全文获取类型
收费全文 | 128篇 |
免费 | 22篇 |
国内免费 | 73篇 |
专业分类
安全科学 | 18篇 |
废物处理 | 23篇 |
环保管理 | 4篇 |
综合类 | 93篇 |
基础理论 | 32篇 |
污染及防治 | 44篇 |
评价与监测 | 8篇 |
社会与环境 | 1篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 6篇 |
2019年 | 8篇 |
2018年 | 6篇 |
2017年 | 9篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 10篇 |
2013年 | 22篇 |
2012年 | 24篇 |
2011年 | 20篇 |
2010年 | 10篇 |
2009年 | 18篇 |
2008年 | 6篇 |
2007年 | 12篇 |
2006年 | 14篇 |
2005年 | 4篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
排序方式: 共有223条查询结果,搜索用时 718 毫秒
201.
202.
通过对来自美国加州拉玛达(La Mirada)市污染点的原始菌源炭进行甲基叔丁基醚(MTBE)降解菌生物强化,试图建立具有更有效MTBE降解效果的生物活性炭(BAC)功能,尝试利用新形成的菌源炭覆盖新鲜椰壳活性炭(GAC)而达到新BAC功能的快速有效启动,并考察不同空床停留时间(EBCT)、GAC吸附饱和状态对BAC功能启动的影响。同时,对具有成熟BAC功能的炭柱中的混合菌落进行基于16SrDNA的聚合酶链反应(PCR)—变性梯度凝胶电泳(DGGE)分析,以确定混合菌落中的主要功能菌种属。结果表明,针对模拟的低MTBE浓度进水,新鲜GAC和菌源炭A添加体积分数分别为40%和60%的NAS柱出水MTBE质量浓度最终稳定低于0.005mg/L,平均去除率接近99%,出水MTBE完全达到美国环境保护署(EPA)的饮用水建议阈值(<20μg/L),建立了成熟的BAC功能;成熟的菌源炭可在30d左右通过覆盖法迅速实现新BAC功能的启动;EBCT的延长有利于新BAC功能的启动和维持,接种初期应尽量采用较长EBCT以保证取得足够和稳定的生物量;MTBE吸附饱和前后的GAC在启动新BAC功能时存在差异,鉴于吸附饱和GAC在接种初期会因MTBE解吸而造成出水MTBE浓度较高,建议采用新鲜活性炭覆盖需接种炭柱;BAC功能成熟炭柱中包括的5种主要菌种里有4种为未培养微生物,1种为未分类菌种,其理化性质和具体属性尚不明确。 相似文献
203.
采用铁碳微电解耦合光-Fenton氧化法降解模拟废水中的十溴联苯醚(BDE-209)。探索了铁碳微电解法降解BDE-209的影响因素,考察了铁碳微电解耦合光-Fenton氧化法对BDE-209的降解效果。实验结果表明:在模拟废水BDE-209质量浓度为1 mg/L、初始废水p H为2.0、铁碳质量比为1∶1、铁粉投加量为12 g/L、微电解温度为40 oC、微电解时间为60 min的条件下,铁碳微电解法的BDE-209降解率达到82.5%;当H2O2溶液投加量为4 m L/L时,铁碳微电解耦合光-Fenton氧化法的BDE-209降解率达到95.7%。说明添加H2O2的Fenton体系对BDE-209的降解有明显促进作用。 相似文献
204.
二甲醚(DME)作为可再生的清洁燃料,因为其优越的性能而越来越受关注,但与此同时其燃烧的安全性却容易被忽视。自蒙特利尔议定书以后,含磷化合物成为抑制碳氢化合物火焰最理想的卤代烷替代物,选取甲基磷酸二甲酯(DMMP)应用于二甲醚火焰,基于分层结构首次构筑了DME/DMMP详细化学反应机理。通过模拟研究发现,DMMP对DME层流预混火焰表现出与碳氢火焰同样明显的抑制作用。进一步进行火焰抑制机理分析,结果显示DMMP对DME层流火焰的抑制主要是因为PO_2和HOPO的循环反应促进了H和OH重组,同时得出DMMP对DME富燃火焰抑制更有效的结论。 相似文献
205.
