标准气溶胶发生系统的建立与性能评估

针对气溶胶测量仪器校准和实验室气溶胶光学特性研究的需求,搭建了一套标准气溶胶发生系统,并对其性能开展了测试研究.系统采用恒定流量的雾化器产生气溶胶,经过扩散干燥管干燥以及电荷中和器带电中和后,产生标准气溶胶粒子.利用氯化钠样品对系统的性能进行了测试,结果表明,当样品溶液浓度增加时,系统雾化产生粒子的数浓度和粒径均随之增加;当载气气压增加,系统雾化产生粒子的数浓度随之增加,而粒径随之减小.在测试时间内,系统发生的多分散气溶胶粒子的几何平均粒径波动小于1%,总粒子数浓度波动小于2%,单分散气溶胶粒子数浓度的稳定性好于4%.     

CLIMATOLOGICAL WATERSHED CALIBRATION1

ABSTRACT: This study tests the hypothesis that climatic data can be used to develop a watershed model so that stream flow changes following forest harvest can be determined. Measured independent variables were precipitation, daily maximum and minimum temperature, and concurrent relative humidity. Computed variables were humidity deficit, saturated vapor pressure, and ambient vapor pressure. These climatic variables were combined to compute a monthly evaporation index. Finally, the evaporation index and monthly precipitation were regressed with measured monthly stream flow and the monthly estimates of stream flow were combined for the hydrologic year. A regression of predicted versus measured annual stream flow had a standard error of 1.5 inches (within 6.1 percent of the measured value). When 10, 15, and 20 years of data were used to develop the regression equations, predicted minus measured stream flow for the last 7 years of record (1972–1978) were within 16.8, 11.5, and 9.7 percent of the measured mean, respectively. Although single watershed calibration can be used in special conditions, the paired watershed approach is expected to remain the preferred method for determining the effects of forest management on the water resource.     

DECISION FRAMEWORK FOR SEDIMENT CONTROL IN MUDDY CREEK WATERSHED1

ABSTRACT: The tailwater of Bridgewater Dam, below Lake James, North Carolina, is a designated trout stream. It has environmental attributes for a good cold water fishery with the exception of high suspended sediments. Muddy Creek, a tributary about 1.5 km downstream of the dam, is a major source of sediments. The Muddy Creek Watershed Restoration Initiative was established to develop and implement a sediment control plan. The Watershed Analysis Risk Management Framework was applied to simulate soil erosion and sedimentation and to help determine appropriate action. The simulated sediment concentrations of the river were comparable to observed data from November 1994 to November 2001. For the base condition, the sediment load was 135,000 kg/d from surface erosion and 1,300,000 kg/d from bank erosion. Increasing the buffer strip from existing 50 to 80 percent to 100 percent of stream segments would only reduce surface erosion to 70,400 kg/d with little change in sediment concentrations. Eliminating riverbank erosion would reduce the sediment load from 920,000 to 87,700 kg/d. The bank stabilization project would not only lower suspended sediment concentrations for Muddy Creek, but also reduce the lake sediment accumulation in the downstream Lake Rhodhiss by approximately 13 percent.     

HYDROLOGIC MODELING OF TWO GLACIATED WATERSHEDS IN NORTHEAST PENNSYLVANIA1

ABSTRACT: A hydrologic modeling study, using the Hydrologic Simulation Program - FORTRAN (HSPF), was conducted in two glaciated watersheds, Purdy Creek and Ariel Creek in northeastern Pennsylvania. Both watersheds have wetlands and poorly drained soils due to low hydraulic conductivity and presence of fragipans. The HSPF model was calibrated in the Purdy Creek watershed and verified in the Ariel Creek watershed for June 1992 to December 1993 period. In Purdy Creek, the total volume of observed stream-flow during the entire simulation period was 13.36 × 10⁶ m³ and the simulated streamflow volume was 13.82 × 10⁶ m³ (5 percent difference). For the verification simulation in Ariel Creek, the difference between the total observed and simulated flow volumes was 17 percent. Simulated peak flow discharges were within two hours of the observed for 30 of 46 peak flow events (discharge greater than 0.1 m³/sec) in Purdy Creek and 27 of 53 events in Ariel Creek. For 22 of the 46 events in Purdy Creek and 24 of 53 in Ariel Creek, the differences between the observed and simulated peak discharge rates were less than 30 percent. These 22 events accounted for 63 percent of total volume of streamflow observed during the selected 46 peak flow events in Purdy Creek. In Ariel Creek, these 24 peak flow events accounted for 62 percent of the total flow observed during all peak flow events. Differences in observed and simulated peak flow rates and volumes (on a percent basis) were greater during the snowmelt runoff events and summer periods than for other times.     

