全文获取类型
收费全文 | 175篇 |
免费 | 21篇 |
国内免费 | 168篇 |
专业分类
安全科学 | 9篇 |
废物处理 | 7篇 |
环保管理 | 2篇 |
综合类 | 239篇 |
基础理论 | 36篇 |
污染及防治 | 54篇 |
评价与监测 | 17篇 |
出版年
2023年 | 3篇 |
2022年 | 8篇 |
2021年 | 12篇 |
2020年 | 11篇 |
2019年 | 22篇 |
2018年 | 19篇 |
2017年 | 23篇 |
2016年 | 16篇 |
2015年 | 17篇 |
2014年 | 21篇 |
2013年 | 21篇 |
2012年 | 13篇 |
2011年 | 19篇 |
2010年 | 11篇 |
2009年 | 21篇 |
2008年 | 10篇 |
2007年 | 26篇 |
2006年 | 17篇 |
2005年 | 7篇 |
2004年 | 17篇 |
2003年 | 12篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 3篇 |
排序方式: 共有364条查询结果,搜索用时 15 毫秒
81.
研究以50~100目的海绵状铁粉为还原剂,采用静态试验方法,研究了铁对硝酸盐氮的还原作用及其影响因素,分析了铁粉用量、铁炭比、pH值、硝酸盐氮初始浓度、温度以及铁粉表面预处理对硝酸盐去除率的影响。试验结果表明,最佳铁氮质量比为400∶1,铁粉投入过多对硝酸盐的去除率没有进一步促进;活性炭的加入有助于零价铁(Fe0)还原硝酸盐,降低反应后溶液中的NH+4-N浓度,试验最佳的铁炭比为1∶2;溶液的初始pH值降低有利于硝酸盐氮的去除;硝酸盐氮初始浓度越大,反应的平均速率越高;升高温度和酸洗预处理,有利于提高硝酸盐的去除率;产物分析表明,试验过程中,去除的NO-3-N含量中约60%以上转化为NH+4-N,NO-2-N浓度很低。 相似文献
82.
限量曝气进水时间对硝化颗粒污泥的影响特性研究 总被引:1,自引:1,他引:0
缺氧-好氧环境的交替循环对氨氧化细菌和亚硝酸盐氧化细菌具有重要影响.本研究通过逐渐增加限量曝气进水时间(从10 min至120 min)延长缺氧时段,考察柱形SBR中硝化颗粒污泥对不同缺氧-好氧环境交替循环的响应特性.整个研究过程中,硝化颗粒污泥保持着稳定的颗粒特征,粒径大于0.8 mm的颗粒污泥占总污泥量的质量分数始终在95%以上,颗粒平均沉降速率维持在125~130 m·h-1之间.尽管缺氧时段不断延长,但NH+4-N去除率和NO-2-N累积率分别稳定在(60±5)%、(85±5)%;此外,在每个周期的曝气反应时段,NH+4-N的去除速率以及NO-2-N和NO-3-N的累积速率分别保持在90mg·(L·h)-1、70 mg·(L·h)-1和15 mg·(L·h)-1左右.以上结果表明,限量进水时间的延长及其所造成的不同时间跨度的缺氧环境对硝化颗粒污泥没有较为显著的影响. 相似文献
83.
本文报道在0.1M亚硝酸钠,1.5×10~(-3)M的1,2-丙二胺,pH9.0—9.5底液中铬在—1.76伏处(对饱和甘汞电极)产生-催化波,测定范围在0.1ng/ml内,铬的浓度与导数波高成良好线性关系,测定下限为8×10~(-10)M(相当于0.04ng/ml)。经实验证明,在1,2-丙二胺-亚硝酸盐或硝酸盐两体系中,铬都在—1.76伏处产生催化波,因此,可认为铬的催化机理可能与文献[3]报道的在CyDTA-NO_3体系中三价铬产生催化波的机理相似即: Cr~(6 ) 3e—→Cr~(3 ); Cr~(3 ) y—→Cr~(3 )—y; Cr~(2 )—y e—→C~(2 )—y; Cr~(2 )—y NO_3~—→Cr~(3 )—y No_2~-其中:y代表1,2-丙二胺。将自来水进行简单的前处理后,可以直接应用本法测定水中六价、三价铬的含量以及水中的总铬量。 相似文献
84.
