微界面理论及模式在环境水质学中的应用

介绍了微界面理论的核心内容及其在有机有毒化学品、悬浮沉积物、水处理药剂等环境水质学中的应用。     

有毒物质事故泄漏对河流污染的数学模拟

通过对有毒物质事故泄漏行为的数学模拟分析，提出了一种计算有毒物质河流断面超标风险率的方法，并通过实例模拟分析，探讨了在一定条件下，即为确保饮用水质的安全，把超标风险率控制在一定范围内，应采取的措施。     

条件价值评估法研究居民改善空气质量需求

采用条件价值评估方法,调查了北京市居民改善空气质量的支付意愿,初步分析居民对空气质量这种公共环境物品的需求状况,探讨了影响居民对公共环境物品需求的人口和社会经济因素.研究结果表明,居民的经济状况是影响对公共环境物品需求的重要因素,居民的经济状况比较好则对公共环境物品的需求越高,但是支付意愿与家庭收入弹性<1.随着教育水平的提高,对公共环境物品的需求也增加.另外,性别和健康状况也影响居民对公共环境物品的需求.从政策实施的角度来看,政府必须完善人们对公共环境物品需求偏好的表达机制,才能制定政策实现公共环境物品的有效供给.     

Variation of grain Cd and Zn concentrations of 110 hybrid rice cultivars grown in a low-Cd paddy soil

Enhanced Cd uptake and Zn depletion in rice grains and high potential for food Cd exposure by the high-yielding hybrid cultivars of China had been addressed. A field experiment was conducted in 2006 to determine the di erence in grain Cd and Zn between cultivars. Total 110 cultivars including super rice and common hybrid rice cultivars were grown on a single paddy soil (Entic Haplaquept) with a neutral reaction and low total Cd content. Grain Cd and Zn concentrations were determined with graphite atomic adsorption spectrophotometer (GFAAS) and flame atomic adsorption spectrophotometer (AAS) respectively.Wide variation of Cd content in grain was found in a range of 0.004–0.057 mg/kg, while the Zn content in a range of 10.25–30.06 mg/kg among the cultivars. Higher Cd but lower Zn concentration in grains of super rice cultivars was observed compared to the common hybrid ones. A highly significant positive linear correlation of grain Cd/Zn with grain Cd was found for super rice and common hybrid cultivars, meanwhile much higher slope for these hybrid cultivars than the reported non-hybrid cultivars was also observed. Using the limit value of the Chinese chemical guidelines for foods (MOHC and SSC, 2005), calculated potential risk of food Cd exposure with “Zn hungry” through diet intake was prominent with all the studied 110 hybrid rice cultivars, possessing high potential health problems for rice production in South China using the super rice cultivars. Breeding of genotypes of rice cultivars with low grain Cd and low Cd/Zn ratio is needed for rice production in acidic red soils where Cd bioavailability is prevalently high.     

Bioaccumulation and depuration of chromium in the selected organs and whole body tissues of freshwater fish Cirrhinus mrigala individually and in binary solutions with nickel

Contamination of aquatic ecosystems with heavy metals has been receiving increased worldwide attention due to their harmful e ects on human health and other organisms in the environment. Most of the studies dealing with toxic e ects of metals deal with single metal species, while the aquatic organisms are typically exposed to mixtures of metals. Hence, in order to provide data supporting the usefulness of freshwater fish as indicators of heavy metal pollution, it has been proposed in the present study to investigate the bioaccumulation and depuration of chromium in the selected organs of freshwater fingerlings Cirrhinus mrigala, individually and in binary solutions with nickel. The results show that the kidney is a target organ for chromium accumulation, which implies that it is also the “critical” organ for toxic symptoms. The results further show that accumulation of nickel in all the tissues of C. mrigala is higher than that of chromium. In addition, the metal accumulations of the binary mixtures of chromium and nickel are substantially higher than those of the individual metals, indicating synergistic interactions between the two metals. Theoretically the simplest explanation for an additive joint action of toxicants in a mixture is that they act in a qualitatively similar way. The observed data suggest that C. mrigala could be suitable monitoring organisms to study the bioavailability of water-bound metals in freshwater habitats.     

城市固体废弃物污染治理范式

党的十七大报告中提出建设生态文明,基本形成节约能源资源和保护生态环境的产业结构、增长方式、消费模式,体现人与自然的和谐共生,经济建设与环境保护的协调发展。人类在享受物质文明的同时不能忽略生态文明,否则引起的生态和环境问题会影响到社会经济的可持续发展。生态文明应该体现在社会的各个层面,尤其是作为人类文明标志的城市,代表现代社会发展形态的都市,饱受废弃物污染之苦的人口聚集地,更应该注重对废弃物的治理。如何有效治理城市固体废弃物的污染,什么样的治理范式是合理高效的？从环境经济的角度讲,城市固体废弃物属于准公共物品,兼有公共物品和私人物品双重属性,涉及到多方利益主体,因此需要构建多方参与的互动型治理范式。     

我国近海有毒微藻及其毒素的分布危害和风险评估

近年我国海域有害赤潮频发,赤潮优势种的变化显著,最近7a记录了51种引发赤潮的优势赤潮生物,其中由有毒微藻引发的赤潮增加。有毒微藻在我国海域广泛分布,至少3个株产麻痹性贝毒的亚历山大藻,5种能产生腹泻性贝毒软海绵酸毒素和鳍藻毒素、以及扇贝毒素的鳍藻在我国沿海都有分布;产生虾夷扇贝毒素的三种甲藻在北黄海常年存在。我国多种贝类中已发现麻痹性贝毒、软海绵酸毒素和鳍藻毒素、扇贝毒素、虾夷扇贝毒素和环亚胺毒素等多种微藻毒素。本文较系统的归纳综述了我国有害赤潮、优势种的变化趋势和分布特点,产生的藻毒素结构;我国双壳贝类等海洋生物中存在的微藻毒素的种类结构;首次利用风险商值法研究评估了我国贝类的健康风险。结果表明,只有春季来自福建的2个样品具有食用风险;但大连海区的贝类样品、评估值全都接近安全限值,可能表明具有某种区域性风险;在春末夏初,大窑湾的贻贝风险最大,其次是扇贝,牡蛎的风险最小;不同的贝器官,富集藻毒素的能力差别大,消化腺中的藻毒素含量远高于其它器官,不同的食用方式可能会导致不同的中毒风险。总体上,我国沿海常见种双壳贝类的麻痹性贝毒和虾夷扇贝毒素食用风险低。     

混合物质谱的简单分类算法

有毒化合物质谱分类是以光谱数据的数值特性为基础的。这此数据的计算机分类提供了各种参数,用以确定属于有毒化合物中某一类的对应化合物。质谱数据的简单分类算法常被用于自相关变换质谱的主分量建模。主分量的有效值为相互确认为确定。对环境空气中１１９种被监测的有毒化合物,有色谱－质谱联用的试验和校正数据所得到的４类预报正确率为７６．５％。     

加强我国化学品危险性管理的基础工作

在现代社会生活中,化学品已成为必不可少的物质。这给我们的生活带来了极大的方便,但也形成了新的全球性的公害问题。 为了控制或减轻化学品对人体健康和环境的危害,我们必须增强控制化学品公害的能力。但是能力的培养是长期的,多方面的,尤其是发展中国家,