从全混流反应器热稳定性的角度探讨高危工艺的危险性

通过对全混流反应器(CSTR)热平衡条件下多态的分析,探讨热稳定性条件,并对一级不可逆反应在CSTR中的热稳定性进行定性分析;探讨不同反应热和活化能对反应过程热稳定性的影响,及其对反应器发生"飞温"事故要求紧急停车时的控制要求的影响,进而从反应工程的角度对高危工艺的界定提出新的思路。分析结果表明,工艺的危险性不仅与工艺的种类相关,更与工艺本身的热力学、动力学特征密切相关。通过对高危工艺的热稳定状况的分析,能够动态地揭示其在温度扰动下发生"飞温"或"熄火"的过程,从本质上把握高危工艺潜在的危险性,并能有针对性地制定自动化改造方案,提高化工企业的本质安全度。     

大气压力对细水雾灭火系统泵组流量特性及效率的影响

柱塞泵是泵组式细水雾灭火系统的关键部件,它是细水雾喷头实施喷雾的供水源和压力驱动源.为研究大气压力,特别是高海拔低气压环境对柱塞泵流量特性及效率的影响,通过在合肥及拉萨两地的对比试验,给出了环境压力与柱塞泵流量特性及效率的关系.结果表明,大气压力减小使柱塞泵的流量减小,因此,在高原低气压环境下使用柱塞泵,应采用增加柱塞泵进口压力的措施,以保证泵组式细水雾灭火系统的设计性能;不同大气压力下泵组的效率无明显变化,即大气压力对泵组的效率无明显影响.     

经过水泥固化的重金属废物的穿透渗漏实验

采用穿透渗漏实验方法研究了经水泥固化的重金属废物的长期渗漏行为。用由Ｐｂ＾２＋、Ｚｎ＾２＋、Ｃｕ＾２＋、Ｎｉ＾２＋和Ｃｒ＾６＋５种重金属组成的合成废物样品进行２组实验。实验研究了渗漏实验液流速、ＰＨ的变化和金属渗漏能力对固体废物长期渗漏行为的影响。     

Temporal moments analysis of preferential solute transport in soils

Temporal moments analysis of solute breakthrough curves is used to investigate the preferential leaching of chloride, nitrate and phosphate through an Australian soil. Recent studies have shown that current models and methods do not adequately describe the leaching of nutrients through soil, often underestimating the risk of groundwater contamination by surface-applied chemicals, and overestimating the concentration of resident solutes. This inaccuracy results primarily from ignoring soil structure and non-equilibrium between soil constituents, water and solutes. Therefore simple models are required to accurately characterise solute transport in natural and agricultural soils under non-equilibrium conditions. A multiple sample percolation system, consisting of 25 individual collection wells was constructed to study the effects of localised soil heterogeneities on the transport of nutrients (NO₃ ^–, Cl^–, PO₄ ^{3 –}) in the vadose zone of an agricultural soil predominantly dominated by clay. Using data collected from the multiple sample percolation experiments, this paper compares and contrasts the performance of temporal moments analysis with two mathematical models for predicting solute transport, the advective-dispersion model with a reaction term (ADR) and a two-region preferential flow model (TRM) suitable for modelling preferential transport. The values for solute transport parameters predicted by temporal moments analysis were in excellent agreement with experimental data and results from ADR and TRM. It is concluded that temporal moments analysis when applied with other physical models such as the ADR and TRM, provide an excellent means of obtaining values for important solute transport parameters and gaining insight of preferential flow. These results have significant ramifications for modelling solute transport and predicting nutrient loadings.     

Simulating Nitrate Leaching Profiles in a Highly Permeable Vadose Zone

An approach is developed to simulate leaching of a dissolved chemical constituent in the vadose zone of an aquifer. Specifically, nitrate loading at the water table for different water table depths, for a range of aquifer permeability values, and for different cases of heterogeneity of the aquifer, are considered. Models from the literature are first used to derive soil–water characteristic curves (water retention and hydraulic conductivity) from a grain size distribution curve for unsaturated conditions. Given infiltration from the surface, the initial conditions for the chemical concentration, and the water content profile, leaching of the chemical in the vadose zone is simulated as a function of both time and depth. The methodology is illustrated for a permeable aquifer. Simulations are undertaken using a finite element code for saturated and unsaturated flow. Different scenarios are simulated depending on the heterogeneity of the aquifer and the depth of the water table. Modeling results show that in the example case studied, nitrate concentration loading at the water table does not depend strongly on the position of the water table, but rather on the material properties of the aquifer. The contribution of this endeavor resides in the methodology which allows a prediction of nitrate leaching using only the grain size property of the aquifer. It allows practitioners to obtain a first assessment of leaching with limited data.     

