Disentangling technological innovations: a micro-econometric analysis of their determinants

On the basis of a unique firm-level dataset from the German manufacturing sector, this paper empirically examines the determinants of environmental and non-environmental product and process innovations. The micro-econometric analysis with multivariate probit models points to an extremely high relevance of R&D activities for all technological innovation types, as well as to the relevance of a few market pull factors. The estimation results additionally reveal the importance of organisational measures for environmental product and process innovations. In this regard, not only certified environmental management systems, but also specific process- and product-related environmental organisational measures and even general organisational measures, such as the certification of a quality management system according to ISO 9001, play a crucial role. The estimation results therefore suggest the encouragement of firm-internal R&D activities and organisational measures by (environmental) policy in order to stimulate environmental technological innovations, which are able to both limit the environmental burden and contribute to the technological modernisation of the economy.     

Impact of pregnancy and other factors including smoking on the urinary levels of triclosan

Data from National Health and Nutrition Examination Survey were used to evaluate the impact of pregnancy on the levels of triclosan (TCS) in urine. Regression models were fitted to evaluate this association with adjustment for other factors that may affect the levels of TCS. Pregnant females had higher levels of TCS than non-pregnant females but the differences were not statistically significant. Levels of TCS were statistically significantly lower during the second trimester than during the third trimester. Smoking was associated with statistically significantly lower levels of TCS. The reasons for the association between smoking and the levels of TCS are not known. Further research is needed in this area.     

苯酚、2,4-二氯酚与苯胺类化合物联合毒性效益

采用藻类生长抑制实验测定了苯酚、2,4-二氯酚与6种苯胺衍生物对斜生栅列藻的单一毒性和二元混合物的联合毒性,得到化合物单独存在时的半抑制浓度EC50和共存时的半抑制浓度EC50mix。采用毒性单位法、相加指数法、混合毒性指数法和相似性参数法进行联合毒性评价,结果表明：苯酚＋2,4-二氯胺、苯酚＋二苯胺及苯酚＋苯胺等毒性混合时主要表现为协同作用;而其它二元混合物采用不同方法评价联合毒性结果有差异。当苯酚与苯胺按照不同毒性配比混合时（1︰4,4︰1,1︰1,2︰1）,表现为协同作用。以辛醇/水分配系数法为结构描述符,分别建立了单一毒性和联合毒性的定量构效关系（QSAR）模型。结果表明,苯酚、2,4-二氯酚与苯胺类化合物对斜生栅列藻的毒性主要与化合物在生物体内的分配作用有关。     

Wintertime peroxyacetyl nitrate (PAN) in the megacity Beijing: Role of photochemical and meteorological processes

Previous measurements of peroxyacetyl nitrate(PAN) in Asian megacities were scarce and mainly conducted for relative short periods in summer. Here, we present and analyze the measurements of PAN, O3, NOx, etc., made at an urban site(CMA) in Beijing from 25 January to 22 March 2010. The hourly concentration of PAN averaged 0.70 × 10 9mol/mol(0.23 × 10 9–3.51 × 10 9mol/mol) and was well correlated with that of NO2but not O3, indicating that the variations of the winter concentrations of PAN and O3in urban Beijing are decoupled with each other. Wind conditions and transport of air masses exert very significant impacts on O3, PAN, and other species. Air masses arriving at the site originated either from the boundary layer over the highly polluted N-S-W sector or from the free troposphere over the W-N sector. The descending free-tropospheric air was rich in O3, with an average PAN/O3ratio smaller than 0.031, while the boundary layer air over the polluted sector contained higher levels of PAN and primary pollutants, with an average PAN/O3ratio of 0.11. These facts related with transport conditions can well explain the observed PAN-O3decoupling. Photochemical production is important to PAN in the winter over Beijing. The concentration of the peroxyacetyl(PA) radical was estimated to be in the range of 0.0014 × 10 12–0.0042 × 10 12 mol/mol. The contributions of the formation reaction and thermal decomposition to PAN's variation were calculated and found to be significant even in the colder period in air over Beijing, with the production exceeding the decomposition.     

Characteristics of ozone and ozone precursors (VOCs and NOx) around a petroleum refinery in Beijing, China

A field measurement campaign for ozone and ozone precursors(VOCs and NOx) was conducted in summer 2011 around a petroleum refinery in the Beijing rural region. Three observation sites were arranged, one at southwest of the refinery as the background, and two at northeast of the refinery as the downwind receptors. Monitoring data revealed the presence of serious surface O3 pollution with the characteristics of high average daily mean and maximum concentrations(64.0 and 145.4 ppbV in no-rain days, respectively) and multi-peak diurnal variation. For NOx, the average hourly concentrations of NO2 and NO were in the range of 20.5–46.1 and 1.8–6.4 ppbV, respectively. For VOC measurement, a total of 51 compounds were detected. Normally, TVOCs at the background site was only dozens of ppbC, while TVOCs at the downwind sites reached several hundreds of ppbC. By subtracting the VOC concentrations at background, chemical profiles of VOC emission from the refinery were obtained, mainly including alkanes(60.0% ± 4.3%), alkenes(21.1% ± 5.5%) and aromatics(18.9% ± 3.9%). Moreover, some differences in chemical profiles for the same measurement hours were observed between the downwind sites; the volume ratios of alkanes with low reactivity and those of alkenes with high reactivity respectively showed an increasing trend and a decreasing trend. Finally, based on temporal and spatial variations of VOC mixing ratios, their photochemical degradations and dispersion degradations were estimated to be 0.15–0.27 and 0.42–0.62, respectively, by the photochemical age calculation method, indicating stronger photochemical reactions around the refinery.     

