Preparation,characterization of sludge adsorbent and investigations on its removal of hydrogen sulfide under room temperature

To recycle the sludge resource from sewage treatment plants and solve the problem of odor pollution, the sludge was converted into an adsorbent by carbonized pyrolysis and the process was optimized by orthogonal experiments. The capability for odor removal as well as the structure of the adsorbent was studied with H₂S as a target pollutant. The results indicate that the main factor affecting the deodorization performance of the adsorbent is the activating time. The sludge adsorbent sample SAC1 prepared under optimum conditions exhibits the best deodorization performance with a H₂S breakthrough time of 58 min and an iodine value nearly that of the coal activated carbon. The breakthrough time of H₂S is much longer than that on the coal activated carbon. On the other hand, characterization results from X-ray diffractometer (XRD), X-ray photoelectron spectrometer (XPS) and scanning electron microscope (SEM) techniques show that SAC1 is composed of mainly graphite carbon with lower oxygen content on the surface. The bulk of SAC1 exhibits a honeycomb structure with well developed porosity and a high specific surface area of 120.47 m²·g^-1, with the average pore diameter being about 5 nm. Such a structure is in favor of H₂S adsorption. Moreover, SAC1 is detected to contain various metal elements such as Zn, Fe, Mg, etc., leading to a superior deodorization property to that of coal activated carbon.     

Effects of cucl2 on UV‐mutagenesis and on DNA damage in a restriction fragment of E. Coli gpt∗

CuCl₂ does not cause Trp⁺ reversion in E. coli WP2. However, when the bacteria are exposed to CuCl₂ and UV‐irradiated, a greater than 3‐fold enhancement of mutagenesis (compared to UV alone) is seen at 30 μMCuCl₂, and significant enhancement is seen even at 3 μM. The mechanism for this comutagenic effect was studied using a restriction fragment of the E. coli gpt gene. Whereas UV or CuCl₂ alone caused few strand breaks, UV + CuCl₂ induced breaks at every site. This reaction was blocked by KI, a free radical scavenger. While UV alone induced alkali‐labile sites, UV+ CuCl₂ induced many more such sites and altered the sequence specificity. We suggest that at least some of the comutagenic effect might be due to hydroxyl radical formed via a Fenton reaction.     

Hydrogen sulfide removal by iron containing activated carbon

Activated carbon modified by impregnation with iron (III) chloride solution (Fe‐ACs) were studied to try to raise their adsorption capacity for hydrogen sulfide, a malodorous substance.

The surface area and pore volume of activated carbon were decreased by impregnation, but the amount of hydrogen sulfide adsorbed onto Fe‐AC was larger than that onto raw activated carbon (R‐AC). In particular, a large increase of the amount adsorbed onto Fe‐AC was noted at low equilibrium pressure. It was assumed that the increase of amount of hydrogen sulfide adsorbed onto Fe‐AC was due to the chemical interaction between iron (III) chloride on the pores in addition to the physical adsorption onto pores of activated carbon. Fe‐AC shows a high selectivity for hydrogen sulfide.     

Study on removing selenate from groundwater by autohydrogenotrophic microorganisms

Performance of autohydrogenotrophic bacteria for bio-reduction of selenate (Se(VI)) under anaerobic conditions was investigated with batch experiments. Results showed Se(VI) was bio-reduced to selenite (Se(IV)) as an intermediate product, and then to elemental selenium (Se⁰). Reduction kinetics could be described by the pseudo-first-order model. In particular, the influences of pH value and temperature on Se(VI) reduction by autohydrogentrophic organisms were examined. The high degradation rate was achieved at pH 7.0 to 8.0; and the best reduction temperature was between 25°C and 35°C. This study is of help for treating groundwater with selenium contamination by autohydrogenotrophic bacteria as well as its reactor development.     

粉煤灰增强超声/H2O2降解左氧氟沙星的实验研究

研究粉煤灰对超声/H2O2体系降解左氧氟沙星的增强效果,考察了粉煤灰添加量、H2O2浓度、溶液初始pH值、左氧氟沙星初始浓度等对降解效果的影响.结果表明,与单独超声,H2O2氧化,超声/H2O2,超声/粉煤灰,粉煤灰/H2O2氧化相比,粉煤灰有效增强了超声/H2O2体系对左氧氟沙星的降解,降解反应符合一级反应动力学.粉煤灰添加量为1.5g/L,H2O2浓度为15.0mmol/L,pH=7.16,超声功率325W,左氧氟沙星初始浓度20mg/L,反应160min,左氧氟沙星的去除率达到99.12%,TOC去除率为17.37 %.利用荧光探针法对不同体系产生的·OH浓度进行了分析比较,粉煤灰作为非均相催化剂,主要在于发生类Fenton反应.采用HPLC/MS/MS方法对3种反应产物进行了分析,结果表明左氧氟沙星主要是通过喹诺酮环失去-C2,哌嗪环去亚甲基化以及·OH进攻喹诺酮环发生降解.     

Process control factors for continuous microbial perchlorate reduction in the presence of zero-valent iron

Process control parameters influencing microbial perchlorate reduction via a flow-through zero-valent iron （ZVI） column reactor were investigated in order to optimize perchlorate removal from water. Mixed perchlorate reducers were obtained from a wastewater treatment plant and inoculated into the reactor without further acclimation. Examined parameters included hydraulic residence time （HRT）, pH, nutrients requirement, and perchlorate reduction kinetics. The minimum HRT for the system was concluded to be 8 hr. The removal efficiency of 10 mg. L-1 influent perchlorate concentration was reduced by 20%-80% without control to the neutral pH （HRT = 8 hr）. Therefore pH was determined to be an important parameter for microbial perchlorate reduction. Furthermore, a viable alternative to pH buffer was discussed. The microbial perchlorate reduction followed the first order kinetics, with a rate constant （K） of 0.761 hr-1. The results from this study will contribute to the implementation of a safe, cost effective, and efficient system for perchlorate reduction to below regulated levels.     

