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大孔强碱阴树脂去除饮用水中微量有机物 总被引:2,自引:0,他引:2
比较了大孔强碱阴树脂和颗粒活性炭在饮用水的深度处理中对有机物的去除效果。结果表明:(1)大孔强碱阴树脂的吸附容量比颗粒活性炭的大。在pH为8时,大孔强碱阴树脂对TOC的去除率最高。pH6~8时,对TOC的去除率没有明显的区别,而颗粒活性炭在pH为2时。对TOC的去除率最高;水温低能提高2种吸附材料的吸附容量。(2)在动态实验条件下。当流速相同,大孔强碱阴树脂的穿透时间明显比颗粒活性炭的长,大孔强碱阴树脂的制水量约是吸附床的10000倍。而颗粒活性炭却只有吸附床的4000倍。在饮用水的深度处理中,大孔强碱阴树脂可作为活性炭的最佳替代品。 相似文献
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就如何使用ClO2和O3对水中石油类污染物氧化去除进行了研究,确定了最佳反应时间、pH和氧化剂用量对去除率的影响。ClO2的最佳投加量应为有机物总量的1.5倍,反应时间可控制在20min上。ClO2处理pH5.0~6.5溶液时的去除效果最好。同时进行了O3的对照实验。分析了ClO2和O3在水处理应用中的优缺点。 相似文献
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Glyphosate has become the most commonly used herbicide worldwide and is reputedly environmentally benign, nontoxic, and safe for use near wildlife and humans. However, studies indicate its toxicity is underestimated and its persistence in the environment is greater than once thought. Its actions as a neurotoxin and endocrine disruptor indicate its potential to act in similar ways to persistent organic pollutants such as the organochlorines dichlorodiphenyltrichloroethane (DDT) and dioxin. Exposure to glyphosate and glyphosate‐based herbicides for both wildlife and people is likely to be chronic and at sublethal levels, with multiple and ongoing exposure events occurring in urban and agricultural landscapes. Despite this, there has been little research on the impact of glyphosate on wildlife populations, and existing studies appear in the agricultural, toxicology, and water‐chemistry literature that may have limited visibility among wildlife biologists. These studies clearly demonstrate a link between chronic exposure and neurotoxicity, endocrine disruption, cell damage, and immune suppression. There is a strong case for the recognition of glyphosate as an emerging organic contaminant and substantial potential exists for collaborative research among ecologists, toxicologists, and chemists to quantify the impact of glyphosate on wildlife and to evaluate the role of biosentinel species in a preemptive move to mitigate downstream impacts on people. There is scope to develop a decision framework to aid the choice of species to biomonitor and analysis methods based on the target contaminant, spatial and temporal extent of contamination, and perceived risk. Birds in particular offer considerable potential in this role because they span agricultural and urban environments, coastal, inland, and wetland ecosystems where glyphosate residues are known to be present. 相似文献
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Raiane Costa Souza Roberto Bagattini Portella Paula Valéria Nunes Brito Almeida Caroline Oliveira Pinto Priscila Gubert 《Journal of environmental science and health. Part. B》2020,55(6):530-538
AbstractOrganochlorine pesticides (OCPs) are widely used around the world as insecticides, herbicides, fungicides, nematicides, and rodenticides. Despite banned in Brazil, the usage remains occurring in many countries. The persistence and extreme mobility of OCPs contribute to the contamination of the environment and the human body. The OCPs bioaccumulation in adipose tissue triggers the excretion into human milk during breastfeeding. Hence, the present study determined eighteen OCPs residues in the breast milk of mothers from the Western Region of Bahia State, Brazil. Nine different residue species were found, including beta-Hexachlorocyclohexane (9.24?±?0.00?ng g?1 fat), delta- Hexachlorocyclohexane (22.15?±?10.48?ng g?1 fat), Heptachlor (58.08?±?74.13?ng g?1 fat), Aldrin (142.65?±?50.65?ng g?1 fat), Dieldrin (774.62?±?472.68?ng g?1 fat), Endosulfan I (408.44?±?245.51?ng g?1 fat), Dichloro-diphenyl-dichloro-ethylene (29.17?±?22.42?ng g?1 fat), Dichloro-diphenyl-trichloro-ethane (28.87?±?0.00?ng g?1 fat) and Methoxychlor (1699.67?±?797.43?ng g?1 fat). The Methoxychlor presence in all samples may reveal a recent exposure, while Dieldrin and Endosulfan I analyses can point to distant past exposure. 相似文献
28.