崂山风景区旅游环境容量研究

通过对历年游客流量调查，分析了崂山风景区客流时间和空间分布特征。计算了景区9条步道游线，3条索道和7个人文景观区的日容量、月容量和年容量，并分析了景区旅游环境容量的利用强度，发现2004年景区各条步道游线、各条索道和各个人文景观区的日、月、年容量利用强度均为适载，但第一、第二和第三高峰日已严重超载。最后，制定了游客流量宏观调控对策及微观调控措施。     

云南蒋家沟泥石流运动特征及其发展趋势

根据蒋家沟1965~2005年的泥石流运动观测资料与会泽气象站1965~2005年日降水资料,应用Hurst指数分析泥石流的运动要素,研究发现:泥石流年输沙量的Hurst指数为0.682时,年输沙量呈较强的正持续性,未来呈增长趋势;降雨量的Hurst指数0.605时,降雨量呈较弱的正持续性,未来呈较弱的增长趋势。同时,运用小波分析方法,发现泥石流输沙量具有多时间尺度周期的特征,主要表现为:第8、14和24年分别为其第1、2和3活动周期;结合小波方差图分析可知:在未来15 a以上,年输沙量将呈减少趋势,泥石流活跃程度弱;而15 a以内,未来将会保持较短时间的增加趋势,泥石流活跃程度强。综合以上分析可知:蒋家沟泥石流具有规模巨大,作用强烈,类型齐全等主要特征。     

泥石流灾害风险评价方法及其应用研究

探讨泥石流灾害风险评价的理论和方法;利用已有的泥石流灾害资料,建立泥石流风险评价体系和实施流程;提出风险评价的定量计算方法;结合遥感和地理信息系统技术,完成了云南省昆明市东川区泥石流灾害的定量风险评价。研究结果与泥石流实际分布和调查资料基本一致,表明所提出的泥石流灾害风险评价的理论与方法具有一定的理论价值和现实意义,可以为泥石流灾害风险评价和防灾减灾管理提供有益的科学依据。     

A method for regional-scale material flow and decoupling analysis: A demonstration case study of Aichi prefecture, Japan

We have developed a method to analyse the annual material flow in a prefecture and have calculated environmental indicators for a prefecture. Material flow analysis (MFA) is important to clarify the structure of a regional society and obtain environmental indicators for a circular society. However, MFA has not advanced in local governments because of few local statistics. We have developed a method to analyse the annual material flow in Aichi prefecture from 1980 to 2000 using an input–output (I–O) table and statistics of Aichi. We have verified the accuracy of this method by comparing its results for 2000 which calculated on the basis of official I–O table for 1995 with the I–O table data for 2000; the correlation coefficient obtained in this case is greater than 0.95. Moreover, by performing MFA, we have estimated the resource consumption and decoupling indicator of each industry in Aichi prefecture from 1980 to 2000. We could obtain more detailed and accurate environmental indicators by using our method. From these results, we could estimate the progress of Aichi prefecture towards a circular society.     

Anthropogenic metal cycles in China

The flows and stocks of seven important industrial metals were characterized for mainland China for several years in the dynamically changing decade of 1994–2004. One-year snapshot cycles are provided for chromium, nickel, and silver. For copper, zinc, lead, and iron, multiple-year cycles have been completed; they demonstrate that the flows of these metals into use in China doubled between 2000 and 2004. Although the Chinese per capita flows from production to disposal are mostly shown to be below the global average rate, they are increasing or are expected to increase dramatically. The metal resource efficiency is evaluated for several indicators of material flow analysis; these metrics for China are also below the global average values. The research quantitatively illustrates that China’s metal cycles may pose significant resource and environmental challenges in terms of their magnitudes and potential for growth.