全文获取类型
收费全文 | 306篇 |
免费 | 49篇 |
国内免费 | 106篇 |
专业分类
安全科学 | 89篇 |
废物处理 | 48篇 |
环保管理 | 21篇 |
综合类 | 181篇 |
基础理论 | 53篇 |
污染及防治 | 57篇 |
评价与监测 | 10篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 5篇 |
2022年 | 11篇 |
2021年 | 12篇 |
2020年 | 19篇 |
2019年 | 14篇 |
2018年 | 9篇 |
2017年 | 21篇 |
2016年 | 20篇 |
2015年 | 19篇 |
2014年 | 22篇 |
2013年 | 51篇 |
2012年 | 40篇 |
2011年 | 25篇 |
2010年 | 9篇 |
2009年 | 17篇 |
2008年 | 11篇 |
2007年 | 25篇 |
2006年 | 20篇 |
2005年 | 21篇 |
2004年 | 19篇 |
2003年 | 5篇 |
2002年 | 9篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 6篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有461条查询结果,搜索用时 218 毫秒
91.
建立了便携式顶空/气相色谱-质谱法测定硬质聚氨酯泡沫和组合聚醚中一氟三氯甲烷(CFC-11)、二氟二氯甲烷(CFC-12)、二氟一氯甲烷(HCFC-22)及一氟二氯乙烷(HCFC-141b)的定性分析方法,系统考察了色谱柱、顶空体系、顶空温度和顶空时间对测定结果的影响。结果表明,DB-WAX色谱柱对目标物质的分离效果最好,顶空温度为50℃、顶空时间为10 min条件下,目标物质的检测灵敏度最高。在优化条件下,硬质聚氨酯泡沫取样体积为1 cm3时,4种目标物的方法检出限为0.6~0.8 μg;组合聚醚取样量为10 mg时,4种目标物的方法检出限为0.5~0.6 μg。该方法具有较高的灵敏度,定性准确,适用于实际样品的现场快速定性分析。 相似文献
92.
93.
Mehlich 1(M1), mehlich 3(M3) and CaCl2 DTPA have been used to predict the available micronutrient in soil. However, the forms of micronutrient extractable by these extractants are not known. In the present study, ten soils, collected from five provinces and the capital of China, representing a wide range of chemical and physical properties, were analyzed by sequential extraction to isolate five forms of cobalt and nickel, they are exchangeable, carbonate bound, Fe Mn oxide bound, organically bound and residual forms. The chemical forms extracted by M1, M3 and CaCl2 DTPA were also investigated. The results show strong correlation between the carbonate bound or organically bound forms of Co or Ni and the amounts of extractable by any of the above three extractants. The main forms extracted by these extractants are carbonate and organically bound forms. The ranking of these three extractants for extraction of Co and Ni are M1>M3=CaCl2 DTPA and M1=M3>CaCl2 DTPA, respectively. 相似文献
94.
用镍矿渣生产建筑砌块研究 总被引:3,自引:1,他引:3
以碱激发磨细镍矿渣作为胶结材料,用破碎后的镍矿渣作为集料,研究了镍矿渣含量为94%,抗压强度达289MPa的镍矿渣建筑砌块。该种建筑砌块的研制成功,为镍矿渣的处理,开辟了一条途径。 相似文献
95.
探讨一种快捷有效的土壤样品消解方法,即采用王水-过氧化氢体系消化土壤样品。该法操作简便,减少了耗酸量与操作时间。测定结果精密度高,准确性好。 相似文献
96.
