: Data from a recent survey conducted by the Adirondack Lake Survey Corporation were used to evaluate the influence of lake surface area on the acid-base status of lakes in Adirondack State Park, New York. Acid neutralizing capacity (ANC) in the small lakes (< 4 ha) occurred more frequently at extreme values (> 200, < 0 μeq L?1), whereas larger lakes tended to be intermediate in ANC. Consequently, acidic (ANC ≤ 0) and low-pH lakes were typically small. The small lakes also exhibited lower Ca2+ concentration and higher dissolved organic carbon than did larger lakes. Lakes ≥ 4 ha were only half as likely to be acidic as were lakes ≥ 1 ha in area. These data illustrate the dependence of lake chemistry on lake surface area and the importance of the lower lake area limit for a statistical survey of lake water chemistry. 相似文献
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