全文获取类型
收费全文 | 6948篇 |
免费 | 789篇 |
国内免费 | 3213篇 |
专业分类
安全科学 | 604篇 |
废物处理 | 398篇 |
环保管理 | 663篇 |
综合类 | 6497篇 |
基础理论 | 521篇 |
污染及防治 | 2087篇 |
评价与监测 | 102篇 |
社会与环境 | 17篇 |
灾害及防治 | 61篇 |
出版年
2024年 | 77篇 |
2023年 | 192篇 |
2022年 | 295篇 |
2021年 | 362篇 |
2020年 | 330篇 |
2019年 | 376篇 |
2018年 | 249篇 |
2017年 | 283篇 |
2016年 | 355篇 |
2015年 | 474篇 |
2014年 | 834篇 |
2013年 | 533篇 |
2012年 | 595篇 |
2011年 | 601篇 |
2010年 | 553篇 |
2009年 | 604篇 |
2008年 | 602篇 |
2007年 | 571篇 |
2006年 | 550篇 |
2005年 | 426篇 |
2004年 | 381篇 |
2003年 | 343篇 |
2002年 | 249篇 |
2001年 | 180篇 |
2000年 | 149篇 |
1999年 | 130篇 |
1998年 | 92篇 |
1997年 | 85篇 |
1996年 | 93篇 |
1995年 | 82篇 |
1994年 | 64篇 |
1993年 | 73篇 |
1992年 | 48篇 |
1991年 | 52篇 |
1990年 | 33篇 |
1989年 | 32篇 |
1986年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
391.
采用文献调研法比较评价了膜生物反应器与传统生物工艺对垃圾渗滤液的处理效果。结果表明,渗滤液的水质特征(主要指COD)主要由渗滤液年龄决定,B/C值和渗滤液年龄对COD去除有重要影响。传统生物处理常采用多级组合工艺,渗滤液特性、工艺单元数、水力停留时间和有机负荷率等是影响COD去除的重要参数。近年来,MBR工艺的应用日益广泛,对于B/C值较低的老龄渗滤液,MBR工艺可获得更好的COD去除效果,也有利于废水的膜深度处理。 相似文献
392.
Chih Ming M Ya Wen Lee Gui Bing Hong Te Li Su Je Lueng Shie Chang Tang Chang 《环境科学学报(英文版)》2011,23(4):687-692
TiO2 nanoparticles, doped with di erent Pt contents, were prepared by a modified photodeposition method using Degussa P-25 TiO2,
H2PtCl6 6H2O and methanol as the solvents. The physicochemical properties of Pt/TiO2 were investigated by the nitrogen adsorption
and desorption isotherm measurement technique, X-ray di raction analysis and photoluminescence spectra, respectively. Reaction rates
from photocatalytic removal of dichloromethane over Degussa P-25 TiO2 and Pt/TiO2 were evaluated. The average diameter and BET
surface area of the TiO2 catalyst particles were 300 nm and 50 m2/g, respectively. The degradation e ciency was 99.0%, 82.7%, 55.2%,
and 57.9% with TiO2 at inlet concentrations of 50, 100, 200, and 300 ppm, respectively. And the degradation e ciency was 99.3%,
79.7%, 76.5%, and 73.4% with a 0.005 wt.% Pt/TiO2 at inlet concentrations of 50, 100, 200, and 300 ppm, respectively. In addition, we
found that the photoluminescence emission peak intensities decreased with increases in the doping amount of Pt, which indicates that
the irradiative recombination was weakened. Furthermore, the results showed that the UV/0.005 wt.% Pt/TiO2 process was capable of
e ciently decomposing gaseous DCM in air. 相似文献
393.
Chemical forms of Zn, Ni, Cu, and Pb in municipal sewage sludge were investigated by adding humus soil to sludge and by
performing sequential extraction procedures. In the final sludge mixtures, Zn and Ni were mainly found in Fe/Mn oxide-bound (F3) and
organic matter/sulfide-bound (F4) forms. For Zn, exchangeable (F1), carbonate-bound (F2), and F3 forms were transformed to F4 and
residual forms (F5). For Ni, F1 and F2 forms were transformed to F1, F2, and F3 forms. Both Cu and Pb were strongly associated with
the stable forms F4 and F5. For Cu, F2 and F3 forms were major contributors, while for Pb, F3 and F4 forms were major contributors to
F5. Humus soil dosage and pH conditions in the sludge were strongly correlated with the forms of heavy metals. Five forms were used
to evaluate metal mobilities in the initial and final sludge mixtures. The mobilities of the four heavy metals studied decreased after 28
days. The metal mobilities in the final sludge mixtures were ranked in the following order: Ni > Zn > Cu = Pb. Leaching tests showed
that the mobilities of Zn and Ni in lower pH conditions (pH 4) were higher than those in higher pH conditions (pH 8). 相似文献
394.
F. Olcay Topac Sagban 《环境科学学报(英文版)》2011,23(4):616-623
The possible impacts on nitrogen-cycle in a p-nitrophenol (PNP) polluted soil and the e ectiveness of wastewater sludge amendments
in restoring nitrification potential and urease activity were evaluated by an incubation study. The results indicated that PNP at 250 mg/kg
soil inhibited urease activity, nitrification potential, arginine ammonification rate and heterotrophic bacteria counts to some extents.
After exposure to PNP, the nitrification potential of the tested soil was dramatically reduced to zero over a period of 30 days. Based
on the findings, nitrification potential was postulated as a simple biochemical indicator for PNP pollution in soils. Nitrogen-cycling
processes in soils responded positively to the applications of wastewater sludges. A sludge application rate of 200 tons/ha was su cient
for successful biostimulation of these nitrogen processes. The microbial activities in sludge-amended, heavy PNP-polluted soils seemed
to recover after 30–45 days, indicating the e ectiveness of sludge as a useful soil amendment. 相似文献
395.