Fenton氧化-混凝联合工艺处理络合铜镍废水的研究 总被引:2,自引:0,他引:2
采用Fenton试剂氧化-混凝联合工艺对难处理络合铜镍电镀废水进行了研究,考察了废水初始pH值、H2O2初始浓度、[Fe^2+]/[H2O2]、反应时间和温度、混凝液pH、混凝剂质量浓度对处理过程的影响,探讨了废水的降解途径和机理.结果表明,在体系初始pH=4,温度30℃,H2O2投加量为800mg/L,[Fe^2+]/[H2O2]=0.1,反应时间60 min,混凝液pH=8及混凝剂质量浓度为500mg/L的条件下,废水的COD去除率为96.98%,Cu^2+为99.91%,Ni^2+为99.92%,处理水完全达到国家一级排放标准.同时依据GC/MS对X-GN降解最终产物的分析结果,推导出废水的基本降解机理和途径. 相似文献
97.
Influence of fertilizer and sewage sludge compost on yield and heavy metal accumulation by lettuce grown in urban soils 总被引:8,自引:0,他引:8
S. B. Sterrett R. L. Chaney C. H. Gifford H. W. Mielke 《Environmental geochemistry and health》1996,18(4):135-142
Previous research has demonstrated that many urban soils are enriched in Pb, Cd and Zn. Culture of vegetable crops in these soils could allow transfer of potentially toxic metals to foods. Tanya lettuce (Lactuca sativa L.) was grown in pots of five urban garden soils and one control agricultural soil to assess the effect of urban-soil metal enrichment, and the effect of soil amendments, on heavy metal uptake by garden vegetables. The amendments included NPK fertilizer, limestone, Ca(H2PO4)2, and two rates of limed sewage sludge compost. Soil Cd ranged from 0.08 to 9.6 mg kg–1; soil Zn from 38 to 3490 mg kg–1; and soil Pb from 12 to 5210 mg kg–1. Lettuce yield on the urban garden soils was as great as or greater than that on the control soil. Lettuce Cd, Zn and Pb concentrations increased from 0.65, 23, and 2.2 mg kg–1 dry matter in the control soil to as high as 3.53, 422 and 37.0 mg kg–1 on the metal-rich urban garden soils. Adding limestone or limed sewage sludge compost raised soil pH and significantly reduced lettuce Cd and Zn, while phosphate fertilizer lowered soil pH and had little effect on Zn but increased Cd concentration in lettuce. Urban garden soils caused a significant increase in lettuce leaf Pb concentration, especially on the highest Pb soil. Adding NPK fertilizer, phosphate, or sludge compost to two high Pb soils lowered lettuce Pb concentration, but adding limestone generally did not. On normally fertilized soils, Pb uptake by lettuce was not exceptionally high until soil Pb substantially exceeded 500 mg kg–1. Comparing garden vegetables and soil as potential sources of Pb risk to children, it is clear that the risk is greater through ingestion of soil or dust than through ingestion of garden vegetables grown on the soil. Urban dwellers should obtain soil metal analyses before selecting garden locations to reduce Pb risk to their children. 相似文献
98.
99.
100.
通过接种亚硝化与厌氧氨氧化污泥,以无机高氨氮(110~130mg/L)废水为对象,研究上流式双层填料反应器的启动与运行.反应器上层与下层分别以沸石和聚氨酯海绵作为填料,启动两种填料高度比分别为2:3和3:2的1号和2号反应器,历时139d成功建立自养脱氮系统.结果表明,1号反应器最高总氮去除率达84.4%,2号最高总氮去除率达81.8%,总氮去除负荷分别达0.15,0.14kgN/(m3·d).进水未添加有机碳源时,2号△NO3--N/△NH4+-N一直稳定在特征值0.11附近,自养脱氮系统更为稳定.在添加有机碳源情况下,2个反应器总氮去除率都得到提升,△NO3--N/△NH4+-N也更为稳定.说明一定浓度的有机物能强化系统稳定运行,提高系统脱氮性能.反冲洗稳定后,1号反应器出水NO3--N由未反冲洗前的17.61mg/L降低到10mg/L以下,说明适当的反冲洗可以有效恢复反应器运行,反冲洗与NOB抑制手段相结合能更好地维持反应器的长期稳定运行. 相似文献