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451.
在陶瓷填料上负载了P25纳米TiO2,对薄膜的制备和甲苯蒸汽在薄膜上的光催化降解进行了研究。在制备过程中得出如下结论:通过增加浸渍-提拉的次数来提高甲苯降解率的方法是有限的,采用长时间的浸渍或者采用自制粘结剂作下涂层都能大幅度提高甲苯的降解率,甲苯的降解率随镀膜量的增加而增加;在光催化过程中得出如下结论:甲苯的降解率随着湿度的增加而增加,随着甲苯初始浓度的增加而减小;甲苯的降解所需要的光强是一定的,在一定的范围内,甲苯的降解率随着光强的增大而增大,但是超过这个范围的过大的光强并不能提高甲苯的降解率,对于相同的光强,254 nm紫外光的降解率远大于365 nm紫外光的降解率。 相似文献
452.
453.
电化学法处理苯酚模拟废水的研究 总被引:2,自引:0,他引:2
电化学法处理废水中有机污染物,具有效率高、操作简便、与环境兼容等优点,是一种很有潜力的高级氧化技术。实验是以废旧一号干电池中的碳棒作电极,用烧杯作电解池,在室温下,通过改变支持电解质(Na2SO4)浓度、负载电压、pH值和苯酚初始浓度等影响因素,对苯酚模拟废水进行电化学处理,利用高效液相色谱仪对其处理效果进行了分析研究,结果表明:支持电解质(Na2SO4)浓度为20.0g/L、负载电压为5.5V、pH值为8.0是处理苯酚模拟废水的最佳条件。最后对苯酚的降解机理进行了初步探讨。 相似文献
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455.
Yuhong SU Xueyun YANG Cary T CHIOU 《Frontiers of Environmental Science & Engineering in China》2008,2(4):468-474
To access the influence of a vegetation on soil microorganisms toward organic pollutant biogegration, this study examined
the rhizospheric effects of four plant species (sudan grass, white clover, alfalfa, and fescue) on the soil microbial community
and in-situ pyrene (PYR) biodegradation. The results indicated that the spiked PYR levels in soils decreased substantially compared to
the control soil without planting. With equal planted densities, the efficiencies of PYR degradation in rhizosphere with sudan
grass, white clover, alfalfa and fescue were 34.0%, 28.4%, 27.7%, and 9.9%, respectively. However, on the basis of equal root
biomass the efficiencies were in order of white clover >> alfalfa > sudan > fescue. The increased PYR biodegradation was attributed
to the enhanced bacterial population and activity induced by plant roots in the rhizosphere. Soil microbial species and biomasses
were elucidated in terms of microbial phospholipid ester-linked fatty acid (PLFA) biomarkers. The principal component analysis
(PCA) revealed significant changes in PLFA pattern in planted and non-planted soils spiked with PYR. Total PLFAs in planted
soils were all higher than those in non-planted soils. PLFA assemblages indicated that bacteria were the primary PYR degrading
microorganisms, and that Gram-positive bacteria exhibited higher tolerance to PYR than Gram-negative bacteria did. 相似文献
456.
457.
选取辽宁省1981-2009年经济与环境数据,通过计量模型探讨辽宁省经济增长与环境质量的演替轨迹.结果表明,1981-2009年辽宁省环境库兹涅茨曲线大体呈现“倒U形+U形+倒U形”特征,即“M形”,表明辽宁省的综合环境污染水平随经济增长呈现波动变化;工业废水排放量、工业废气排放量、工业固体废物产生量等单项指标的环境库兹涅茨曲线形态分别为“U形”曲线左侧部分、“U形+倒U形”和“U形”曲线右侧部分;进一步分析表明,辽宁省EKC特征与工业结构变化、环境保护投资等有显著相关性. 相似文献
458.
