全文获取类型
收费全文 | 215篇 |
免费 | 15篇 |
国内免费 | 89篇 |
专业分类
安全科学 | 30篇 |
废物处理 | 26篇 |
环保管理 | 15篇 |
综合类 | 162篇 |
基础理论 | 47篇 |
污染及防治 | 35篇 |
评价与监测 | 3篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 5篇 |
2022年 | 2篇 |
2021年 | 11篇 |
2020年 | 8篇 |
2019年 | 3篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2015年 | 8篇 |
2014年 | 34篇 |
2013年 | 14篇 |
2012年 | 16篇 |
2011年 | 26篇 |
2010年 | 20篇 |
2009年 | 20篇 |
2008年 | 7篇 |
2007年 | 12篇 |
2006年 | 16篇 |
2005年 | 19篇 |
2004年 | 18篇 |
2003年 | 16篇 |
2002年 | 10篇 |
2001年 | 2篇 |
2000年 | 8篇 |
1999年 | 2篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 5篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有319条查询结果,搜索用时 15 毫秒
11.
Application of magnetic particles modified with amino groups to adsorb
copper ions in aqueous solution 总被引:1,自引:1,他引:0
A magnetic adsorbent can be easily recovered from treated water by magnetic force,without requiring further downstream treatment.In this research,amine-functionalized silica magnetite has been synthesized using N-[3-(trimethoxysilyl)propyl]-ethylenediamine(TPED) as a surface modification agent.The synthesized magnetic amine adsorbents were used to adsorb copper ions in an aqueous solution in a batch system,and the maximum adsorption was found to occur at pH 5.5 ± 0.1.The adsorption equilibrium data fitted t... 相似文献
12.
The adsorption behaviors of heavy metals onto novel low-cost adsorbent, red loess, were investigated. Red loess was characterized by X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectra. The results indicated that red loess mainly consisted of silicate, ferric and aluminum oxides. Solution pH, adsorbent dosage, initial metal concentration, contact time and temperature significantly influenced the efficiency of heavy metals removal. The adsorption reached equilibrium at 4 hr, and the experimental equilibrium data were fitted to Langmuir monolayer adsorption model. The adsorption of Cu(II) and Zn(II) onto red loess was endothermic, while the adsorption of Pb(II) was exothermic. The maximum adsorption capacities of red loess for Pb(II), Cu(II) and Zn(II) were estimated to be 113.6, 34.2 and 17.5 mg/g, respectively at 25°C and pH 6. The maximum removal efficiencies were 100% for Pb(II) at pH 7, 100% for Cu(II) at pH 8, and 80% for Zn(II) at pH 8. The used adsorbents were readily regenerated using dilute HC1 solution, indicating that red loess has a high reusability. All the above results demonstrated that red loess could be used as a possible alternative low-cost adsorbent for the removal of heavy metals from aqueous solution. 相似文献
13.
Surfactant-enhanced remediation (SER) is an effective method for the removal of volatile organic compounds (VOCs) from contaminated soils and groundwater. To reuse the surfactant the VOCs must be separated from the surfactant solutions. The water solubility of VOCs can be enhanced using reversible surfactants with a redox-acive group, (ferrocenylmethyl)dodecyldimethylammonium bromide (Fcl2) and (ferrocenylmethyl)tetradecanedimethylammonium bromide (Fcl4), above and below their critical micelle concentrations (CMC) under reducing (I+) and oxidative (I2+) conditions. The CMC values of Fcl2 and Fcl4 in I+ are 0.94 and 0.56 mmol/L and the solubilization of toluene by Fcl2 and Fcl4 in I+ for toluene is higher than the solubilization achieved with sodium dodecyl sulfate, cetyltrimethylammonium bromide and Trition X-114. The solubilization capacity of the ferrocenyl surfactants for each tested VOCs ranked as follows: ethylbenzene > toluene > benzene. The solubilities of VOCs by reversible surfactant in I+ were 30% higher than those in I2+ at comparable surfactant concentrations. The effects of Fcl4 concentrations on VOCs removal efficiency were as follows: benzene > toluene > ethylbenzene. However, an improved removal efficiency was achieved at low ferrocenyl surfactant concentrations. Furthermore, the reversible surfactant could be recycled through chemical approaches to remove organic pollutants, which could significantly reduce the operating costs of SER technology. 相似文献
14.
15.
16.
介绍了电厂脱硝技术选择性非催化还原法(SNCR),简述其脱硝工艺和反应原理,对脱硝效率和其影响因素等方面进行了分析,总结了SNCR脱硝技术的优缺点,可作为燃煤电厂脱硝工艺的参考。 相似文献
17.
18.
19.
20.