Graphene-supported nanoscale zero-valent iron：Removal of phosphorus from aqueous solution and mechanistic study

Excess phosphorus from non-point pollution sources is one of the key factors causing eutrophication in many lakes in China,so finding a cost-effective method to remove phosphorus from non-point pollution sources is very important for the health of the aqueous environment. Graphene was selected to support nanoscale zero-valent iron(nZVI)for phosphorus removal from synthetic rainwater runoff in this article. Compared with nZVI supported on other porous materials,graphene-supported nZVI(G-nZVI) could remove phosphorus more efficiently. The amount of nZVI in G-nZVI was an important factor in the removal of phosphorus by G-nZVI,and G-nZVI with 20 wt.% nZVI(20% G-nZVI)could remove phosphorus most efficiently. The nZVI was very stable and could disperse very well on graphene,as characterized by transmission electron microscopy(TEM) and scanning electron microscopy(SEM). X-ray photoelectron spectroscopy(XPS),Fourier Transform infrared spectroscopy(FT-IR) and Raman spectroscopy were used to elucidate the reaction process,and the results indicated that Fe-O-P was formed after phosphorus was adsorbed by G-nZVI. The results obtained from X-ray diffraction(XRD) indicated that the reaction product between nZVI supported on graphene and phosphorus was Fe3(PO4)2·8H2O(Vivianite). It was confirmed that the specific reaction mechanism for the removal of phosphorus with nZVI or G-nZVI was mainly due to chemical reaction between nZVI and phosphorus.     

Multiple biomarkers response in maize (Zea mays L.) during exposure to copper

Biomarkers in higher plants played an important role to estimate exposure effects of pollutants in soil ecosystem and have received increasing attention in recent years. The qualitative and quantitative modifications arising in amplified fragment length polymorphism （AFLP） profiles as a measure of DNA effects were compared with a number of parameters, namely, the root length, total soluble protein content in root tips, chlorophylls content and shoot size to select the most sensitive biomarker responding to copper stress in the range of 0--600 mg/kg. The changes occurring in AFLP profiles of root tips following Cu treatment included loss of normal bands and appearance of new bands and variation in band intensity in comparison to that of the normal seedlings, A reduction in root length was observed at the 200 mg/kg of copper, which was accompanied with a decrease in total soluble protein content. According to their sensitivity to the copper toxicity, the above indicator rank in the following order： AFLP profiles 〉 total soluble protein content 〉 root length 〉 chlorophylls content 〉 shoot. We concluded that the AFLP offered a useful alternative hiomarker assay for the detection of genotoxic effects of environmental pollutants.     

国内国际时讯

<正>天津:居民用上外输LNG随着我国经济发展进入新常态以及国民环保意识的加强,关乎国计民生的各领域对LNG等清洁能源的需求逐步加大。近日,在"海巡0201"轮的引导和护航下,满载14.54万立方米LNG的"塞拉莱"轮安全靠泊南疆南LNG码头。此次供暖期以来,担负天津地区居民用气及京津冀地区工业用气运输任务的LNG船舶进出天     

黑龙江开展安全督查

本刊讯11月1日，黑龙江省安全生产信息网上发布消息，从11月7日起至党的十八大结束期间，黑龙江省政府安委会办公室将组织6个督查组分赴全省各地，开展全省安全生产督查，确保十八大期间全省安全生产形势稳定。     

惠州:生态修复“养”西湖

经过多年的整治与养护,惠州西湖南南湖水清湖美、人水和谐的美景给每一个到访的游人都留下了深刻的印象。这些美景的重现,与惠州市近年来正在大力推进的西湖生态修复工作息息相关。     

优质春播小麦99-5产量与气象影响因子回归分析

利用春播优质小麦99-5分期播种产量资料与同期气象资料进行回归分析,结果表明,小麦产量的高低与播种-抽穗期的积温、抽穗-开花期的日照和开花-成熟期的相对湿度呈显著相关.     

重金属铅,镉,锌对小麦DNA构象的影响

采用紫外吸收谱法，研究了不同浓度铅，镉，锌对小麦ＤＮＡ构象的影响。结果显示重金属铅，镉，锌均可影响小麦ＤＮＡ构象，使其紫外吸收峰值发生变化。其中，铅离子对小麦ＤＮＡ构象影响最大，５０μｇ／ｍｌ＾ｐｂ＾２＋处理使小麦出现明显减色反应，１０００μｇ／ｍｌｐｂ＾２＋处理使其沉淀析出；镉离子对小麦ＤＮＡ构象影响不大，可使其产生轻微减色反应，低浓度锌离子使小麦ＤＮＡ发生增色反应，而高浓度使小麦ＤＮＡ发生减色     

基于活化能指标的煤自燃倾向性及发火期研究

在煤的自燃及热分析动力学的基础上,结合对神东矿区3种煤样进行了热重实验,运用热重分析手段对煤从常温到燃点之间的氧化热解过程进行了研究。运用不同动力学机制模型函数分别对热重分析数据进行了处理和相关性分析,结果表明煤炭氧化热解过程符合一级化学反应动力学机制,据此求出活化能等动力学参数。对基于活化能指标的煤的自燃倾向性及自然发火期进行了初步研究。经过研究发现,该方法是科学的、客观的。     

采空区遗煤自燃过程及其规律的数值模拟研究

基于非均质多孔介质中的连续性方程、多相气体渗流———扩散方程和综合传热方程,建立了工作面动态推进下的采空区自燃数值模型。结合实例,从理论上描绘了工作面开采过程中采空区的漏风流态、氧、CO、瓦斯和温度等分布状态及其动态过程。计算中考虑了瓦斯涌出对自燃的耦合作用;工作面动态推进对自燃的影响,以及沿边界冒落非压实性对漏风供氧、自燃高温区产生的影响。从理论上重点讨论了采空区自燃与各因素的定量化关系,得出自然发火期与煤氧化速度、工作面风量二者均呈显著的反比例关系;对于综放工作面采场漏风供氧系统,自然发火期主要取决于煤的耗氧能力,提高工作面风量仅能扩大自燃高温区的范围,增大自燃的发生几率;提高推进度能显著延长采空区自然发火期,呈指数变化。     

安监网络在这里根深叶茂--福建省龙岩市安全生产基层基础建设年侧记

当记者和漳平市安监局局长傅小洲等人驱车来到拱桥镇安全生产监督站时,看到站门上醒目地写着"安全生产监督电话:13600……"怎么把自己的手机当监督电话了?记者纳闷问之,"安监站成立不久,还来不及装电话,况且平常都在外面跑,手机更好联系,我的手机24小时开机."黄长坤憨笑着,"我原来是从镇文化站选调过来了,干安全工作比较辛苦,但干了是实事,人也充实."