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1.
太湖北部小流域沉积物重金属污染特征与评价 总被引:1,自引:0,他引:1
近几十年来重金属的沉积记录、来源及污染水平受到了广泛关注.为探明太湖北部小流域重金属的污染来源和环境质量状况,本研究分析了柱状沉积物中8种重金属(Mn、Cr、Zn、Cu、As、Pb、Ni和Co)含量.运用主成分分析法判定污染源,富集因子法表征重金属富集特征,通过熵权模糊模型对沉积物中重金属污染状况进行评价.结果显示,所有重金属含量均较高,高低依次为Mn > Cr > Zn > Cu > As > Pb > Ni > Co.其中Mn含量最高,为380.06~767.69μg/g.沉积物重金属污染的主要贡献因子为交通排放、农业污染和煤炭燃烧.As的富集指数最大(2.89~15.61).其中77.59%的沉积层属于显著富集,受人类活动影响最为显著.熵权模糊综合评价结果表明,Cu(0.483)和As(0.352)的权重值最大,是沉积物中的首要污染物,且65.52%的沉积层重金属含量处于中度污染水平. 相似文献
2.
以南京江北新区分流制雨水管道沉积物为研究对象,考察不同粒径沉积物中铵态氮(NH3-N)和硝态氮(NO3--N)干期分布特征,分析其随干期长度的变化关系,并探讨沉积物理化性质及微生物菌群结构对NH3-N和NO3--N干期分布的影响.结果表明:粒径≤0.075mm的沉积物中NH3-N占比最高(交通区30.8%,商业区36.7%);交通区粒径≤0.075mm的沉积物中NO3--N占比最高(33.0%),而商业区粒径0.075~0.15mm沉积物中NO3--N占比最高(34.4%);干期长度与交通区0.075~0.15mm粒径段的沉积物中NO3--N含量及商业区粒径≥0.3mm的沉积物中NH3-N含量之间的相关性均最显著;雨水管道沉积物中NH3-N和NO3--N的干期分布与O-H和N-H等官能团、表面极性和亲水性、微观形貌等有一定关联;交通区雨水管道沉积物中Gemmobacter等反硝化优势菌种(相对丰度总和为20.15%)对NO3--N干期分布影响更显著. 相似文献
3.
利用磷吸附指数(PSI)、磷吸附饱和度(DPS)和磷释放风险指数(ERI)研究了2016年10月和2017年5月海州湾表层沉积物的磷吸附容量及潜在释放风险.结果显示,2016年秋季PSI变化范围为99.58~199.39[mgP/(100g)]/[μmol/L],DPS变化范围为23.118%~34.289%;2017年夏季PSI变化范围是130.29~198.57[mgP/(100g)]/[μmol/L],DPS变化范围为25.545%~42.135%,两次调查中PSI和DPS均表现出相反的平面分布趋势.PSI和Alox、Feox呈显著正相关,说明Feox和Alox是影响海州湾表层沉积物吸附磷的主要因素,且Feox占主导作用;DPS与Alox和Feox分别表现出了显著负相关性和极显著负相关性,说明Alox和Feox含量的增大会降低表层沉积物的磷吸附饱和度.2016年10月磷释放风险指数(ERI)的变化范围为11.59%~34.18%,2017年5月磷释放风险指数(ERI)的变化范围为12.86%~32.34%,从2次调查结果整体来看,海州湾表层沉积物的磷释放风险为中度风险. 相似文献
4.
A. M. Cicero M. G. Finoia M. Gabellini E. Veschetti 《Environmental monitoring and assessment》2000,64(3):607-616
The Italian guidelines concerning the dumping of dredgingmaterials implies chemical, physical and microbiologicalcharacterisation of dumping sediments collected through aspecific sampling strategy.POP's such as PCB's and organochlorine pesticides, areconsidered as priority pollutants in all the InternationalConventions for the protection of the marine environment, inconsequence of their persistence, toxicity and bioaccumulation capacity.In the present article the concentrations and distribution ofPCB's and organochlorine pesticides in dredging sediments ofPiombino harbour (northern Thyrrenian sea) were investigates.The results showed high POP's concentrations in all the studiedareas. The maximum values were: 3.94 mg kg-1 dry weight for PCB's(IUPAC Nos. 28; 52; 101, 118; 137; 153; 180; 209); 2.04 mg kg-1 d.w.for HCH's (-, -, - and -hexachlorocyclohexane isomers); 0.28 mg kg-1 d.w. for DD's (DDT + DDE + DDD).Subsequently, the data related to each pollutant were treatedwith statistical tests, in order to verify how well the samplingstrategy is able to represent the distribution of contaminantsin the dredging area. Finally, management strategies werederived for the studied dredging sediments. 相似文献
5.
The metal pollution in water and sediment of the River Hindon in western Uttar Pradesh (India) was assessed for Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn. The metal concentrations in water showed wide temporal variation compared with bed sediment because of variability in water discharge and variations in suspended solid loadings. Metal concentrations in bed sediments provided a better evaluation of the degree and the extent of contamination in the aquatic environment, Santagarh and Atali being the most polluted sites of the river. The ratio of heavy metals to conservative elements (Fe, Al, etc.) may reveal the geochemical imbalances due to the elevated metal concentrations normally attributed to anthropogenic sources. Metal/Al ratios for the bed sediments of the river Hindon were used to determine the relative mobility and general trend of relative mobility occurred Fe > Mn > Zn > Cr > Ni > Pb > Cu > Cd. 相似文献
6.
