全文获取类型
收费全文 | 976篇 |
免费 | 76篇 |
国内免费 | 301篇 |
专业分类
安全科学 | 133篇 |
废物处理 | 7篇 |
环保管理 | 91篇 |
综合类 | 675篇 |
基础理论 | 282篇 |
污染及防治 | 58篇 |
评价与监测 | 22篇 |
社会与环境 | 30篇 |
灾害及防治 | 55篇 |
出版年
2024年 | 14篇 |
2023年 | 34篇 |
2022年 | 56篇 |
2021年 | 68篇 |
2020年 | 25篇 |
2019年 | 44篇 |
2018年 | 21篇 |
2017年 | 40篇 |
2016年 | 38篇 |
2015年 | 50篇 |
2014年 | 107篇 |
2013年 | 58篇 |
2012年 | 75篇 |
2011年 | 88篇 |
2010年 | 58篇 |
2009年 | 57篇 |
2008年 | 55篇 |
2007年 | 52篇 |
2006年 | 47篇 |
2005年 | 49篇 |
2004年 | 38篇 |
2003年 | 27篇 |
2002年 | 29篇 |
2001年 | 29篇 |
2000年 | 30篇 |
1999年 | 23篇 |
1998年 | 19篇 |
1997年 | 13篇 |
1996年 | 16篇 |
1995年 | 18篇 |
1994年 | 6篇 |
1993年 | 9篇 |
1992年 | 22篇 |
1991年 | 7篇 |
1990年 | 14篇 |
1989年 | 12篇 |
1988年 | 3篇 |
1987年 | 2篇 |
排序方式: 共有1353条查询结果,搜索用时 15 毫秒
31.
华北平原玉米-小麦轮作农田N2O交换通量的研究 总被引:8,自引:2,他引:6
以华北地区冬小麦-夏玉米轮作农田为研究对象,运用静态箱法对正常施肥及正常施肥结合秸秆还田农田N2O交换通量进行了连续1 a对比研究.正常施肥及正常施肥结合秸秆还田样地N2O全年的累积排放量分别为7.61 kg.hm-2和12.6kg.hm-2,其中秸秆还田引起N2O排放明显增加主要发生在玉米生长季节.两种处理样地在玉米季N2O的排放量占全年累积排放的57%~86%,表明华北玉米-小麦轮作体系中N2O排放主要集中在玉米季.各次施肥后10 d内N2O的累积排放量约占全年总排放量的71%~88%,显然现有化肥极大促进了华北农田N2O排放. 相似文献
32.
Enzymatic decolourization of the azo dye, Direct Yellow (DY106) by Cucurbita pepo (courgette) peroxidase (CP) is a complex process, which is greatly affected by pH, temperature, enzyme activity and the concentrations of H2O2 and dye. Courgette peroxidase was extracted and its performance was evaluated by using the free-CP (FCP) and immobilized-CP (ICP) forms in the decolourization of DY106. Immobilization of peroxidase in calcium alginate beads was performed according to a strategy aiming to minimize enzyme leakage and keep its activity at a maximum value by optimizing sodium alginate content, enzyme loading and calcium chloride concentration. The initial conditions at which the highest DY106 decolourization yield was obtained were found at pH 2, temperature 20℃, H2O2 dose 1 mmol/L (FCP) and 100 mmol/L (ICP). The highest decolourization rates were obtained for dye concentrations 50 mg/L (FCP) and 80 mg/L (ICP). Under optimal conditions, the FCP was able to decolorize more than 87% of the dye within 2 min. While with ICP, the decolourization yield was 75% within 15 min. The decolourization and removal of DY106 was proved by UV-Vis analysis. Fourier transform infrared (FT-IR) spectroscopy analysis was also performed on DY106 and enzymatic treatment precipitated byproduct. 相似文献
33.
34.
Removal of phosphate by Fe-coordinated amino-functionalized 3D mesoporous
silicates hybrid materials
Phosphate removal from aqueous waste streams is an important approach to control the eutrophication downstream bodies of water.
A Fe(III) coordinated amino-functionalized silicate adsorbent for phosphate adsorption was synthesized by a post-grafting and metal
cation incorporation process. The surface structure of the adsorbent was characterized by X-ray di raction, N2 adsoropion/desoprotion
technique, and Fourier transform infrared spectroscopy. The experimental results showed that the adsorption equilibrium data were well
fitted to the Langmuir equation. The maximum adsorption capacity of the modified silicate material was 51.8 mg/g. The kinetic data
from the adsorption of phosphate were fitted to pseudo second-order model. The phosphate adsorption was highly pH dependent and
the relatively high removal of phosphate fell within the pH range 3.0–6.0. The coexistence of other anions in solutions has an adverse
e ect on phosphate adsorption; a decrease in adsorption capacity followed the order of exogenous anions: F?? > SO2?? 4 > NO??3 > Cl??. In
addition, the adsorbed phosphate could be desorbed by NaOH solutions. This silicate adsorbent with a large adsorption capacity and
relatively high selectivity could be utilized for the removal of phosphate from aqueous waste streams or in aquatic environment. 相似文献
35.
