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101.
研究了用聚合氯化铝(PAC)、聚合硫酸铁(PFS)、聚丙烯酰胺(PAM)及改性蒙托石等不同无机—有机高分子絮凝剂复配使用处理炼钢厂连铸含油废水的除油效果,考察了不同絮凝剂的复配以及絮凝剂的不同复配比例对处理效果的影响。试验结果表明,用聚合氯化铝(PAC)+聚合硫酸铁(PFS)+聚丙烯酰胺(PAM)3种絮凝剂复配使用除油效果最佳,当3种絮凝剂的复配比为2∶2∶3时除油效果最好,除油率达到88.2%,达到国家排放标准。 相似文献
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103.
ABSTRACT: Following an enclosure of a sink-hole connecting Lake Tarpon to the Gulf of Mexico, the chloride concentration of lake waters decreased. Water and chloride budgets for the lake in 1975 were prepared, and predictions using the model of Lerman and Brunskill (1971) were made as to the time required for the lake to achieve fresh water status. Model verification indicated good agreement with predictions in 1976; however, data on [C1-] for 1977 and 1978 are not as supportive of the model used. The information concerning the Lake Tarpon watershed provided by this latter fact is discussed. 相似文献
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105.
Chloride ingress and freeze-thaw cycles are the most important mechanisms for deterioration of concrete in cold areas. In this study, chloride ingress into concrete that has been exposed to freeze-thaw cycles was investigated. Data demonstrated that freeze-thaw cycles allow for a larger effective diffusion coefficient. Based on our findings, the concept of a developing coefficient was defined to obtain the evolution equation of the effective diffusion coefficient. Together with considering the effect of aging of concrete on the effective diffusion coefficient, the time-dependent diffusion coefficient was also obtained. Based on Fick's second law and time-dependent diffusion coefficient, chloride ingress model of concrete in cold regions was derived. Finally, the model was tested by comparing predicted results, lab results, and in situ inspection data. 相似文献
106.
The elemental mercury removal abilities of three different zeolites (NaA, NaX, HZSM-5) impregnated with iron (III) chloride were studied on alab-scale fixed-bed reactor. X-ray diffraction, nitrogen adsorption porosimetry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and temperature programmed desorption (TPD) analy-ses were used to investigate the physicochemical properties. Results indicated that the pore structure and active chloride species on the surface of the samples are the key factors for physisorption and oxidation of Hg0, respectively. Relatively high surface area and micropore volume are beneficial to efficient mercury adsorption. The active Cl species generated on the surface of the samples were effective oxidants able to convert elemental mercury (Hg0) into oxidized mercury (Hg2+). The crystallization of NaCl due to the ion exchange effect during the impregnation of NaA and NaX reduced the number of active Cl species on the surface, and restricted the physisorption of Hg0. Therefore, the Hg0 removal efficiencies of the samples were inhibited. The TPD analysis revealed that the species of mercury on the surface of FeCl3-HZSM-5 was mainly in the form of mercuric chloride(HgCl2), while on FeCl3-NaX and FeCl3-NaA it was mainly mercuri coxide(HgO). 相似文献
107.
利用碱性过硫酸钾消解紫外分光光度法,探讨了消解时间和消解温度对空白吸光值的影响,认为增加消解时间可以降低空白吸光值,而提高消解温度对空白吸光值的影响不大;对于某些样品中总氮含量低于氨氮含量的现象,将碱性过硫酸钾装入小试管,再放入装有水样的比色管中,虽然能够减少氨气形式逸出的氮含量,但回收率较低;连续流动和流动注射-盐酸萘乙二胺分光光度法,在以后的修订中应增加过硫酸钾含氮量以及镉柱还原能力大小的界定. 相似文献
108.
在水的CODcr测定中,将30 ml回流量确定为常规检测回流量,可节省浓硫酸和硫酸银用量50%;将消解回流时间从120 min缩短为30 min,已满足对地表水和各类废水中CODcr的准确测定,可节省水电费用75%以上,含氯水样中Cl-的掩蔽研究表明:按国标法用10倍Cl-重量的HgSO4 掩蔽Cl-,加标(CODcr =100 mg/L)回收率为110%~120%左右,用30~40倍Cl -重量的HgSO4 掩蔽Cl-,加标回收率为100%左右,对HgSO4 掩蔽Cl-的条件和机理作了适当探讨.另外,采用加入H2 SO4-后加入HgSO4 的方法可减少HgSO4 的耗用量70%以上. 相似文献
109.
目的 分析研究铝及铝合金在自然水环境中的腐蚀行为。方法 通过开展LM3纯铝、5083铝、LF6M去包铝及带包铝在淡海水交替、海水及淡水自然环境下2 a的暴露试验,将3种环境下材料的腐蚀形貌、腐蚀速率进行对比。总结4种铝及铝合金材料在不同水环境下的腐蚀规律,对其腐蚀机理进行简要的探讨,并对其长周期的腐蚀行为进行预测。结果 通过对4种材料局部腐蚀协同影响因子(b)的对比可以发现,淡水环境对LM3纯铝局部腐蚀的影响最大,淡海水环境对5083铝合金局部腐蚀影响最大,淡水及淡海水环境对2种LF6M铝合金材料局部腐蚀的影响都很大。结论 5083、LF6M带包铝及去包铝,在淡海水交替自然环境下的耐蚀性能最差,LM3纯铝在淡水环境下耐蚀性能最差。 相似文献
110.
Few studies exist on how chloride from chloride‐based deicers is transported in infiltration‐based stormwater control measures. In 2009, the U.S. Environmental Protection Agency (USEPA) constructed a 0.4 ha parking lot in Edison, New Jersey, that was surfaced with permeable interlocking concrete pavers (PICP), pervious concrete (PC), and porous asphalt (PA). Each surface type has four equally sized, lined sections that direct all infiltrate to separate 5.7 m3 collection tanks. The USEPA acute criterion for aquatic life (860 mg/l) was exceeded in events immediately following a snow event. Concentrations of the infiltrate exceeded the detection limit (5 mg/l) year round but did not exceed the USEPA chronic toxicity (230 mg/l) after April. The chloride concentration decreased with cumulative rainfall since previous snow event, and a power regression described this relationship. In the power regression, the coefficient (b) described the initial concentration following a snow event, and the exponent (m) described the rate in which chloride was flushed through the system with infiltrating water. PC had the largest coefficient (5,664) and largest absolute exponent (?0.92), followed closely by PICP (b = 4,943 and m = ?0.87), and distantly by PA (b = 2,907 and m = ?0.67). The differences in release rate were proportional to the measured surface infiltration rates of 4,000; 2,400; and 200 cm/h for PC, PICP, and PA, respectively. These results will assist those who manage or regulate stormwater where receiving waters are chloride impaired. 相似文献