全文获取类型
收费全文 | 113篇 |
免费 | 10篇 |
国内免费 | 69篇 |
专业分类
安全科学 | 6篇 |
废物处理 | 16篇 |
环保管理 | 4篇 |
综合类 | 103篇 |
基础理论 | 35篇 |
污染及防治 | 19篇 |
评价与监测 | 7篇 |
社会与环境 | 2篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 1篇 |
2019年 | 6篇 |
2018年 | 6篇 |
2017年 | 9篇 |
2016年 | 8篇 |
2015年 | 11篇 |
2014年 | 10篇 |
2013年 | 19篇 |
2012年 | 8篇 |
2011年 | 14篇 |
2010年 | 5篇 |
2009年 | 6篇 |
2008年 | 4篇 |
2007年 | 13篇 |
2006年 | 7篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2002年 | 8篇 |
2001年 | 4篇 |
2000年 | 8篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有192条查询结果,搜索用时 15 毫秒
21.
发现1株对银离子有强吸附能力的蜡状芽孢杆菌HQ-1,研究了其对银离子的吸附特性及吸附机理.结果表明,菌体对银的吸附量可达91.75 mg/g,吸附过程符合Pseudo-second Order吸附动力学模型,相关系数高达0.999 9;吸附热力学很好地符合Freundlich吸附等温模型,相关系数为0.99;考察菌体浓度和温度对吸附的影响发现,菌体浓度增加有利于对银离子的吸附,温度对吸附影响较小;FTIR、SEM及EDAX实验结果表明吸附存在2种吸附机理,一为菌体表面一些含氮氧的基团对Ag+的络合作用,二为菌体分泌的胞外多糖等物质对Ag+的微沉淀成晶作用. 相似文献
22.
Berislav Momčilović Juraj Prejac Vjeran Višnjević Ninoslav Mimica Sandra Morović Asja Čelebić 《毒物与环境化学》2013,95(6):1238-1246
Environmental exposure to silver (Ag) was assessed in occupationally non-exposed adult human population by analyzing Ag in the hair (H?·?Ag) and whole blood (WB?·?Ag). H?·?Ag was analyzed in 311 (123 men, M; 188 women, W); while WB?·?Ag was determined in 235 of these individuals (90 M, 145 W). Women had more H?·?Ag than men (M 0.05 vs. W 0.076), whereas WB?·?Ag concentrations in men and women were not significantly different. A natural distribution of the median derivatives was utilized to generate the dataset to fit the logistic sigmoid curve to assess the current human body burden of environmental Ag population exposure for M and W separately. The H?·?Ag (µg?g?1) below 0.0105 for M and 0.0145 for W, reflects low level of environmental Ag exposure. The adaptive physiological saturation phase followed where H?·?Ag rose rapidly, first for M and then for W in parallel with biological assay. Both parallel saturation curves converged and plateaued at 0.215 for M and 0.965 for W (µg?g?1). The current level of human environmental Ag exposure is low, but cases of high Ag exposure occurred sporadically. In conjunction with the medical histories overt clinical neural toxicity may be expected for H?·?Ag at 4?µg?g?1and higher. There were no significant correlation between the H?·?Ag and WB?·?Ag. 相似文献
23.
R. Sahraei A. Farmany S. S. Mortazavi M. Roushani S. Sobhanardakani M. Ghoochian 《毒物与环境化学》2013,95(2):214-220
A method is reported for the determination of methyl violet in the range of 10–120 nmol L?1. The method is based on the catalytic effect of silver nanoparticles (AgNPs) on the oxidation reaction of methyl violet by potassium bromate in acid medium. The reaction is followed spectrophotometrically by measuring the change in absorbance () at 620 nm using a fixed time method. The reaction variables were optimized in order to achieve highest sensitivity. The 3б criterion detection limit was 5 nmol L?1, and the relative standard deviation for ten replicate determinations at a concentration of methyl violet of 15 nmol L?1 was 0.97% (n = 10). The method was successfully applied to the determination of methyl violet in river water samples. 相似文献
24.