猪肝微粒体体外代谢2,2’,4,4’-四溴联苯醚 总被引:2,自引:0,他引:2
多溴联苯醚(PBDEs)是一类在环境中普遍存在的持久性有机污染物,研究PBDEs的体外代谢行为对理解其在体内的富集和转化具有重要意义。文章以猪肝微粒体作为研究对象,以体外代谢形式研究其对2,2’,4,4’-四溴联苯醚(BDE-47)的代谢能力,优化了代谢条件,并研究了0.01、0.05、0.1、0.5、1、5、10 mg/L的BDE-47对细胞色素P450酶系中7-乙氧基香豆素-O-脱乙基酶(ECOD)、7-乙氧基异吩唑酮-O-脱乙基酶(EROD)和苯胺4-羟基化酶(ANH)活性的影响。结果表明,孵育0.1 mg/L的BDE-47时,猪肝微粒体对BDE-47的代谢率可达到28.6%。实验所设各浓度BDE-47均能够保护微粒体的ECOD活性,但较高浓度的BDE-47(0.5、1、5 mg/L)对微粒体的EROD活性有显著抑制作用,而各浓度BDE-47对ANH活性没有显著影响。 相似文献
206.
Response surface methodology analysis of the photocatalytic removal of Methylene Blue using bismuth vanadate prepared via polyol route 总被引:1,自引:1,他引:0
Visible-light driven photocatalyst bismuth vanadate (BiVO4) photocatalyst was synthesized by the polyol route using ethylene glycol. The precipitate was washed, dried and calcined at 450℃ for 3 hr. The sample was characterized by X-ray diffractometry (XRD), field emission scanning electron microscopy (FE-SEM), zeta potential, surface area (BET method) and band gap energy via diffuse reflectance spectroscopy (DRS). The synthesized BiVO4 has a monoclinic phase with a surface area of 4.3 m2/g and a band gap energy of 2.46 eV. A majority of the particles were in the range of 90-130 nm as obtained from the particle size distribution histrogram. The efficiency of the sample as a visible-light driven photocatalyst was examined by photodegrading Methylene Blue (MB). The effects of some operational photodegradation parameters such as mass loading, initial dye concentration and pH were also examined. Experimental design methodology was applied by response surface modeling and optimization of the removal of MB. The multivariate experimental design was employed to develop a quadratic model as a functional relationship between the percentage removal of MB and three experimental factors (BiVO4 loading, MB initial concentration and pH). The percentage removal of MB approached 67.21% under optimized conditions. In addition, a satisfactory goodness-of-fit was achieved between the predictive and the experimental results. 相似文献
207.
M. Fernández-Pérez M. Villafranca-Sánchez F. Flores-Céspedes 《Journal of environmental science and health. Part. B》2013,48(7):863-868
An encapsulation system was developed and designed to give long-lasting effectiveness of the insect growth regulator cyromazine. Cyromazine was incorporated in lignin-poly (ethylene glycol) (PE) controlled-release formulations by means of a melting process. The basic formulation [lignin (65%)–PE (20%)–cyromazine (15%)] was coated in a Wurster-type fluidized-bed equipment using two different amounts of ethylcellulose. That of the highest one was modified by the addition of a plasticizer, dibutyl sebacate (DBS). The effect on cyromazine release rate caused by the incorporation of ethylcellulose and DBS in lignin-PE formulation was studied by immersion of the granules in water under static conditions. Using an empirical equation, the time taken for 50% of the active ingredient to be released into water (T50) was calculated. From the analysis of the T50 values, the influence of ethylcellulose appears clearly defined, observing a delay in release rate of cyromazine with respect to the basic lignin-PE formulation. In addition, the granules coated with ethylcellulose and the plasticizer lead the slowest release rate into water. The release of cyromazine into water is controlled by a diffusion mechanism. The thickness and permeability of the coating film are the most important factors that affect cyromazine release. 相似文献
208.