Operational and Design Considerations of a Trickling Filter for Ammonia Removal from Potable Water 总被引:1,自引:0,他引:1
We studied the steady-state behavior of a mathematical model of a nitrifying trickling filter. In particular, we studied the effect of the operating conditions of the filter on the complete and safe nitrification. We presented the results with the help of the operating diagram of the system and we determined the range of operating conditions resulting in optimal operation. We also computed biofilm thickness along the filter depth and concentration profiles inside the biofilm, and compared them with experimental results found in the literature. The comparison shows very good qualitative agreement between model predictions and experimental data. 相似文献
85.
Molybdenum (Mo) deficiency and nitrogen contamination have been proved to be relevant to the higher incidence of esophageal cancer. In order to reduce the amount of nitrate and nitrite in grains and vegetables, ammonium molybdate has been used as a trace-element fertilizer in Linxian County, a high risk area of esophageal cancer. This supplementation has significantly raised the yield and the Mo content of the crops. The nitrate and nitrite levels in crops and vegetables were reduced by 12-53 and 20-32% respectively. The amount of ascorbic acid in vegetables which can block the in vivo synthesis of nitroso compounds is increased by 10-70%.Taking the inhibitory effect of Mo on cancer into account, Mo supplement by using Mo fertilizer probably can serve as an effective chemoprevention measure against this disease in high risk areas. 相似文献
86.
为了测定使用甲醇燃料的发动机排气里的亚硝酸甲酯(MeONO)和硝酸甲酯(MeONO_2)含量,建立了色谱分析方法。本方法的最小检测限MeONO为20ppb,MeONO_2为50ppb。对自制的MeONO和MeONO_2进行了质谱鉴定,并对所制备的一定浓度的样品进行了稳定性考察。应用本方法测定了甲醇机排气中的MeONO含量为5ppm—250ppm,MeONO_2含量为<50ppb。 相似文献
87.
A fuzzy logic approach has been developed to assess the groundwater pollution levels below agricultural fields. The data collected
for Kumluca Plain of Turkey have been utilized to develop the approach. The plain is known with its intensive agricultural
activities, which imply excessive application of fertilizers. The characteristics of the soils and underlying groundwater
for this plain were monitored during the years 1999 and 2000. Additionally, an extensive field survey related to the types
and yields of crops, fertilizer application and irrigation water was carried out. Both the soil and groundwater have exhibited
high levels of nitrogen, phosphorus and salinity with considerable spatial and temporal variations. The pollution level of
groundwater at several established stations within the plain were assessed using Fuzzy Logic. Water Pollution Index (WPI)
values are calculated by Fuzzy Logic utilizing the most significant groundwater pollutants in the area namely nitrite, nitrate
and orthophosphate together with the groundwater vulnerability to pollution. The results of the calculated WPI and the monitoring
study have yielded good agreement. WPI indicated high to moderate water pollution levels at Kumluca plain depending on factors
such as agricultural age, depth to groundwater, soil characteristics and vulnerability of groundwater to pollution. Fuzzy
Logic approach has shown to be a practical, simple and useful tool to assess groundwater pollution levels. 相似文献
88.
接种0~4℃贮存2个月亚硝酸盐反硝化颗粒污泥,以甲醇为电子供体、亚硝酸盐为电子受体在USB(上流式污泥床)反应器内进行二次启动。结果显示,在逐步提高进水负荷下,约46 d完成了反应器二次启动,污泥床负荷达到3.43 g N/(L·d),NO2-N去除率为99%;在稳定运行阶段,当进水NO2-N浓度为50 mg/L、负荷从1.7 g N/(L·d)逐步提高至5.1 g N/(L·d)时,NO2-N去除率均大于98%;当表观流速为2.68 m/h、进水负荷逐步提高至8.0 g N/(L·d)时,脱氮率下降至63%,过程中污泥床最大去除速率约为5.7 g N/(L·d)。研究认为,亚硝酸盐颗粒污泥床具有稳定和去除效率高等特点。 相似文献
89.
90.