亚甲基蓝分光光度法测定硫化物校准曲线斜率、截距参考值研究

通过近三年实验室采用亚甲基蓝分光光度法测定硫化物校准曲线制作的一系列原始数据的收集,并通过数理统计方法对校准曲线、-余标准偏差、斜率扩展不确定度、截距扩展不确定度开展了详细讨论,得出亚甲基蓝分光光度法测定硫化物校准曲线斜率(b)参考范围为:0.019 1±0.00044,截距(a)参考值范围:0.003 3±0.005 0.此结果对实验室分析人员判定硫化物项目校准曲线制作是否合格具有一定的参考价值.     

SWAT‐LUT: A Desktop Graphical User Interface for Updating Land Use in SWAT

Long‐term simulations of agricultural watersheds have often been done assuming constant land use over time, but this is not a realistic assumption for many agricultural regions. This paper presents the soil and water assessment tool (SWAT)‐Landuse Update Tool (LUT), a standalone, user‐friendly desktop‐based tool for updating land use in the SWAT model that allows users to process multi‐year land use data. SWAT‐LUT is compatible with several SWAT model interfaces, provides users with several options to easily prepare and incorporate land use changes (LUCs) over a simulation period, and allows users to incorporate past or emerging land use categories. Incorporation of LUCs is expected to provide realistic model parameterization and scenario simulations. SWAT‐LUT is a public domain interface written in Python programming language. Two applications at the Fort Cobb Reservoir Experimental Watershed located in Oklahoma and pertinent results are provided to demonstrate its use. Incorporating LUCs related to implementation of recommended conservation practices over the years reduced discharge, evapotranspiration, sediment, total nitrogen, and total phosphorus loads by 59%, 9%, 68%, 53%, and 88%, respectively. The user’s manual is included in this article as Supporting Information. The SWAT‐LUT executable file and an example SWAT project with three land use rasters and the user’s manual are available at the United States Department of Agriculture‐Agricultural Research Service Grazinglands Research Laboratory website under Software. Editor’s note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.     

社区治安高危人员异常轨迹识别与预警方法研究*

为解决社区治安高危人员异常轨迹难以实时感知、精确识别、及时预警的问题,对社区治安高危人员动态轨迹进行标定,并建立动态轨迹序列化模型,通过序列化模型构建动态行为链;根据静态身份属性与动态轨迹时空特征信息,建立异常轨迹分析模型。结果表明:动态轨迹标定可实现对GPS轨迹数据高效、准确标定;异常轨迹分析模型可实现异常轨迹识别与预警。研究结果适用于社区高危人群管控,可为社区治安防控提供技术支持。     

全国重点城市空气自动监测系统质量考核中质量控制的探讨

详细介绍了武汉市环境监测中心站在质量考核中所采用的实验方法,并对考核中出现的若干质量问题进行分析,供交流与探讨。     

标定低浓度高锰酸钾溶液的方法比较

比较以高锰酸钾本身和邻菲哕啉-Fe^2＋作指示剂，对低浓度高锰酸钾溶液进行标定发现，以邻菲啰啉-Fe^2＋作指示剂的标定，结果更为准确。     

在役GIS内置特高频传感器校验方法研究

运行中的GIS内置传感器因其不易拆装,很难对其可靠性及有效性进行校验。根据GIS的结构特点以及特高频信号在GIS内的传输特点,提出一种对内置式特高频传感器的有效性进行校验的方法。通过在相邻传感器注入特高频信号并对信号幅值进行检测,通过检测及计算结果来判断特高频传感器的有效性,经现场验证,该方法简单有效。     

OH自由基绝对标定系统的建立和研究

利用H2 O在 1 85nm紫外光照射下产生定量OH自由基 ,用低压扩散激光诱导荧光技术建立了OH自由基标定系统 .在实验条件下 ,体系产生OH自由基的浓度范围为 3× 1 0 7— 2× 1 0 9个·cm- 3,得到归一化荧光信号 (S)与OH自由基浓度的定量关系为S =6 0 4× 1 0 - 9[OH]- 0 0 4 0 7(R2 =0 987) ,并研究和讨论了饱和效应以及体系中可能存在的干扰 .     

MODEL DEVELOPMENT FOR CONJUNCTIVE USE STUDY OF THE SAN JACINTO BASIN,CALIFORNIA1

ABSTRACT: A two-layered confined-unconfined numerical model for flow and mass transport is developed for the San Jacinto Basin. The model structure is determined by the geological structure of the Basin and model parameters are calibrated using 20 years of historical records. The total number of historical head observations used for the flow model calibration is 1,117 and the total number of the estimated parameters is 91. The two-layered transport model is also calibrated using historical water quality records. Sensitivity analysis of the flow model shows that only 68 parameters (out of a total of 91) are relatively sensitive and reliable. However, the unreliable parameters (23 of them) are found to be insensitive and thus not significant to the prediction and management of conjunctive use of surface water and ground water. The developed flow model has been used to study the two proposed artificial recharge scenarios for the San Jacinto Basin. We have found that during a relatively dry condition, an artificial recharge rate of 80 acre-ft/day can be achieved during the recharge period October through January. However, for a relatively wet condition, only 80 percent of the proposed rate can be effectively stored in the Basin during these months.     

LINEAR PROGRAMS FOR NONLINEAR HYDROLOGIC ESTIMATION1

ABSTRACT: The minimization of the sum of absolute deviations and the minimization of the absolute maximum deviation (mini-max) were transformed into equivalent linear programs for the estimation of parameters in a transient and linear hydrologic system. It is demonstrated that these two methods yield viable parameter estimates that are globally optimal and reproduce properly the timing and magnitude of hydrologic events and associated variables such as total runoff. The two linear estimation methods compared favorably with the popular least-squares nonlinear estimation method. The generality of the theoretical developments shows that linear program equivalents are adequate competitors of nonlinear methods of hydrologic estimation and parameter calibration.     

Spatial Calibration and Temporal Validation of Flow for Regional Scale Hydrologic Modeling1

Abstract: Physically based regional scale hydrologic modeling is gaining importance for planning and management of water resources. Calibration and validation of such regional scale model is necessary before applying it for scenario assessment. However, in most regional scale hydrologic modeling, flow validation is performed at the river basin outlet without accounting for spatial variations in hydrological parameters within the subunits. In this study, we calibrated the model to capture the spatial variations in runoff at subwatershed level to assure local water balance, and validated the streamflow at key gaging stations along the river to assure temporal variability. Ohio and Arkansas‐White‐Red River Basins of the United States were modeled using Soil and Water Assessment Tool (SWAT) for the period from 1961 to 1990. R² values of average annual runoff at subwatersheds were 0.78 and 0.99 for the Ohio and Arkansas Basins. Observed and simulated annual and monthly streamflow from 1961 to 1990 is used for temporal validation at the gages. R² values estimated were greater than 0.6. In summary, spatially distributed calibration at subwatersheds and temporal validation at the stream gages accounted for the spatial and temporal hydrological patterns reasonably well in the two river basins. This study highlights the importance of spatially distributed calibration and validation in large river basins.