NO和H2O2对大豆幼苗铝毒害的缓解效应及其相互作用

NO和H₂O₂作为信号分子参与植物对非生物胁迫的响应,为了确定NO和H₂O₂介导的大豆耐铝作用以及二者的交互作用,以浙春3号大豆为材料,分析了铝毒胁迫下根尖内源及外源NO和H₂O₂对大豆铝毒的缓解效应,并研究了NO和H₂O₂代谢相关酶的活性变化, 其中外源NO由SNP(亚硝基铁氰化钠,Na₂[Fe(CN)₅NO]·2H₂O)提供. 结果显示:Al处理显著抑制大豆根生长,促使Al在根尖积累并显著提高大豆根尖内源w(NO)和w(H₂O₂). 在H₂O₂₊Al、SNP+Al和H₂O₂₊SNP+Al处理下,大豆根相对伸长率比单独Al处理下分别升高了64.6%、63.5%和69.5%,根尖w(Al)则分别减少了34.6%、36.8%和32.9%,表明NO和H₂O₂对铝毒害均具有缓解作用.外源NO能够促使根尖内源H₂O₂显著积累,降低POD(过氧化物酶)活性,而外源H₂O₂对内源根尖w(NO)无影响.NO和H₂O₂在缓解铝毒的信号途径中存在信号互作,NO处于H₂O₂的上游,其通过POD活性调节内源w(H₂O₂).      

含硫化氢天然气井公共安全技术标准体系比对研究

含硫化氢天然气井重大事故对公众安全具有重大危害,建立和完善含硫化氢天然气井公共安全技术标准体系,对于加强含硫气井应急管理,保护人民群众生命健康安全具有重要意义。针对含硫化氢天然气井公共安全技术标准,调研了加拿大和美国等国外含硫气井开发典型地区的含硫化氢天然气井公共安全技术标准体系,分析了其体系构成和标准内容,总结了其特点,比对国外含硫化氢天然气井公共安全技术标准体系,基于对国内的调研,分析了我国含硫化氢天然气井公共安全技术标准体系存在的不足;通过对国内外三百多项相关标准的调研和比对分析,基于我国实际现状,分析提出了标准体系建设的相关建议,为我国含硫化氢天然气井公共安全标准体系的完善和标准制定工作提供参考。     

高硫油炼制企业H_2S中毒风险分析

随着企业炼油规模不断扩大及原油中含硫量不断提高,炼油企业中H2S中毒事故风险迅速增大。在对高硫油炼制企业H2S的分布及危险源状况分析的基础上,指出炼油企业存在两类H2S危险源,即含有H2S的气体和含有H2S的酸性水,炼油装置产出含H2S的气体中H2S含量一般在1%～92%,酸性水中H2S含量一般在0.01%～4.0%;介绍了不同H2S浓度等级的空气可对人产生的毒性危害后果,H2S在空气中数分钟内致人死亡的浓度为1500mg/m3;对炼油企业重大酸性气泄漏事故、酸性水泄漏事故进行定量毒性危害计算和分析,给出H2S毒性危害低危区、高危区及迅速致死区达到的下风距离及覆盖的区域面积,重大酸性气、酸性水泄漏事故迅速致死浓度可达到下风距离分别为300m和89m;指出H2S中毒已成为高硫油炼制企业的重大风险,应该加强安全措施,重点防控。     

考虑区域特点和车型差异的氢燃料电池汽车全生命周期减碳预测分析

发展氢燃料电池汽车是我国实现“双碳”战略的重要路径之一,目前我国多个区域正在推广应用包括乘用车、客车以及重卡在内的氢燃料电池汽车,如何量化研究未来不同车型和不同区域的氢燃料电池汽车减碳潜力成为如今的研究热点之一.基于全生命周期的评价方法,考虑了未来的汽车燃油经济性、电力碳排放因子、氢能碳排放因子和氢燃料电池汽车推广规模及制氢方式的区域差异,量化评价了不同类型的氢燃料电池汽车（FCV）、传统燃油汽车（ICEV）和纯电动汽车（BEV）的全生命周期碳排放量（以CO₂当量计）,对比分析了氢燃料电池汽车在不同时间及不同区域的减碳潜力,并对百公里氢耗量进行了不确定性分析.结果发现,到2025年氢燃料电池客车的全生命周期碳排放比传统燃油客车降低36.0%,而氢燃料电池重卡相较于传统燃油重卡并没有减碳效益.随着未来我国氢能来源结构的不断优化,到2035年氢燃料电池重卡的全生命周期碳排放比传统燃油重卡降低36.5%,相较于乘用车和客车两种车型,其减碳效益是最明显的.以2035年京津冀示范群为例,随着百公里氢耗量降低20%,FCV乘用车、客车和重卡的减碳规模分别增加了7.29%、9.93%和19.57%.因此建议氢燃料电池汽车推广应短期以客车为主,长期以重卡为主,乘用车推广作为补充.分区域和分阶段推广氢燃料电池汽车更有助于推进我国汽车领域的低碳化进程.