The competition between submersed plants has been recognized as an important factor influencing the structure of plant communities
in shallow lakes. The ability of different species to take up and store nutrients from the surrounding ambience varies, and hence plant
community structure might be expected to affect the cycling of nutrients in lake ecosystems. In this study, the uptake of phosphorus
by Hydrilla verticillata and Vallisneria natans was studied and compared in monoculture and competitive mixed-culture plantings.
Results showed that for both studied species the phosphorus concentrations of different tissues and of whole plants was unaffected by
competition. However, the quantity of phosphorus accumulated by whole plants of H. verticillata was significantly higher in mixture
culture than in monoculture, while that of V. natans was lower in the mixed culture. The results indicated that H. verticillata has a
competitive advantage over V. natans, when the two species are grown in competition, and is able to accumulate a greater quantity of
phosphorus. 相似文献
36.
文章确立了小麦、香蕉中戊唑醇残留检测方法,小麦样品加水10 mL用丙酮为萃取溶剂,石油醚液液分配,中性氧化铝柱层析净化,用气相色谱(GC-NPD)检测。香蕉样品加水5 mL用丙酮为萃取溶剂,石油醚液液分配,浓缩后用气相色谱(GC-NPD)检测。分别设置不同时间批次,同一批次间的平行样及实验室内人员分析,分别从方法灵敏度、方法准确度、方法精密度及其质量控制图、标准工作液的稳定性来探讨该方法的可靠性,结果表明该方法可以作为香蕉和小麦种戊唑醇残留检测的标准分析方法。 相似文献
37.
38.
The photocatalytic degradation of methylene blue(MB) over Fe-doped CaTiO3 under UV-visible light was investigated. The as-prepared samples were characterized using X-ray diffraction(XRD), scanning electron microscope(SEM) equipped with an energy dispersive spectrometer(EDS) system, Fourier transform infrared spectra(FT-IR), and UV-visible diffuse reflectance spectroscopy(DRS). The results show that the doping with Fe significantly promoted the light absorption ability of CaTiO3 in the visible light region. The Fe-doped CaTiO3 exhibited higher photocatalytic activity than CaTiO3 for the degradation of MB.However, the photocatalytic activity of the Fe-doped CaTiO3 was greatly influenced by the calcination temperature during the preparation process. The Fe-doped CaTiO3 prepared at500°C exhibited the best photocatalytic activity, with degradation of almost 100% MB(10 ppm)under UV-visible light for 180 min. 相似文献
39.
Removal of noxious dyes is gaining public and technological attention. Herein grafting polymerization was employed to produce a novel adsorbent using acrylic acid and carboxymethyl cellulose for dye removal. Scanning electron microscopy and Fourier-transform infrared spectroscopy verified the adsorbent formed under optimized reaction conditions. The removal ratio of adsorbent to Methyl Orange, Disperse Blue 2BLN and malachite green chloride reached to 84.2%, 79.6% and 99.9%, respectively. The greater agreement between the calculated and experimental results suggested that pseudo second-order kinetic model better represents the kinetic adsorption data. Equilibrium adsorptions of dyes were better explained by the Temkin isotherm. The results implied that this new cellulose-based absorbent had the universaiity for removal of dyes through the chemical adsorption mechanism. 相似文献
40.
港口细颗粒物(PM2.5)排放是沿海地区大气颗粒物污染的重要来源之一。我国《环境空气质量标准》(GB3095—2012)要求,港口总体规划和建设项目环境影响评价应包含PM2.5的影响预测及分析,然而目前我国还没有科学系统的港口营运期PM2.5环境影响评价方法。本文根据我国港口环境影响评价工作实践和文献报道,识别出运输船舶、工作船舶、港口机械设备和集疏运车辆的尾气为港口范围内主要的PM2.5排放源,其中运输船舶按照发动机类型和燃料品种进行分类,港内工作船舶和港口机械设备按照发动机功率进行分类,集疏运车辆按照尾气排放标准进行分类,并给出了相应的排放因子;考虑环境评价期间排放源活动水平的数据精度,建立了简化的"自下而上"的港口营运期PM2.5排放量估算方法;根据我国港口环境评价工作经验,选取ADMS模式作为港口营运期PM2.5环境影响预测的模式,从而建立了各类污染源排放速率的计算公式。 相似文献