火灾中人员的行为及其模拟计算方法的研究

在综合分析国内外人员疏散模型和模拟软件发展现状的基础上,研究人员在火灾中的行为理论、计算机模型、模拟原理等,并介绍了目前国际上研究人员行为方面综合功能较强的Building EXODUS软件的原理和特点,最后以具体实例说明了Building EXODUS软件在人群疏散模拟分析中的具体应用.研究表明,1)在不考虑其他因素的影响下,疏散总时间与人数成正比;2)在火灾等紧急情况下,当某个出口不能通行时,可能会使大量人员在另一个出口处造成"瓶颈"现象,因此,增加备用安全出口很重要;3)疏散时间实际上是一随机变量,会因各种情况的变化而不同,如在很大程度上受人员特性(如年龄等因素)的影响,传统计算方法一般会低估疏散时间而不能作为建筑疏散设计的依据;4)利用计算机模拟软件可以对火灾中各种可能发生的情况进行评价,评价结果比传统方法更科学、可信.火灾中人员行为的研究需要从心理学和社会学角度建立人群中个人行为与社会行为的理论框架,而疏散模拟是一个由多个因素组成的复杂系统,大量人群环境的模拟需要涉及人与人、人与环境间的相互作用.     

Development of a Dynamic Aquatic Model (DynA Model): Estimating Temporal Emissions of DDT to Lake Maggiore (N. Italy)

- DOI: http://dx.doi.org/10.1065/espr2006.01.009 Background, Aims and Scope Most existing models used to describe the fate of chemicals in surface water and sediment generally consider a 'static scenario', in which a contaminant is discharged at a constant rate and environmental input parameters do not change during the simulation time. This approach is not suitable in environmental scenarios characterized by daily or periodic changes of several input parameters. The aim of this study is to estimate approximate emissions of DDT lo Lake Maggiore using a new surface water model, (DynA Model) that describes the fate of a chemical in a dynamic scenario. Methods The model is developed on the grounds of an existing and validated model (QWASI). A numerical solution was adopted to build the fully dynamic version of the model. Results and Discussion The model was applied to Lake Maggiore emitting DDT at a constant rate until steady-state was reached. Emissions were stopped and later sporadic 'pulse' emissions were added. This was done to calculate the amount of DDT needed to simulate concentrations close to those measured in water and sediments. This allowed the evaluation of the order of magnitude of emissions. An uncertainty analysis for sediment resuspension was also performed, given the lack of measured resuspension rates. Conclusion The model showed the time response of the Lake Maggiore system to varying emission scenarios and provided what are regarded as reasonable estimates of DDT emissions. The model demonstrated the importance of sediment-water exchange. Recommendation and Outlook In order to better calculate DDT concentrations the model should be run with different discharge scenarios to clarify the time trends of concentrations, possibly with the use of different sets of measured data (such as biota and sediment deposition/resuspension rates).     

The impact of European Regional Development Fund on separate waste collection: Evidence from Italian regions

We analyze the impact of Regulation (EC) No 1080/2006 on separate collection rate of Italian regions. We exploit longitudinal data for 20 NUTS-2 Italian regions and eighteen years (from 1996 to 2013). We identify regions which are exposed to “Convergence” objective as the treatment group and regions which are not exposed to this objective as the control group and use a Difference in differences estimation. The estimates suggest that the Regulation (EC) No 1080/2006 has not influenced the convergence process among the Italian regions. The main policy implications are discussed.     

Local survival of pied flycatcher males and females in a pollution gradient of a Cu smelter

Survival is one of the most central population measures when the effects of the pollution are studied in natural bird populations. However, only few studies have actually measured rigorous survival estimates on adult birds. In recent years there has been a methodological advance in survival analyses by mark-recapture models. We modelled local survival (including mortality and emigration) with the program MARK in a population of a small insectivorous passerine bird, the pied flycatcher (Ficedula hypoleuca), around a point source of heavy metals. The local survival of females in the polluted area was about 50% lower than in the other areas. Males, however, survived relatively well in the heavily polluted area, but showed somewhat lower survival in the moderately polluted area. Different pollution effects between two sexes might be due to pollution-related differences in reproductive effort in females and males, and/or more intensive uptake of heavy metals by laying females.