25.
纳米银和银离子对土壤中硝化微生物及其氨氧化速率的影响 总被引:1,自引:0,他引:1
为研究纳米银对土壤硝化微生物及其氮转化的影响,采用土壤培养方式,对不同剂量纳米银(10、50、100 mg·kg~(-1))和银离子(1、5、10 mg·kg~(-1))暴露下黄棕壤和水稻土硝化细菌数量、土壤酶活性、amoA基因丰度、NH_4~+-N与NO_3~--N含量变化以及土壤潜在氨氧化速率进行研究.结果表明,纳米银和银离子暴露后,2种土壤亚硝酸细菌和硝酸细菌数量显著减少;土壤酶活性受到抑制,对脲酶的影响大于过氧化氢酶;土壤氨氧化细菌(AOB)和氨氧化古菌(AOA)的amoA基因丰度均降低,对AOB基因丰度的影响大于AOA.在2种土壤中外源添加(NH_4)_2SO_4时,随着纳米银和银离子暴露剂量增加,土壤NH_4~+-N含量累积,NO_3~--N含量减少,氨氧化速率降低,铵态氮向硝态氮的转化受阻.综上所述,纳米银和银离子对土壤硝化微生物产生毒害作用并影响铵态氮转化,且影响程度与土壤理化性质有关. 相似文献
26.
在鲢鲤鱼混养鱼塘内进行增饲麸皮碳源的试验研究,探讨麸皮在常规养殖鱼塘生成生物絮团的效果及对鱼类生长和养殖水体水质的影响。结果显示:增饲麸皮可以显著促进鱼塘生物絮团的生长;与对照鱼塘相比,增饲麸皮的鱼塘鲜鱼产量提高16.32%,其增重率、特定生长率、生长势显著高于对照鱼塘;鲢鱼的生长性能高于鲤鱼,鲤鱼的饲料系数低于对照鱼塘,生物絮团对鲢鱼的促生长作用高于鲤鱼;与对照鱼塘相比,增饲麸皮的鱼塘水体透明度降低、总悬浮物(TSS)浓度上升,NO2-N、NH3-N、TN浓度显著降低,养殖水体部分水质指标得到改善。 相似文献
27.
28.
29.
Ali Fanous Michael Hecker Angelika Görg Harun Parlar Fritz Jacob 《Journal of environmental science and health. Part. B》2013,48(7):666-675
Cobalt and silver are toxic for cells, but mechanisms of this toxicity are largely unknown. Analysis of Corynebacterium glutamicum proteome from cells grown in control and cobalt or silver enriched media was performed by two dimensional gel electrophoresis (2DE) followed by mass spectrometry. Our results indicate that the cell adapted to cobalt stress by inducing five defense mechanisms: Scavenging of free radicals, promotion of the generation of energy, reparation of DNA, reparation and biogenesis of Fe-S cluster proteins and supporting and reparation of cell wall. In response to the detoxification of Ag+ many proteins were up-regulated, which involved reparation of damaged DNA, minimizing the toxic effect of reactive oxygen species (ROS) and energy generation. Overexpression of proteins involved in cell wall biosynthesis (1,4-alpha-glucan branching enzyme and nucleoside-diphosphate-sugar epimerase) upon cobalt stress and induction of proteins involved in energy metabolism (2-methylcitrate dehydratase and 1, 2-methylcitrate synthase) upon silver demonstrate the potential of these enzymes as biomarkers of sub-lethal Ag+ and Co toxicity. 相似文献
30.
本研究建立了一种用空气-乙炔火焰原子吸收分光光度法测定浸渍活性炭中银含量的分析方法,对酸介质浓度、共存元素的干扰进行了探讨,在0—1.0ml沪范围内,银含量与吸光度呈线性关系,相关系数为0.9999。对09型浸渍活性炭标准物质进行测定,测定结果的相对标准偏差为0.191%(n=10),加标回收率为97.5%-101.4%。 相似文献