石墨气体扩散电极的制备与性能优化

电极的制备工艺及参数直接影响电极材料的活性。主要考察了C/PTFE质量比、碾压压力、煅烧温度、造孔剂NH4HCO3及稀土掺杂等因素对电极产出H2O2的影响规律。研究结果表明,电极最佳制备条件为:石墨和PTFE质量比为2∶1、石墨、造孔剂和稀土元素质量比为6∶1∶1、碾压压力10 MPa、煅烧温度330℃。在pH=3、电解质Na2SO4浓度为0.05mol/L条件下,电解2 h后,改性电极产生的H2O2从95 mg/L提高到350 mg/L,提高了268.4%。     

直接投菌法在城市重污染河流治理中的应用研究

在无截污和清除内源的情况下,对深圳市甘坑河采用梅花式接种法将本源微生物菌剂分两次直接接入河流水体及底泥中。结果表明,第1次接种后的4 d内各项水质指标都不稳定,4 d后,悬浮物、COD、TP和NH3-N等浓度下降,水质明显改善;但从第8天开始,COD、NH3-N和TP的去除率同时下降,本源微生物的处理效率开始降低,需进行第2次接种;第2次接种后,DO浓度提升至2.0 mg/L以上,COD、TP和NH3-N的去除率分别保持在40%、30%和40%以上。结果表明,直接投菌法在城市重污染河道治理中可以初步消除河道的黑臭现象,修复水质。     

Chemical oxidation of sulfadiazine by the Fenton process: Kinetics,pathways, toxicity evaluation

This paper investigated sulfadiazine oxidation by the Fenton process under various reaction conditions. The reaction conditions tested in the experiments included the initial pH value of reaction solutions, and the dosages of ferrous ions and hydrogen peroxide. Under the reaction conditions with pH 3, 0.25 mM of ferrous ion and 2 mM of hydrogen peroxide, a removal efficiency of nearly 100% was achieved for sulfadiazine. A series of intermediate products including 4-OH-sulfadiazine/or 5-OH-sulfadiazine, 2-aminopyrimidine, sulfanilamide, formic acid, and oxalic acid were identified. Based on these products, the possible oxidation pathway of sulfadiazine by Fenton's reagent was proposed. The toxicity evaluation of reaction solutions showed increased antimicrobial effects following the Fenton oxidation process. The results from this study suggest that the Fenton oxidation process could remove sulfadiazine, but also increase solution toxicity due to the presence of more toxic products.     

Cornmeal-induced resistance to ciprofloxacin and erythromycin in enterococci

Triclosan is used as an antibacterial agent in household items and personal care products. Since this compound is found in maternal milk of humans and bodies of wild animals, there is growing concern among some consumer groups and scientific community that triclosan is adverse for humans and wild animals. In order to estimate adverse actions of triclosan, the effects of triclosan on intracellular Zn²⁺ concentration and cellular thiol content were studied in rat thymocytes by the use of flow cytometer with appropriate fluorescent probes. Triclosan at 1-3 μM (sublethal concentrations) increased the intensity of FluoZin-3 fluorescence (intracellular Zn²⁺ concentration) and decreased the intensity of 5-chloromethylfluorescein (5-CMF) fluorescence (cellular thiol content). Negative correlation (r = −0.985) between triclosan-induced changes in FluoZin-3 and 5-CMF fluorescences was found. Removal of external Zn²⁺ did not significantly affect the triclosan-induced augmentation of FluoZin-3 fluorescence, suggesting an intracellular Zn²⁺ release by triclosan. These actions of triclosan were similar to those of H₂O₂ and triclosan significantly potentiated the cytotoxicity of H₂O₂. Therefore, the results may suggest that triclosan at sublethal concentrations induces oxidative stress that decreases cellular thiol content, resulting in an increase in intracellular Zn²⁺ concentration by Zn²⁺ release from intracellular store(s). Since recent studies show many physiological roles of intracellular Zn²⁺ in cellular functions, the triclosan-induced disturbance of cellular Zn²⁺ homeostasis may induce adverse actions on the cells.     

