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21.
IntroductionTheo chlorophenolisaverytoxicandpoorlybiodegradablepollutant,whichisusedasanintermediateinthemanufactureofhigherchlorophenolandphenolresinsandforextractingsulphurandnitrogencompoundsfromcoals.Itisalsousedinorganicsynthesis(dyesandpesticide) .Oxidationofo chlorophenolwastewaterincatalyticwetairoxidationisofpracticalinterestsinceawastewatercontainingo chlorophenolover 2 0 0ppmmaynotbetreatedeffectivelybydirectbiologicalmethods.Advancedoxidationprocesses(AOPs)havebeensuccessfullyuse… 相似文献
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1IntroductionNovelbiologicalactivatedcarbonandactivatedsludgesystemhasshownitsefectiveabilitytoreduceCODintoxicorganicwastewa... 相似文献
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Based on wet air oxidation (WAO) and Fenton reagent, thispaper raises a new low pressure wet catalytic oxidation(LPWCO)which requires low pressure for the treatment of highlyconcentrated and refractory organic wastewater. Compared withgeneral wet air oxidation, the pressure of the treatment(0.1-0.6MPa) is only one of tens to percentage of latter(3.5-10MPa). Inaddition, its temperature is no more than 180℃.Compared withFenton reagent, while H2O2/COD(weight ratio) less than 1.2, theremoval of COD in the treatment is over twenty percents more thanFenton's even the value of COD is more than 14000mg/L. In thispaper, we study the effect factor of COD removal and the mechanismof this treatment. The existence of synergistic effect (catalytic oxidation and carbonization) for COD removal in H2SO4-Fenton reagent system under the condition of applied pressure and heating (0.1-0.6MPa, 104-165℃) was verified. The best condition of this disposal are as follows:H2O2/COD(weight ratio)=0.2-1.0, Fe2+ 0.6×10-3 mol, H2SO4 0.5mol, COD>1×104mg/L, the operating pressure is 0.1-0.6MPa and temperature is 104-165℃. This method suit to dispose the high-concentrated refractory wastewater, especially to the wastewater containing H2SO produced in the manufacture of pesticide, dyestuff and petrochemical works. 相似文献
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Li Yongmei Li Wenshu Gu Guowei 《Frontiers of Environmental Science & Engineering in China》2007,1(4):493-497
Batch experiments were carried out to investigate the promotive effect of pyridine on indole degradation under denitrifying
conditions. The seed sludge was obtained from a local coal-coking wastewater treatment facility and was acclimated in the
laboratory. Indole and pyridine were supplemented to the synthetic wastewater at different ratios. The optimum ratio of chemical
oxygen demand (COD) to nitrate (C/N) was 8.4–8.9 for both denitrification and indole and pyridine degradation. At a temperature
of 28°C and pH of 7.0–7.5, the nitrate reductase activity (NRA) was in the best state. The addition of pyridine could promote
NRA and the degradation of indole. When the initial concentration of indole was 150 mg/L, the concentration ratio of indole
to pyridine was in the range of 1–10. Under optimum C/N conditions, the degradation of indole could be described with pseudo-zero-order
kinetics. There was no accumulation of nitrite during the reaction. When the concentration ratio of pyridine to indole was
less than 0.25 with an increase in the pyridine proportion, there were more significant augment rates for NRA and the degradation
of indole than the situation when the concentration ratio was more than 0.25.
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Translated from Environmental Science, 2006, 27(2): 300–304 [译自: 环境科学] 相似文献
28.
对含柠檬酸盐电镀废水的几种处理方法的比较表明,氯化钡添加法能较好地使柠檬酸盐沉淀,操作简便,处理效果理想,其柠檬酸根离子的去除率达98%以上。 相似文献
29.
高浓度印染废水处理工程工艺条件与实例分析 总被引:8,自引:0,他引:8
研究以三相生物流化床作为工程化反应器处理印染废水的工程工艺条件及操作特性,分别测定流化床内的气相含率,兴体循环速度及体积氧传质系数。 相似文献
30.
对石油亚砜(PSO)萃取巯基醋酸的条件和影响进行了实验研究,确定了石油亚砜通过氢键和巯基醋酸形成的萃合物的组成.为从废水中回收巯基醋酸以及石油硫醚的综合利用提供了依据. 相似文献