全文获取类型
收费全文 | 301篇 |
免费 | 39篇 |
国内免费 | 124篇 |
专业分类
安全科学 | 37篇 |
废物处理 | 34篇 |
环保管理 | 22篇 |
综合类 | 248篇 |
基础理论 | 42篇 |
污染及防治 | 63篇 |
评价与监测 | 10篇 |
社会与环境 | 7篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 6篇 |
2022年 | 22篇 |
2021年 | 15篇 |
2020年 | 12篇 |
2019年 | 11篇 |
2018年 | 10篇 |
2017年 | 9篇 |
2016年 | 17篇 |
2015年 | 15篇 |
2014年 | 9篇 |
2013年 | 32篇 |
2012年 | 26篇 |
2011年 | 18篇 |
2010年 | 15篇 |
2009年 | 25篇 |
2008年 | 16篇 |
2007年 | 24篇 |
2006年 | 24篇 |
2005年 | 21篇 |
2004年 | 18篇 |
2003年 | 13篇 |
2002年 | 22篇 |
2001年 | 17篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 11篇 |
1997年 | 7篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有464条查询结果,搜索用时 15 毫秒
51.
Seasonal variations of Rn concentrations in the air of a tunnel located in Nagano city 总被引:2,自引:0,他引:2
H. Muramatsu Y. Tashiro N. Hasegawa C. Misawa M. Minami 《Journal of environmental radioactivity》2002,60(3):1070-274
The seasonal variation of 222Rn concentrations in the air of tunnels constructed during World War II at Nagano City has been investigated. The determination of 222Rn concentrations in tunnel air was performed using a solid-state nuclear track detector technique. The monthly radon concentrations changed smoothly, decreasing towards winter and increasing towards summer, and it was found that the concentrations strongly correlate with the temperature difference between the inside and the outside of the tunnel. In the innermost areas of the tunnel, the maximum concentration was observed in July, its value being about 6500 Bq m (-3). The concentrations of radon in the tunnel air decrease exponentially towards the openings of the tunnel, which indicates that the radon concentration in the tunnel is basically governed by diffusion and mixing of radon gas with air. These observations lead to the conclusion that the seasonal variation of the radon concentration in the tunnel air is mainly caused by a convection current due to a stack effect induced by the temperature difference between the tunnel air and the outside air. 相似文献
52.
The speciation of titrated copper in a dissolved tannic acid (TA) solution with an initial concentration of 4 mmol organic carbon (OC)/l was investigated in a nine-step titration experiment (Cu/OC molar ratio = 0.0030–0.0567). We differentiated between soluble and insoluble Cu species by 0.45 μm filtration. Measurements with a copper ion selective electrode (ISE) and diffusive gradients in thin films (DGT) were conducted to quantify unbound Cu(II) cations (‘free’ Cu) and labile soluble Cu complexes. For the DGT measurements, we used an APA hydrogel and a Chelex 100 chelating resin (Na form). Insoluble organic Cu complexes (>0.45 μm) was the dominant Cu species for Cu/OC = 0.0030–0.0567 with a maximum fraction of 0.96 of total Cu. At Cu/OC > 0.0100, Cu-catalysed degradation of aggregate structures resulted in a strong increase of free Cu and (labile) soluble Cu complexes with a maximum fraction of 0.28 and 0.32 of total Cu, respectively. Labile (i.e. DGT-detectable) soluble Cu complexes had a relatively high averaged diffusion coefficient (D) in the APA hydrogel (3.50 × 10−6– 5.58 × 10−6 cm2 s−1). 相似文献
53.
近二十年来发展起来的光催化技术可利用太阳光能对水体中的多种有机污染物进行降解.这符合可持续发展的长远需要,具有诱人的发展前景。光催化技术利用可再生的清洁资源,氧化能力强.适用于广谱有机物,能使难被一般氧化剂氧化、又难生物降解的污染物降解.是当前太阳能利用及水污染控制方面开辟的前沿领域.在治理环境污染方面具有明显的发展优势。本文以溶胶-凝胶法、金属有机化学气相淀积、煅烧沉淀法等多种方法制备光活性二氧化钛膜。 相似文献
54.
55.
56.
生物膜法降解甲苯废气过程的探讨 总被引:12,自引:0,他引:12
采用陶粒为填料的生物滤池降解甲苯废气,并对清水试验和生物膜试验的结果进行分析,发现生物膜法降解甲苯这样的挥发性有机物(VOCs)具有良好的效果,已不再是清水试验中单纯的物理吸收过程,而是伴有生化反应的吸收过程,是以气膜控制为主的传质过程。 相似文献
57.
推导了BAF前置反硝化工艺简化动力学模型,揭示了BAF去除有机物与反应速率常数与膜厚的关系。同时以生物膜中活性物质与非活性物质增长生物数学模型体系为基础,从理论上推导了BAF最佳膜厚的范围。 相似文献
58.
Influences of working pressure on properties for TiO2 films deposited by DC
pulse magnetron sputtering 总被引:1,自引:1,他引:0
TiO2 films were deposited at room temperature by DC pulse magnetron sputtering system.The crystalline structures,morphological features and photocatalytic activity of TiO2 films were systematically investigated by X-ray diffraction (XRD),atomic force microscopy and ultraviolet spectrophotometer,respectively.The results indicated that the working pressure was the key deposition parameters influencing the TiO2 film phase composition at room temperature,which directly affected its photocatalytic activity.With increasing the working pressure,the target self-bias decreases monotonously.Therefore,low temperature TiO2 phase (anatase) could be deposited with high working pressure.The anatase TiO2 films deposited with 1.4 Pa working pressure displayed the highest photocatalytic activity by decomposition of Methyl Orange solution,which the degradation rate reached the maximum (35%) after irradiation by ultraviolet light for 1 h. 相似文献
59.
ITO/CdS/ZnO interface composite films were successfully prepared by subsequent electrodeposition of CdS and ZnO onto indium tin oxide (ITO) glass substrates. The obtained ITO/CdS/ZnO composite films were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), and UV-Vis spectroscopy. The photocatalytic activity of ITO/CdS/ZnO composite films were investigated using methyl orange (MO) as a model organic compound under UV light irradiation. The influence of operating parameters on MO degradation including initial concentration of MO, pH value of solution, and inorganic anion species over the composite films were examined. A blue shift of absorption threshold was observed for the ITO/CdS/ZnO film in comparison with ITO/ZnO film. ITO/CdS/ZnO composite films prepared under specific conditions showed a higher photocatalytic activity than that of ITO/ZnO films. It was also found that the photocatalytic degradation of MO on the composite filing followed pseudo-first order kinetics. 相似文献
60.