Self-made cation exchange resin supported nanoscale zero-valent iron （R-nZVI） was used to remove phosphorus in rainwater runoff. 80% of phosphorus in rainwater runoff from grassland was removed with an initial concentration of 0.72 mg. L-1 phosphorus when the dosage of R-nZVl is 8 g per liter rainwater, while only 26% of phosphorus was removed when using cation exchange resin without supported nanoscale zero-valent iron under the same condition. The adsorption capacity of R-nZVI increased up to 185 times of that of the cation exchange resin at a saturated equilibrium phosphorous concentration of 0.42 mg. L-1. Various techniques were implemented to characterize the R-nZVI and explore the mechanism of its removal of phosphate. Scanning electron microscopy （SEM） indicated that new crystal had been formed on the surface of R-nZVI. The result from inductive coupled plasma （ICP） indicated that 2.1% of nZVI was loaded on the support material. The specific surface area was increased after the load of nanoscale zero-valent iron （nZVI）, according to the measurement of BET-N2 method. The result of specific surface area analysis also proved that phosphorus was removed mainly through chemical adsorption process. X-ray photoelectron spectroscopy （XPS） analysis showed that the new product obtained from chemical reaction between phosphate and iron was ferrous phosphate. 相似文献
China is at present experiencing a very rapid urbanization process, which has brought a number of adverse impacts upon the water environment. In particular, urban runoff quantity and quality control have emerged as one of the key concerns for municipal officials. One of the strategies being considered is the use of a Low Impact Development type of Best Management Practices (LID BMPs) for urban storm water runoff quantity and quality control. In this paper, the situation surrounding urban runoff control in China is reviewed first. Then the conventional strategy and technologies for the construction and management of urban drainage systems are discussed, while exploring their inherent dilemmas. The LID BMPs are then introduced to control urban runoff in the context of urban sustainable water systems. After the comprehensive analysis of the various LID BMPs, the advances in LID BMPs research and practice for urban runoff control in China are investigated and summarized. At last, the difficulties of implementing LID BMPs in China are discussed, and a direction for the future is proposed. 相似文献
Ratio of turbidity and TSS (Tur/TSS) was used to characterize PSD of stormwater particles.Pb and Zn preferred to accumulate in finer RDS, while Cu, Cr and Ni in coarser RDS.HMs pollution in stormwater particles increased linearly with Tur/TSS.Dissolvability of HMs and PSD variations contribute to the differences between RDS and stormwater. Stormwater runoff, derived from the wash-off of road-deposited sediments (RDS), contains elevated heavy metal (HM) concentrations and, thus, imposes an increasing threat to urban aquatic ecosystems. In-depth understanding of the variations of HMs pollution from RDS to stormwater during transport processes facilitates the development of effective RDS and stormwater control strategies. Toward this end, the distribution of HMs (Cu, Pb, Zn, Cr, and Ni) in RDS and stormwater were investigated simultaneously. The results show a preferential accumulation of Pb and Zn in the finer (<38.5 μm) RDS, and Cu, Cr and Ni in the coarser (38.5–150 μm) RDS. For stormwater, n.d.~48.6% of HMs fractionated into the dissolved phase, and stormwater particles constitute the primary carriers of HMs. Furthermore, the accumulation of HMs in stormwater particles increased linearly with finer particle size distributions (PSD). Geoaccumulation index (Igeo) highlighted the predominant pollution of both RDS and stormwater particles by Cu, Pb and Zn. Nonetheless, Cu, Pb, and Ni mostly contributed the potential ecological risk of RDS, whereas Cu, Pb, and Zn mainly contributed that of stormwater particles. Moreover, contamination by Cu, Pb and Zn was significantly higher in stormwater particles than that in RDS. These differences are attributable to the solubility and size-dependent accumulation of HMs in RDS, as well as the PSD variations during transport processes. The study outcomes highlight the importance of very fine (nano- and submicron- scale) RDS in stormwater pollution and the necessity of control. 相似文献
A bioretention unit (BRU) or cell is a green infrastructure practice that is widely used as a low impact development (LID) technique for urban stormwater management. Bioretention is considered a good fit for use in China’s sponge city construction projects. However, studies on bioretention design, which incorporates site-specific environmental and social-economic conditions in China are still very much needed. In this study, an experimental BRU, consisted of two cells planted with Turf grass and Buxus sinica,was tested with eighteen synthesized storm events. Three levels (high, median, low) of flows and concentrations of pollutants (TN, TP and COD) were fed to the BRU and the performance of which was examined. The results showed that the BRU not only delayed and lowered the peak flows but also removed TN, TP and COD in various ways and to different extents. Under the high, medium and low inflow rate conditions, the outflow peaks were delayed for at least 13 minutes and lowered at least 52%. The two cells stored a maximum of 231 mm and 265 mm for turf grass and Buxus sinica, respectively. For both cells the total depth available for storage was 1,220 mm, including a maximum 110 mm deep ponding area. The largest infiltrate rate was 206 mm/h for both cells with different plants. For the eighteen events, TP and COD were removed at least 60% and 42% by mean concentration, and 65% and 49% by total load, respectively. In the reservoir layer, the efficiency ratio of removal of TN, TP and COD were 52%, 8% and 38%, respectively, within 5 days after runoff events stopped. Furthermore, the engineering implication of the hydrological and water quality performances in sponge city construction projects is discussed.
