Solar driven nitrous acid formation on building material surfaces containing titanium dioxide: A concern for air quality in urban areas?

The photoenhanced uptake of nitrogen dioxide (NO₂) to the surface of commercially available self-cleaning window glass has been studied under controlled laboratory conditions. This material is one of an array of modern building products which incorporate titanium dioxide (TiO₂) nanoparticles and are finding increasing use in populated urban areas. Amongst the principal drivers for the use of these materials is that they are thought to facilitate the irreversible removal of pollutants such as NO₂ and organic molecules from the atmosphere and thus act to remediate air quality. While it appears that TiO₂ materials do indeed remove organic molecules from built environments, in this study we show that the photoenhanced uptake of NO₂ to one example material, self-cleaning window glass, is in fact accompanied by the substantial formation (50–70%) of gaseous nitrous acid (HONO). This finding has direct and serious implications for the use of these materials in urban areas. Not only is HONO a harmful respiratory irritant, it is also readily photolysed by solar radiation leading to the formation of hydroxyl radicals (OH) together with the re-release of NO_x as NO. The net effect of subsequent OH initiated chemistry can then be the further degradation of air quality through the formation of secondary pollutants such as ozone and VOC oxidation products. In summary, we suggest that a scientifically conceived technical strategy for air quality remediation based on this technology, while widely perceived as universally beneficial, could in fact have effects precisely opposite to those intended.     

Comments on current environmental events in Kuwait

This article describes and assesses the impact of oil spillage and oil well fires on Kuwait and its surroundings. The marine ecology of the Arabian Gulf is shown to be relatively resistant to damage from oil spillage. The risks of the contamination of thermal desalination plants by oil and oil products are assessed, and remedies are suggested. Air pollution from burning oil wells is described and its consequences are predicted. Editor’s note: Professor Hosny Khordagui worked as a research scientist at the Environmental and Earth Science Department of the Kuwait Institute for Scientific Research. The Iraqi invasion of Kuwait on August 2, 1990, led to the permanent loss of most of his data, research reports, and laboratory equipment, and Prof. Khordagui was constrained to live under the Iraqi occupation for a few weeks. His article “A Conceptual Approach to the Selection of a Control Measure for Residual Chlorine Discharge in Kuwait Bay” will appear in a forthcoming issue ofEnvironmental Management.     

西昌市大气污染现状调查及保护对策

本文对西昌市大气污染现状进行调查分析，揭示了大气环境污染的特征及其变化规律，从宏观上提出了保护大气环境的对策。     

Evaluation of methods for determining adverse impacts of air pollution on terrestrial ecosystems

Methods used to determine adverse impacts of air pollution on four levels of biological organization of terrestrial ecosystems were evaluated for their use in decision making by federal land managers of class I areas and as guidelines for scientists employed to design field studies in these areas. At the level of the individual, visible injury, biomass, and sulfur uptake were the most often used components; at the population level, natality and mortality; at the community level, diversity; and at the ecosystem level, biogeochemical cycling. Most studies focused on structural responses of individual organisms. These components are relatively sensitive and are easy and inexpensive to measure; however, linkages of these parameters to adverse impacts on populations, communities, or ecosystems are lacking. Measurements of effects of air pollution at the higher levels of organization are confounded by natural variability, long response times, climatic variation, pathogens, and other factors. In addition, the lack of replication and of true control areas creates severe problems for design of monitoring programs and testing of hypotheses concerning effects.     

Designating Air Quality Management Areas (AQMAs) in the UK Implications for Securing UK Air Quality Objectives

Across the United Kingdom, the majority of local authoritieshave now completed their first phase of local air qualityreview and assessment work, as required under the AirQuality Strategy for England, