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291.
2016年8月1日—2017年7月31日在上海市崇明岛森林公园空气质量观测站进行了为期1年的大气气体污染物、PM_(2.5)水溶性成分在线监测。各项常规大气污染物在该站浓度均较低,但污染物极值较高,说明崇明地区仍有显著的区域污染现象。PM_(2.5)中硝酸根平均浓度(10. 0μg/m~3)高于硫酸根(6. 8μg/m~3),2种成分均在冬季出现最高值。崇明地区PM_(2.5)污染中污染物区域传输是主要贡献因子,但夏季硫酸根二次生成较为明显。风速风向及后向气流轨迹分析表明,南通工业区及城区是崇明地区PM_(2.5)二次无机成分气态前体物的重要贡献来源,而来自山东中部、江苏北部及长三角苏锡常地区的污染传输过程亦对硫酸根、硝酸根浓度有显著贡献。 相似文献
292.
采用活性炭管吸附废气中的乙酸乙酯和乙酸丁酯,经二硫化碳萃取解析,使用DM-1色谱柱分离后FID检测.实验结果表明:(1)采用活性炭管吸附废气中的目标组份,富集效率良好,二硫化碳解析率可达92%以上;(2)当乙酸乙酯和乙酸丁酯的含量为6.8~102 ng时,测定结果的相对标准偏差分别在1.8% ~4.2%和3.2% ~6.1%之间(n=6);(3)当样品采集量为30 L时,方法检出限分别为0.02 mg·m-3和0.02 mg·m-3.因此,方法能满足实验对空气废气中的乙酸乙酯和乙酸丁酯的检测要求. 相似文献
293.
294.
DRAGANA MUTAVDŽIĆ IVAN BRNARDIĆ MARIJA KAŠTELAN-MACAN 《Journal of environmental science and health. Part. B》2013,48(7):1085-1101
The purpose of this investigation was to determine the influence of humic acids (HA) and Ca-montmorillonite (CaM) on the solid-phase extraction (SPE) efficiency of atrazine, alachlor and α-cypermethrin from water samples at various pH-values. The nature and intensity of binding of the studied pesticides to CaM were determined by X-ray diffraction analysis and termogravimetric analysis (TGA) test. The studied pesticides eluted from discs were analysed by thin-layer chromatography (TLC). The effects of CaM and humic acid were generally pH-dependent and acted independently in extraction efficiency influence. Lower recovery of pesticides was observed at higher pH values when CaM was ≥0.1 g and was attributed to greater dispersion of clay, increased surface area and subsequent adsorption. Concentrations of dissolved organic carbon (DOC) in humic acid had less effect on the extraction efficiency when water was at pH 8 compared to water at pH 2, which was probably due to greater nonpolar interactions of the pesticides to the charge-neutralized humic acid molecule. 相似文献
295.
从暴露于污染物蒽的鲤肝脏中提取出芳香烃受体,并采用紫外可见分光光度计进行最大吸收波长扫描,再通过离子交换层析法分离纯化鲤体内的芳香烃受体,并采用聚丙烯酰胺凝胶电泳对受体进行鉴定,最后通过傅里叶变换红外光谱探讨芳香烃受体与蒽结合后的结构变化.结果表明,提取的芳香烃受体在280 nm处有特征吸收峰,测得质量浓度为27.3 mg/mL.通过离子交换层析法纯化了单一组分的受体蛋白质,其相对分子质量约为110 kD.测定了芳香烃受体的红外光谱,与蒽结合后其在一定波段的谱峰发生了明显位移,表明污染物配体蒽能与芳香烃受体结合,并对其蛋白二级结构产生明显影响. 相似文献
296.
Ryszard Cholewa Dorothea Beutling Jolanta Budzyk Marian Pietrzak 《Journal of environmental science and health. Part. B》2013,48(8):590-594
A highly selective and sensitive method based on gas chromatography-tandem mass spectrometry (GC-MS/MS) to identify and quantify persistent organochlorine pesticides, (18 compounds including primary compounds and metabolites), in animal internal organs (kidneys, liver, and brain) has been developed. Tandem mass spectrometric conditions were individually optimized for each target compound in Multiple Reaction Monitoring (MRM) mode to obtain maximum sensitivity. Prior to instrumental analysis, a sample preparation method based on matrix solid phase dispersion (MSPD) followed by acidic digestion with sulfuric acid to reduce matrix co-extractives was employed. Analyses of real samples were carried out on coypus (Myocastor coypus) from the autumn slaughter of 19 animals. In the analyzed samples, three of the target compounds, namely DDE-pp′ (DDT metabolite), HCB and lindane, were detected. Their concentration levels fell in the ranges of 0.003–0.007, 0.003–0.025, and 0.003–0.021 mg kg?1 (0.005, 0.010, and 0.010 mg kg?1 on average) in the case of DDE-pp′, HCB and lindane, respectively. Although low quantities of organochlorine pesticides do not pose an immediate danger to consumers' health, they should be of public health concern considering long-term, low-dose exposure. 相似文献
297.
S. Otto W. Keller N. Drescher 《Journal of environmental science and health. Part. B》2013,48(3):179-191
Abstract A new gas chromatographic method reliable in the microgram range, was developed to measure ETU residues in various crops. Contrary to previously published procedures, this new method does not require prior derivatization of the ETU. The limit of sensitivity was shown to be 0.01 ppm using the flame photometric detector, FPD (sulfur mode, 394 nm). 相似文献
298.
浑河-大辽河水系水体与沉积物中典型全氟化合物的污染水平及生态风险评价 总被引:2,自引:0,他引:2
采用超高效液相色谱串联质谱(UPLC-ESI-MS/MS)分析了水体和沉积物中全氟化合物(PFCs)浓度水平,结果表明,浑河-大辽河的干流水中,PFCs总浓度范围为1.80~13.0 ng·L-1,其中,PFHx A、PFHp A、PFOA、PFOS和PFDA是主要污染物;沈阳细河中PFCs的总浓度为27.0~50.0 ng·L-1,其主要污染物为PFPA、PFOA、PFOS和PFDA.在浑河-大辽河沉积物中,PFHx A是唯一的检出物,其含量为0.130~0.490 ng·g-1干重;除了PFHx A,PFOS也是细河中的主要污染物,其浓度水平分别为0.070~0.220 ng·g-1和0.180~0.830 ng·g-1干重.采用实测的水和沉积物中PFOA和PFOS的暴露浓度以及预测的无效应浓度(PNEC),运用商值法对浑河-大辽河干流及沈阳细河水体和沉积物中PFOA和PFOS的生态风险进行评价.结果表明水体和沉积物中PFOA和PFOS的浓度均未达到对生态环境具有风险的水平. 相似文献
299.
建立了一种中空纤维膜液相微萃取的样品前处理技术,结合液相色谱法测定印染废水中芳香胺,并且优化了萃取溶剂、供体相、接收相、搅拌速度、萃取时间等前处理条件.实验结果表明,以正辛醇为萃取溶剂,0.1 mol·L-1Na OH为供体相,0.1 mol·L-1HCl为接收相时,400 r·min-1作为搅拌速度,30 min萃取后的芳香胺富集倍数可达到101—193倍,萃取效率达20.2%—38.6%.结合液相色谱检测芳香胺的线性范围为0.01—0.25 mg·L-1,检出限为1.0—2.0μg·L-1,回收率为95.2%—105.2%.表明该方法可用于检测印染废水中的芳香胺类物质. 相似文献
300.
In order to search the degradability of kraft lignin, the potential bacterial strains Bacillus subtilis (GU193980) and Klebsiella pneumoniae (GU193981) were isolated, screened and applied in axenic and co-culture conditions. Results revealed that mixed culture showed better decolorization efficiency (80%) and reduction of pollution parameters (COD 73% and BOD 62%) than axenic culture. This indicated syntrophic growth of these two bacteria rather than any antagonistic effect. The HPLC analysis of degraded samples of kraft lignin has shown the reduction in peak area compared to control, suggesting that decrease in color intensity might be largely attributed to the degradation of lignin by isolated bacteria. Further, the GC–MS analysis showed that most of the compounds detected in control were diminished after bacterial treatment. Further, the seed germination test using Phaseolus aureus has supported the detoxification of bacterial decolorized kraft lignin for environmental safety. All these observations have revealed that the developed bacterial co-culture was capable for the effective degradation and decolorization of lignin containing rayon grade pulp mill wastewater for environmental safety. 相似文献