以绢云母为载体,采用水解-沉淀法制备出了绢云母负载纳米TiO2粉体(TiO2/M),以尿素为氮源,采用后掺杂法制得具有可见光响应的N掺杂TiO2/M.采用XRD,XPS,SEM,DUV等手段对样品进行了性能表征;并以日光色镝灯为光源,甲基橙为模拟污染物检测其光催化活性.研究了N的掺杂对粉体中TiO2晶相结构,粒度和光催化性能的影响.结果表明,绢云母与TiO2通过桥氧相连形成包覆层,N的掺杂抑制了TiO2晶粒的长大,减缓锐钛矿向金红石相的转变,同时N的掺杂形成Ti—O—N键,形成新的能级结构,使样品对光的吸收边红移至440—550 nm,具有明显的可见光响应,对甲基橙的光催化降解率与没有掺N的样品相比,最高可达1.6倍. 相似文献
459.
Yu TianJianguo Wu Andrew T. SmithTianming Wang Xiaojun KouJianping Ge 《Ecological modelling》2011,222(17):3166-3180
The Amur tiger (Panthera tigris altaica) is a flagship species of the boreal forest ecosystem in northeastern China and Russia Far East. During the past century, the tiger population has declined sharply from more than 3000 to fewer than 600 individuals, and its habitat has become much smaller and greatly fragmented. Poaching, habitat degradation, habitat loss, and habitat fragmentation have been widely recognized as the primary causes for the observed population decline. Using a population viability analysis tool (RAMAS/GIS), we simulated the effects of poaching, habitat degradation, habitat loss, and habitat fragmentation on the population dynamics and extinction risk of the Amur tiger, and then explored the relative effectiveness of three conservation strategies involving improving habitat quality and establishing movement corridors in China and Russia. A series of controlled simulation experiments were performed based on the current spatial distribution of habitat and field-observed vital rates. Our results showed that the Amur tiger population could be viable for the next 100 years if the current habitat area and quality were well-maintained, with poaching strictly prohibited of the tigers and their main prey species. Poaching and habitat degradation (mainly prey scarcity) had the largest negative impacts on the tiger population persistence. While the effect of habitat loss was also substantial, habitat fragmentation per se had less influence on the long-term fate of the tiger population. However, to sustain the subpopulations in both Russia and China would take much greater conservation efforts. The viability of the Chinese population of tigers would rely heavily on its connectivity with the largest patch on the other side of the border. Improving the habitat quality of small patches only or increasing habitat connectivity through movement corridors alone would not be enough to guarantee the long-term population persistence of the Amur tiger in both Russia and China. The only conservation strategy that allowed for long-term persistence of tigers in both countries required both the improvement of habitat quality and the establishment of a transnational reserve network. Our study provides new insights into the metapopulation dynamics and persistence of the Amur tiger, which should be useful in landscape and conservation planning for protecting the biggest cat species in the world. 相似文献
460.
为评价二氯喹啉酸在水稻及其土壤中的安全性,建立其在水稻上的使用规范,于2008、2009年在杭州、济南和铁力三地进行田间试验,研究了二氯喹啉酸在水稻、土壤和田水中消解动态及最终残留量。建立了二氯喹啉酸在水稻、土壤和田水中残留量的超高效液相色谱串联质谱测定方法。在添加水平5~100μg.kg-1范围内,二氯喹啉酸的平均回收率在81.6%~105.7%之间,相对标准偏差均低于17.9%。残留试验结果表明,二氯喹啉酸在植株、土壤和田水中消解均符合一级动力学方程,消解半衰期分别为16.4~18.6、16.6~21.9和15.4~16.9 d;二氯喹啉酸在植株、土壤、糙米和稻壳中最终残留量均未检出(〈5μg.kg-1)。若二氯喹啉酸在水稻中的最高残留限量推荐值为0.5 mg.kg-1,建议每年以有效成分25 g.mu-1的剂量,于水稻移栽后10 d喷施1次,用于防治水稻田中稗草。 相似文献