Pretreatment of thickened waste activated sludge (TWAS) by combined microwave and alkaline pretreatment (MAP) was studied to
improve thermophilic anaerobic digestion efficiency. Uniform design was applied to determine the combination of target temperature
(110–210°C), microwave holding time (1–51 min), and NaOH dose (0–2.5 g NaOH/g suspended solids (SS)) in terms of their effect
on volatile suspended solids (VSS) solubilization. Maximum solubilization ratio (85.1%) of VSS was observed at 210°C with 0.2
g-NaOH/g-SS and 35 min holding time. The effects of 12 different pretreatment methods were investigated in 28 thermophilic batch
reactors by monitoring cumulative methane production (CMP). Improvements in methane production in the TWAS were directly related
to the microwave and alkaline pretreatment of the sludge. The highest CMP was a 27% improvement over the control. In spite of the
increase in soluble chemical oxygen demand concentration and the decrease in dewaterability of digested sludge, a semi-continuous
thermophilic reactor fed with pretreated TWAS without neutralization (at 170°C with 1 min holding time and 0.05 g NaOH/g SS)
was stable and functioned well, with volatile solid (VS) and total chemical oxygen demand (TCOD) reductions of 28% and 18%,
respectively, which were higher than those of the control system. Additionally, methane yields (L@STP/g-CODadded, at standard
temperature and pressure (STP) conditions of 0°C and 101.325 kPa) and (L@STP/g VSadded) increased by 17% and 13%, respectively,
compared to the control reactor. 相似文献
396.
Comparative study of heavy metal and pathogenic bacterial contamination in
sludge and manure in biogas and non-biogas swine farms 总被引:1,自引:0,他引:1
Phitsanu Tulayakul Alongkot Boonsoongnern Suwicha Kasemsuwan Srisamai Wiriyaramp Juree Pankumnoe Suwanna Tippayaluck Hathairad Hananantachai RatchaneekornMingkhwan Ramnaree Netvichian Sutha Khaodhiar 《环境科学学报(英文版)》2011,23(6):991-997
The objective of this study is to determine and compare the heavy metal (Zn, Cu, Cd, Pb) and bacterial (E. coli, coliform and
Salmonella spp.) contamination between swine farms utilizing biogas and non-biogas systems in the central part of Thailand. Results
showed that average levels of E. coli, coliform, BOD, COD, Zn, Cu and Pb in sludge from the post-biogas pond were higher than the
standard limits. Moreover, the levels of E. coli, coliform, Cd and Pb were also higher than the standard limits for dry manure. The levels
of E. coli, coliform and BOD on biogas farms were lower than on non-biogas farms. Following isolation of Salmonella spp:; it was
found that Salmonella serovars Rissen was the most abundant at 18.46% (12/65), followed by Anatum 12.31% (8/65), and Kedougou
9.23% (6/65). The pathogenic strains of Salmonella serovars Paratyphi B var. java and Typhimurium were present in equal amounts at
4.62% (3/65) in samples from all swine farms. This study revealed that significant reduction in E. coli and coliform levels in sludge
from covered lagoon biogas systems on swine farms. The presence of Salmonella as well as Cd and Pb, in significant amount in dry
manure, suggests that there is a high probability of environmental contamination if it is used for agricultural purposes. Thus, careful
waste and manure disposal from swine farms and the regular monitoring of wastewater is strongly recommended to ensure the safety
of humans, other animals and the environment. 相似文献
397.
398.
399.
市政污泥半干化-焚烧一体化对环境影响的评价 总被引:2,自引:2,他引:0
随着市政污水处理厂的不断增加,城市污泥大幅增长,污泥半干化-焚烧一体化是污泥无害化、减量化和资源化的有效途径之一,通过计算污泥半干化-焚烧过程中物料平衡和热量平衡,同时对排放物进行分析,从而评价市政污泥处理对生态环境的影响,研究的结果表明:每处理100t湿污泥,需要掺烧4.89t无烟煤,在焚烧的过程中,在没有净化工艺的... 相似文献
400.
La-Co-Fe-Cu/HZSM-5在尾气碳颗粒燃烧中的催化性能 总被引:1,自引:1,他引:0
采用柠檬酸络合低温浸渍法制备分子筛负载钙钛矿型复合氧化物催化剂。采用XRD、SEM和H2-TPR等手段对催化剂性能进行表征,并在微型固定床反应器中对催化剂进行活性评价。结果表明,在钙钛矿型复合氧化物中进行B位离子掺杂,可以改善催化活性,碳颗粒燃烧温度降低。在20%LaCoO3/HZSM-5催化剂中用铁离子部分取代钴离子可以改善碳颗粒的燃烧性能,取代量增加碳颗粒燃烧温度降低,但是生成CO2的选择性也降低,以20%LaCo0.2Fe0.8O3/HZSM-5为催化剂,Tig、Tm和Tf分别为256℃、399℃和403℃,但生成CO2的选择性只有72.5%。在20%LaCo1-xFexO3/HZSM-5中的钙钛矿型复合氧化物B位离子中加入铜离子后,在碳颗粒燃烧反应中生成CO2的选择性得到明显改善,Sco2提高10个单位以上。以20%LaCo0.2Fe0.6Cu0.2O3/HZSM-5为催化剂,在碳颗粒燃烧反应中生成CO2的选择性可以达到94.7%,Tig、Tm和Tf分别为242℃、427℃和445℃。 相似文献