采用紫外可见光谱(UV-Vis)、傅立叶变换红外光谱(FTIR)及离子色谱(IC)技术对HNO3在α-Fe2O3表面暗反应和308nm下光解反应进行了研究.考察了时间、HNO3浓度、相对湿度(RH)等条件对反应的影响.结果表明,随着HNO3浓度、光照时间的增加,HNO3在气相与α-Fe2O3表面光解产物浓度均呈指数增加;HNO3在α-Fe2O3表面光解产生的NO2、NO分别为气相产生的3.27及3.87倍,而无论气相还是表面光解的NO2浓度均约为NO的2倍.随着RH的增加,HNO3光解产生的HONO的浓度随之呈指数增大,其产率从RH 20%时的0.023增加到90%时的0.087.α-Fe2O3的表面效应在HNO3的表面光解反应中起主导作用. 相似文献
29.
河流CO2与CH4排放研究进展 总被引:1,自引:0,他引:1
河流作为连接海-陆两大碳库的主要通道,其水-气界面二氧化碳(CO_2)与甲烷(CH_4)排放构成全球碳循环的重要环节,对全球气候变暖的贡献不容小觑.明确河流水体CO_2与CH_4产排过程、时空特征以及控制因素是认识河流生态学功能以及其对变化环境响应的重要内容.基于当前河流CO_2与CH_4排放研究进展,构建河流碳排放动力学概念框架(内源代谢、陆源输入),并从全球尺度、区域尺度、流域尺度综述了河流碳排放时空变异性特征以及存在的研究不足.在理解碳排放动力学概念框架和时空变异特征的基础上,构建了河流CO_2与CH_4动力学控制因子分层框架(内部因子:有机质、温度、营养盐;外部因子:水文、地貌、人类活动),深入探讨了河流碳排放的关键影响因素.最后,根据当前研究中存在的不足,提出河流碳排放应将纳入区域陆地碳平衡过程,今后研究重点应包括流域尺度上河流CO_2与CH_4内源产生与陆源输入相对贡献的量化研究、不同界面CO_2与CH_4产生与排放过程研究、高时空分辨率的监测数据的补充以及变化环境与人类活动干扰下河流碳排放的响应过程等,为理解河流生态学过程及生态系统功能提供基础,同时为我国进一步深入开展相关研究提供借鉴. 相似文献
30.
Annual and monthly-based emission inventories in northern, central and north-eastern provinces in Thailand, where agriculture and related agro-industries are very intensive, were estimated to evaluate the contribution of agricultural activity, including crop residue burning, forest fires and related agro-industries on air quality monitored in corresponding provinces. The monthly-based emission inventories of air pollutants, or, particulate matter (PM), NOx and SO2, for various agricultural crops were estimated based on information on the level of production of typical crops: rice, corn, sugarcane, cassava, soybeans and potatoes using emission factors and other parameters related to country-specific values taking into account crop type and the local residue burning period. The estimated monthly emission inventory was compared with air monitoring data obtained at monitoring stations operated by the Pollution Control Department, Thailand (PCD) for validating the estimated emission inventory. The agro-industry that has the greatest impact on the regions being evaluated, is the sugar processing industry, which uses sugarcane as a raw material and its residue as fuel for the boiler. The backward trajectory analysis of the air mass arriving at the PCD station was calculated to confirm this influence. For the provinces being evaluated which are located in the upper northern, lower northern and northeast in Thailand, agricultural activities and forest fires were shown to be closely correlated to the ambient PM concentration while their contribution to the production of gaseous pollutants is much less. 相似文献