Metabolic transformations of acquired lucibufagins by firefly “femmes fatales”

Summary. Female Photuris fireflies sequester defensive steroidal pyrones (lucibufagins) from male fireflies of the genus Photinus. Lucibufagin analyses of Photuris females and Photinus ignitus males show that the lucibufagin mixtures of predator and prey differ in their composition. Analyses of whole body extracts showed that P. ignitus males contain a mixture of eight non-glycosylated lucibufagins, composed mostly of compounds with two oxygenated positions in the steroidal A-ring (C-3, C-5). After feeding on P. ignitus males, Photuris females contain six major lucibufagins. Three of these compounds are not present in the prey, including the novel lucibufagin glycoside 5β,11α-dihydroxy-12-oxo-3β-O-β-D-xylopyranosylbufalin, and two other lucibufagins with a trioxygenated A-ring (C-2, C-3, C-5). These results indicate that Photuris females transform the sequestered lucibufagins both by glycosylation and oxidation, which could affect the systemic transportability of these compounds due to an increase in their polarity. Received 18 February 1999; accepted 19 April 1999.     

化学生物絮凝-悬浮填料移动床组合工艺处理城市污水研究

采用化学生物絮凝和悬浮填料移动床组合工艺处理城市污水。通过改变化学生物絮凝工艺中投加的混凝剂种类和投加量、改变悬浮填料移动床工艺中水力停留时间和气水比取得不同工况条件下各类污染指标的去除效果。采用该组合工艺,当进水COD(89～319)mg/L,TP(1.24～4.26)mg/L,SS(44～240)mg/L,NH4 -N(14.7～36.3)mg/L时,出水可达到COD<50mg/L,TP<0.5mg/L,SS<20mg/L,NH4 -N<5mg/L。     

电镀废水处理技术工程应用实践

针对电镀废水的特点,根据清污分流、先预处理再综合处理的原则进行合理的细化分类,对不同的水质进行分类物化处理。该处理技术具有工艺合理、可操作性好、自动化程度高等优点,处理后出水水质达到广东省《水污染物排放限值》(DB44/26-2001)二级标准。     

离心机考核测试和带式机脱水性能试验研究

为配合吉林化学工业股份有限公司 30万t乙烯工程A/O工艺废水处理工程化学污泥脱水的需要 ,进行了生产运行离心机性能考核测试和小型带式压滤机应用于化学污泥脱水的中试性能试验研究。本研究确定了小型带式压滤机最佳投泥量、投药量和产泥量等指标。达到了验收的各项技术经济指标 ,具有显著的经济和环境效益。     

Fenton试剂催化氧化--混凝法处理焦化废水的实验研究

用Fenton试剂结合自制聚硅硫酸铝对焦化废水进行了催化氧化—混凝试验研究 ,选择了最佳的工作条件。结果表明 ,经氧化—混凝处理后废水的COD从 1 1 73mg/L降至 38.2mg/L ,去除率达 96 .7%。研究中还发现 ,Fenton试剂具有将废水的 pH值调节为 2 .5～ 3的特性 ,为该工艺实际处理焦化废水提供了科学依据     

A new prediction method of industrial atmospheric pollutant emission intensity based on pollutant emission standard quantification

● Established a quantification method of pollutant emission standard. ● Predicted the SO₂ emission intensity of single coking enterprises in China. ● Evaluated the influence of pollutant discharge standard on prediction accuracy. ● Analyzed the SO₂ emissions of Chinese provincial and municipal coking enterprises. Industrial emissions are the main source of atmospheric pollutants in China. Accurate and reasonable prediction of the emission of atmospheric pollutants from single enterprise can determine the exact source of atmospheric pollutants and control atmospheric pollution precisely. Based on China’s coking enterprises in 2020, we proposed a quantitative method for pollutant emission standards and introduced the quantification results of pollutant emission standards (QRPES) into the construction of support vector regression (SVR) and random forest regression (RFR) prediction methods for SO₂ emission of coking enterprises in China. The results show that, affected by the types of coke ovens and regions, China’s current coking enterprises have implemented a total of 21 emission standards, with marked differences. After adding QRPES, it was found that the root mean squared error (RMSE) of SVR and RFR decreased from 0.055 kt/a and 0.059 kt/a to 0.045 kt/a and 0.039 kt/a, and theR² increased from 0.890 and 0.881 to 0.926 and 0.945, respectively. This shows that the QRPES can greatly improve the prediction accuracy, and the SO₂ emissions of each enterprise are highly correlated with the strictness of standards. The predicted result shows that 45% of SO₂ emissions from Chinese coking enterprises are concentrated in Shanxi, Shaanxi and Hebei provinces in central China. The method created in this paper fills in the blank of forecasting method of air pollutant emission intensity of single enterprise and is of great help to the accurate control of air pollutants.     

三氧化钨光催化法脱色处理化纤厂废水

以WO3粉体作为催化剂对化纤厂废水采用光催化氧化法进行脱色处理,讨论了光催化氧化法的反应机理,以及化纤厂废水的pH值、光催化剂的投入量、光照时间各因素对废水色度去除率的影响。实验结果表明：WO3粉体的投入量为1．000g／L,pH值为3．00时,利用300W高压汞灯光照7h后,废水试样的吸光度由0.596降低至0．020,色度去除率达到96．6％。     

国外快速测定化学消油剂消油效果的几种方法

化学消油剂消油效果的现场评定方法必须满足适合现场操作、材料价廉易得、结果可靠准确等条件。对国外现有的现场快速测定消油剂效果的5种方法进行比较,结果表明,英国的佩内特鉴别法、挪威的菲勒溢出油检测装置和加拿大的梅蒂现场测定法存在一定的缺陷,不推荐使用。美国环保局的现场测定法(EPA FDET)简单、快速、准确。加拿大渥太华一家环境研究机构研制出的现场试验法比EPA FDET法耗时多,但原材料价格低廉,操作简单,结果可靠,值得推广应用。     

己内酰胺生产废水处理技术

采用ENSBR-BDAR-BCOR工艺处理某化纤公司高含氮己内酰胺生产废水,在污泥负荷为0.15～0.28g/(g·d)、进水COD不高于6200mg/L、NH3-N质量浓度不高于560mg/L的情况下,出水COD不高于150mg/L、NH3-N质量浓度不高于20mg/L,COD和NH3-N的去除率分别达到98%和96%,系统可同时除碳脱氮。     

Management of process performance at low water temperatures in respect of filamentous organisms

The management of sludge-settling properties in Nordic conditions is of importance during the low temperature (spring) season because of the peak settler load. A survey was made in 10 Finnish waste water treatment plants(WWTP‘ s) and the total extended filament length and DSVI in haft of the plants exceeded the limits, which indicates sludge bulking( 15 km/g SS and 150 ml/g respectively). The dominant organism was Microthrix parvicella, the abundance of which was 59.22% of total extended filament length on average.Chemicals were tested to control the filaments, and it was found that special attention has to be paid to maintaining the nitrification at low temperature. A dosage of(H2O2-besed) oxidants controlled the growth of Microthrix parvicella effectively and rapidly, whereas with the use of aluminium hydroxidechloride a 2 to 5-week period was needed to decrease the filament length.