pH对煤泥水絮凝沉降的影响

选择聚合氯化铝(PAC)/阴离子型聚丙烯酰胺(PHP)、氯化钙(CaCl2)/非离子型聚丙烯酰胺(NPAM)组合与NPAM、PHP、两性离子型聚丙烯酰胺(ZPAM)作为絮凝剂,在对道清选煤厂水采筛下原生煤泥和浮选尾矿的煤泥水进行组合药剂絮凝实验的基础上,考察了pH对煤泥水絮凝沉降的影响。实验结果表明,在不同的pH下,煤泥水的絮凝效果不同:在酸性条件下,宜单独使用有机高分子絮凝剂;在中性至碱性条件下,无机凝聚剂和有机絮凝剂联合使用效果较好。     

牛粪堆肥升温菌剂的筛选及其作用机制

以糖、淀粉、蛋白质、纤维素培养基及菌株增殖倍数、菌株性能等为筛选方法,从牛粪低温堆肥中筛选不同原料重要功能菌并组成功能菌剂;以不同类别原料菌及单菌株发酵实验对升温机制进行研究。结果表明,芽孢杆菌、假单胞菌、纤维单胞菌及小孢霉菌等为重要功能菌;菌剂起温快,升温效果好,48 h堆体即由低温进入中温,5 d达到高温,腐熟时间可缩短至约17~18 d;糖功能菌升温效果最为显著,淀粉及蛋白质功能菌次之,纤维素功能菌升温能力较弱;菌株利用各种原料能力越强,增殖速度越快,对升温作用越大。各菌株充分利用基质各成分,紧密协同和促进,是低温堆体发酵升温的主要作用机制。     

改善环保疏浚底泥脱水干化效能的实验研究

采用以硫酸亚铁(FeSO4)为主要成分的复合脱水剂作为疏浚泥浆脱水剂(以下简称脱水剂),黄沙、炉渣、煤灰、石灰和粉煤灰分别作为疏浚底泥干化改良剂进行实验研究。结果表明,在脱水剂投加量为100 mg/L条件下,可以提高沉淀效率约20%;在投加脱水剂及5%石灰、粉煤灰、炉渣改良剂的条件下,底泥比阻值下降50%～70%;初期渗水速率提高6%～68%;与原泥相比,以黄沙、炉渣、煤灰为改良剂的底泥,经过4个月干化期后,承载力提高了30%～150%。本研究为疏浚底泥快速脱水干化提供了一种可行的技术途径。     

固定床中粒状脱硫剂除尘效率的研究

建立了非稳态过滤下的固定床颗粒层除尘效率模型.该模型尽可能地包含了影响固定床颗粒层除尘的参数,反映了沉积粉尘对除尘效率的影响;研究了以粒状脱硫剂为滤料的固定床在不同颗粒层厚度、空床气速、粒径下的除尘效率.结果表明,在颗粒层厚度为400～800 cm、空床气速≤0.4 m/s的条件下,颗粒层的除尘效率可达90％以上.     

超声波-铁粉协同降解五氯酚

通过超声波-铁粉联合体系协同降解废水中的五氯酚(PCP).实验结果表明:降解120 min后,PCP去除率可达90.4％;在该体系中铁粉被逐渐腐蚀成Fe2+,随降解时间的延长,Fe2+浓度逐渐增加;体系中的Fe2+可以促进·OH的产生,并且可以与超声空化作用下产生的H2O2发生Fenton试剂氧化反应降解PCP;超声波...     

化学降阻剂在山地环境中的应用研究

把山地环境划分为4种类型,并对各自的特点进行了分析.从导电机理和降阻机理两个方面分析了化学降阻剂的降阻功能,根据不同地质条件讨论了化学降阻剂的合理选择,并对化学降阻剂的应用方法和技术进行了研究,为山区防雷提供一定的参考价值.