7.
In the aquatic environment, the accumulation of chemicalcontaminants by sediments poses a potential threat to endemiclife forms and drinking water resources. Trace metals such asCd, Cu, Cr, Ni, Pb, and toxic organic compounds, are among awide variety of contaminants having an affinity for sediments.In this study, experiments were performed simulating sedimentresuspension in the lower Housatonic River, Connecticut, using aParticle Entrainment Simulator. Analyses of grain sizedistributions, porosities and total organic contents of thesediments suggested that these parameters influence theredistribution and entrainment of settleable solids in the watercolumn. These findings were established by evaluating the impactof one parameter on sediment resuspension as a function ofstream flow with the other two characteristics being heldconstant. Total suspended solids and volatile suspended solidsresuspension concentration ranged from 3.2 to 20648.3 mg L-1,and 1.5 to 1823.8 mg L-1, respectively, with subsequentincreases in flow rates from 9 to 6 dynes cm-2. The resuspension concentrations were augmentedby sediment porosity (22.0 to 57.5%), percent finer grain-size distributions at 0.1 mm, and total organic content (2.7 g kg-1 to 29.0 g kg-1). Using K
p values, and the dissolvedcontaminant levels of various trace metals, the particulatecontaminant levels of the metals were determined under variousoscillation rates. As sediment resuspension increased withincreased stream flow, there was an overall general increasefrom 0.02 to 33.6 g L-1 in the particulatecontaminant levels of Cd, Cu, Cr, Ni and Pb. 相似文献
8.
A. M. Cicero M. Mecozzi R. Morlino D. Pellegrini E. Veschetti 《Environmental monitoring and assessment》2001,71(3):297-316
Dredging is a very important procedure for harbor management. InItaly the guidelines for the offshore dumping of dredged materials are issued by the Ministry of Environment. Theydescribed a few steps of dredging activities, such as thesampling strategy, but do not deal with limits or guide-valuesfor the chemical, physical and biological composition of theresulting sediments. The quality of dredged materials is mainlydependent on the presence of inorganic and organic pollutants.In particular, polychlorinated biphenyls (PCBs) and organo-chlorinated pesticides are seen as a high priority inmarine environment by international organizations because oftheir persistence, toxicity and bioaccumulation capacity.In this article the presence of some PCBs and organo-chlorinatedpesticides in sediment samples collected from the harbor ofLivorno (Northern Tyrrhenian Sea) was investigated. Theconcentration of HCHs, Aldrin, Chlordanes, DDEs, DDTs, and PCBsin 12 representative sites ranged between <1 g kg–1and 95, 19, 32, 35, 107, and 111 g kg–1, respectively.The application of univariate and multivariate statisticaltechniques, such as linear regression analysis and principalcomponent analysis, to the experimental data showed a differentdistribution of PCBs in the two sediment layers. On thecontrary, the vertical distribution of the other investigatedpollutants was more homogeneous and affected by randomvariability. The multivariate approach was an important tool to establish more rational criteria for the management of dredged materials. 相似文献
9.
Georgios D. Gikas Trisevgeni Yiannakopoulou Vassilios A. Tsihrintzis 《Environmental Modeling and Assessment》2006,11(3):219-233
SWAT ver. 2000 was used to predict hydrographs, and sediment, nitrate and total phosphorus loadings from a 1349 km2 mountainous/agricultural watershed in Northern Greece. The model was calibrated and verified using continuous meteorological
data from eight stations within the drainage area, and runoff, sediment and nutrient concentrations measured at nine stations
located within the main tributaries of the watershed, for the time period from May 1st, 1998 to January 31st, 2000. Model
validation methodology and resulting input parameters appropriate for Mediterranean drainage basins are presented. Predicted
by the model hydrographs, sedimentographs and pollutographs are plotted against observed values and show good agreement. Model
performance is evaluated using the root mean square error computation and scattergrams of predicted versus observed data.
The validated model is also used to test the effectiveness of three alternative cropping scenarios in reducing nutrient loadings
from the agricultural part of the watershed. The study showed that this model, if properly validated, can be used effectively
in testing management scenarios in Mediterranean drainage basins. 相似文献
10.
长江口滨岸潮滩沉积物中磷的环境地球化学特征 总被引:21,自引:3,他引:21
研究了长江口滨岸潮滩表层沉积物中磷的分布、形态等环境地球化学特征。结果表明该地区表层沉积物中磷的含量水平在18.0-31.4μmol/g之间,最大值出现在浦东白龙港污水排放口附近,长江口滨岸潮滩沉积物中磷的分布呈现明显的空间和季节性变化规律,这主要与潮滩不同地段磷的来源、沉积物质地的差异,以及水动力、环境介质条件和生物作用的时空变化密切相关。此外,沉积物中磷的形态分级研究表明大部分沉积磷以无机磷形式存在,其中无机磷又以钙结合磷为主;有机磷比例较少。其次,潮滩沉积物表层上覆水中可溶磷的浓度一般都大于沉积物间隙水,沉积物-水界面中磷主要以累积作用过程为主。 相似文献