A series of novel azacrown ether Schiff bases 1–3 have been synthesized in good yield and in a simple way. Their host–guest interaction with [60]fullerene has been studied in toluene by absorption spectroscopic method. All the complexes are found to be stable with 1:1 stoichiometry. Because of their potential applications in industry, agriculture and medicine, they were investigated for their mutagenic and antimutagenic activities using the spot test and the plate incorporation assay of Ames. Compounds 1, 2 and 3 were found to be nonmutagenic in the Ames test using strains TA 1535, TA100 and TA97a of Salmonella typhimurium. However, using strain TA102 revealed that, although both compounds 1 and 2 were nonmutagenic, compound 2 gave a positive response indicating that it acts as an oxidative mutagen. The structure-activity relationship may throw some light on the biological activity of such series of compounds. 相似文献
209.
介绍抚顺醇醚化学厂醇醚生产废水的排放与水质特点 ,结合工艺流程介绍处理工艺设计和技术参数。几年来的运行结果表明 ,采用生物滤池 生物接触氧化 纤维球过滤三级工艺处理醇醚表面活性剂废水 ,处理效果良好 ,出水CODCr<10 0mg/L ,SS <15mg/L ,滤后水可用于厂区绿化。 相似文献
210.
Fischer A Oehm C Selle M Werner P 《Environmental science and pollution research international》2005,12(6):381-386
Background Methyl tertiary butyl ether (MTBE) is a fuel additive which is used all over the world. In recent years it has often been
found in groundwater, mainly in the USA, but also in Europe. Although MTBE seems to be a minor toxic, it affects the taste
and odour of water at concentrations of < 30 μg/L. Although MTBE is often a recalcitrant compound, it is known that many ethers
can be degraded by abiotic means. The aim of this study was to examine biotic and abiotic transformations of MTBE with respect
to the particular conditions of a contaminated site (former refinery) in Leuna, Germany.
Methods Groundwater samples from wells of a contaminated site were used for aerobic and anaerobic degradation experiments. The abiotic
degradation experiment (hydrolysis) was conducted employing an ion-exchange resin and MTBE solutions in distilled water. MTBE,
tertiary butyl formate (TBF) and tertiary butyl alcohol (TBA) were measured by a gas chromatograph with flame ionisation detector
(FID). Aldehydes and organic acids were respectively analysed by a gas chromatograph with electron capture detector (ECD)
and high-performance ion chromatography (HPIC).
Results and Discussion Under aerobic conditions, MTBE was degraded in laboratory experiments. Only 4 of a total of 30 anaerobic experiments exhibited
degradation, and the process was very slow. In no cases were metabolites detected, but a few degradation products (TBF, TBA
and formic acid) were found on the site, possibly due to the lower temperatures in groundwater. The abiotic degradation of
MTBE with an ion-exchange resin as a catalyst at pH 3.5 was much faster than hydrolysis in diluted hydrochloric acid (pH 1.0).
Conclusion Although the aerobic degradation of MTBE in the environment seems to be possible, the specific conditions responsible are
widely unknown. Successful aerobic degradation only seems to take place if there is a lack of other utilisable compounds.
However, MTBE is often accompanied by other fuel compounds on contaminated sites and anaerobic conditions prevail. MTBE is
often recalcitrant under anaerobic conditions, at least in the presence of other carbon sources. The abiotic hydrolysis of
MTBE seems to be of secondary importance (on site), but it might be possible to enhance it with catalysts.
Recommendation and Outlook MTBE only seems to be recalcitrant under particular conditions. In some cases, the degradation of MTBE on contaminated sites
could be supported by oxygen. Enhanced hydrolysis could also be an alternative.
- * The basis of this peer-reviewed paper is a presentation at the 9th FECS Conference on 'Chemistry and Environment', 29 August
to 1 September 2004, Bordeaux, France. 相似文献