A HYBRID OPTIMIZATION APPROACH TO THE ESTIMATION OF DISTRIBUTED PARAMETERS IN TWO-DIMENSIONAL CONFINED AQUIFERS1

ABSTRACT: In using non-linear optimization techniques for estimation of parameters in a distributed ground water model, the initial values of the parameters and prior information about them play important roles. In this paper, the genetic algorithm (GA) is combined with the truncated-Newton search technique to estimate groundwater parameters for a confined steady-state ground water model. Use of prior information about the parameters is shown to be important in estimating correct or near-correct values of parameters on a regional scale. The amount of prior information needed for an accurate solution is estimated by evaluation of the sensitivity of the performance function to the parameters. For the example presented here, it is experimentally demonstrated that only one piece of prior information of the least sensitive parameter is sufficient to arrive at the global or near-global optimum solution. For hydraulic head data with measurement errors, the error in the estimation of parameters increases as the standard deviation of the errors increases. Results from our experiments show that, in general, the accuracy of the estimated parameters depends on the level of noise in the hydraulic head data and the initial values used in the truncated-Newton search technique.     

活性污泥法动力学模型应用中的参数校核

对国际水协的活性污泥法动力学模型在应用中遇到的参数校核问题进行研究 ,总结了目前常用的三种方法 :专家法、灵敏度分析法和过程工程 (ProcessEngineering)法。分析了每种方法的原理、优点和不足之处 ,列举了实际应用的例子。     

PRISM vs. CFSR Precipitation Data Effects on Calibration and Validation of SWAT Models

Precipitation is one of the most important drivers in watershed models. Our objective was to compare two sources of interpolated precipitation data in terms of their effect on calibration and validation of two Soil and Water Assessment Tool (SWAT) models. One model was a suburban watershed in metropolitan Atlanta, Georgia. The precipitation sources were Parameter‐elevation Relationships on Independent Slopes Model (PRISM) data on a 4‐km grid and climate forecast system reanalysis (CFSR) data on a 38‐km grid. The PRISM data resulted in a better fit to the calibration data (Nash Sutcliffe efficiency [NSE] = 0.64, Kling‐Gupta efficiency [KGE] = 0.74, p‐factor = 0.84, and r‐factor = 0.43) than the CFSR data (NSE = 0.47, KGE = 0.53, p‐factor = 0.67, and r‐factor = 0.39). Validation results were similar. Sensitive parameters were similar in both the PRISM and CFSR models, but fitted values indicated more rapid groundwater flow to the streams with the PRISM data. The same comparison was made in the Big Creek watershed located approximately 1,000 km away, in central Louisiana. Results were similar with a more responsive groundwater system indicating PRISM data may produce better predictions of streamflow because of a more accurate estimate of rainfall within a watershed or because of a denser grid. Our study implies PRISM is providing a better estimate than CFSR of precipitation within a watershed when rain gauge data are not available, resulting in more accurate simulations of streamflows at the watershed outlet. Editor's note: This paper is part of the featured series on SWAT Applications for Emerging Hydrologic and Water Quality Challenges. See the February 2017 issue for the introduction and background to the series.     

水污染分析校准用汞溶液的研制

研制了水污染分析校准用汞溶液。采用原子荧光光谱法对样品进行了均匀性和稳定性检验,对样品的量值进行了验证并进行了不确定度评定。检验结果表明:汞溶液均匀性良好,室温条件下可稳定36个月以上;样品的标准值为100 mg/L,扩展不确定度为2 mg/L。样品量值与美国AccuStandard公司同种标准物质具有一致性。可用于水中汞检测的测定标准、质量控制、分析方法研究以及实验室能力验证等方面。     

Addressing data challenges in riverine nutrient load modeling of an intensively managed agro-industrial watershed

Data limitations often challenge the reliability of water quality models, especially in intensively managed watersheds. While numerous studies report successful hydrological model setup and calibration, few have addressed in detail the data challenges for multisite and multivariable model calibration to an intensively managed watershed. In this study, we address some of these challenges based on our reflective experience calibrating the Soil and Water Assessment Tool (SWAT) to the Upper Sangamon River Watershed in central Illinois based on daily flow, annual crop yield, and monthly sediment, nitrate, and total phosphorus loads. We highlight some challenges in SWAT calibration processes due to data errors and inconsistencies, and insufficient precipitation and water quality observations. Following, we demonstrate the merits of additional weather and water quality observations that could help reduce input uncertainties, and we provide suggestions for selecting appropriate observations for the model calibration. After dealing with the data issues, we show that the SWAT model could be calibrated with acceptable results for the case study watershed.     

Calibration and Validation of Far Field Dilution Models for Outfall at Worli, Mumbai

The city of Mumbai, India with a population of 15 million discharges about 2225 MLD of domestic wastewater after partial treatment to adjoining marine water body. Under the Mumbai Sewage Disposal Project Scheme, sewage is being disposed to the west coast at Worli and Bandra through 3.4 kms long submarine outfalls. A field study was conducted at recently commissioned outfall diffuser location at Worli, at the onset of neap flood tide to study the dispersion patterns and measure the far field dilutions using radio and dye tracers. Estimated dilutions using different tracers were compared with outputs from an empirical model (Brooks) and a 2D numerical model (DIVAST). Validation using parameters such as BOD and FC, indicated a good match for BOD in near field compared to FC. The radiotracer ⁸²Br and Rhodamine WT generally gave good correlation with Brooks' and DIVAST models for nearfield, however at further distances predictions were not accurate.