Engineered nanomaterials in rivers--exposure scenarios for Switzerland at high spatial and temporal resolution

Probabilistic material flow analysis and graph theory were combined to calculate predicted environmental concentrations (PECs) of engineered nanomaterials (ENMs) in Swiss rivers: 543 river sections were used to assess the geographical variability of nano-TiO₂, nano-ZnO and nano-Ag, and flow measurements over a 20-year period at 21 locations served to evaluate temporal variation. A conservative scenario assuming no ENM removal and an optimistic scenario covering complete ENM transformation/deposition were considered. ENM concentrations varied by a factor 5 due to uncertain ENM emissions (15%-85% quantiles of ENM emissions) and up to a factor of 10 due to temporal river flow variations (15%-85% quantiles of flow). The results indicate highly variable local PECs and a location- and time-dependent risk evaluation. Nano-TiO₂ median PECs ranged from 11 to 1′623 ng L⁻¹ (conservative scenario) and from 2 to 1′618 ng L⁻¹ (optimistic scenario). The equivalent values for nano-ZnO and nano-Ag were by factors of 14 and 240 smaller.     

Modifications of black carbons and their influence on pyrene sorption

Sorption of pyrene on black carbons (BCs) obtained by heating sawdust at two temperatures (400 and 700 °C, denoted as 400BC and 700BC, respectively), as well as on modified BCs (via oxidation, oximation, and hydrolysis) was studied to investigate the role of BC structural characteristics in sorption of hydrophobic organic compounds. Pyrene was bound strongly by 700BC and 400BC, with organic carbon normalized distribution coefficients (K_oc) of 10^5.04-10^5.86 and 10^4.65-10^5.16, respectively, at equilibrium pyrene concentrations of 10-100 μg L⁻¹. Both chemical composition and pore distribution of the two BCs changed after modifications, which led to changes in their sorption characteristics for pyrene. After modifications, the linearity of pyrene sorption isotherm increased for 700BC but decreased for 400BC. For 700BC, both oxidation and oximation reduced pyrene sorption, with K_oc decreasing by 69.1-73.7% and 18.7-33.9%, respectively, whereas hydrolysis did not exert a significant influence. For 400BC, oxidation and hydrolysis reduced K_oc by 2.28-25.9% and 29.2-33.9%, respectively, while oximation increased K_oc. In most cases, the change in sorption capacity could be explained by the changes in C content and type, polarity, surface area, and micropore volume of the BCs; however, the role of conformation (the accessibility to sorption sites) could not be ignored.     

给水曝气生物滤池内置粉末活性炭复合净水效果的研究

在给水曝气生物滤池内置粉末活性炭,对比分析其对各工艺单元水质净化效果的影响,确定给水曝气生物滤池内置粉末活性炭的作用与最佳投加量,研究表明,给水曝气生物滤池将活性炭截留在滤池内,大幅度提高了粉末活性炭利用率,部分未饱和粉末活性炭通过反冲洗排入后续常规处理系统,作为生物载体仍能够进一步发挥生物强化作用。当粉末活性炭的投加量为8 mg/L时,砂滤出水氨氮、CODMn、浊度和色度均值分别为：0.02 mg/L,1.82 mg/L0,.46 NTU和6度,去除率分别达到99.6%、71.2%、99.1%和80.6%,出水指标达到《生活饮用水卫生标准（》GB5749-2006）和《饮用净水水质标准（》CJ94-2005）规定的标准。与常规工艺相比,投加量降低了20%～60%。     

PVA降解混合菌系生长和产酶的营养条件分析

研究碳源、氮源以及不同金属离子对PVA降解混合菌系生长和产酶的影响。结果表明,混合菌系生长过程中无机氮源优于有机氮源;补充碳源可促进混合菌系的生长,但酶活比不添加时稍有降低。金属离子对酶活影响的正交实验表明Mg2＋浓度影响最大,其次是Fe2＋和K＋浓度,Ca2＋、Mn2＋、Zn2＋和Cu2＋浓度影响较小;最佳浓度分别为Mg2＋0.05 g/L、Fe2＋0.04 g/L、K＋2 g/L和Ca2＋0.05 g/L。     

活性炭纤维(ACF)应用于有机废气回收和净化的进展

活性炭纤维(ACF)有比普通活性炭吸附量大、吸附和脱附速度快等优点,因此应用于有机废气的回收和净化,具有良好的经济、环境和社会效益。文中介绍了ACF的微观结构、表面化学以及吸附性能,并综述了近年来ACF在有机废气回收和治理方面的国内概况。     

浅谈对热电企业的环境监督管理

对热电企业的环境监管工作是环保部门的重要职责,根据在对热电企业日常监管中遇到的问题,论述了监管的常用方法,包括监督企业环境管理落实情况、核查企业环保数据真实性及重视群众对企业的监督,并就相关工作展开了具体讨论。     

Environmental assessment of garden waste management in the Municipality of Aarhus, Denmark

An environmental assessment of six scenarios for handling of garden waste in the Municipality of Aarhus (Denmark) was performed from a life cycle perspective by means of the LCA-model EASEWASTE. In the first (baseline) scenario, the current garden waste management system based on windrow composting was assessed, while in the other five scenarios alternative solutions including incineration and home composting of fractions of the garden waste were evaluated. The environmental profile (normalised to Person Equivalent, PE) of the current garden waste management in Aarhus is in the order of −6 to 8 mPE Mg⁻¹ ww for the non-toxic categories and up to 100 mPE Mg⁻¹ ww for the toxic categories. The potential impacts on non-toxic categories are much smaller than what is found for other fractions of municipal solid waste. Incineration (up to 35% of the garden waste) and home composting (up to 18% of the garden waste) seem from an environmental point of view suitable for diverting waste away from the composting facility in order to increase its capacity. In particular the incineration of woody parts of the garden waste improved the environmental profile of the garden waste management significantly.     

光催化还原CO2的研究进展

介绍了多种将CO2转化为化工产品的光催化还原体系,包括TiO2体系、金属修饰的TiO2体系、有机光敏化剂修饰的TiO2体系和其他光敏半导体材料体系.评述了不同光催化体系的特点及其催化性能.讨论了光源波长、反应温度、CO2压力和浓度、H2O和CO2摩尔比等实验条件对反应产物种类及其产量的影响,指出催化剂的活性、光源波长和...     

燃煤电厂袋式除尘器滤料耐氧化性能试验研究

燃煤电厂锅炉烟气中含有SOx和NOx,会氧化腐蚀滤料。试验研究了燃煤电厂布袋除尘器滤料断裂强力与运行时间的关系。结果表明,滤料在酸性环境中会被氧化同时断裂强力下降,但断裂强力下降后均会出现反弹,后处理工艺可提高滤料的抗氧化性能,但会降低滤料的断裂强力。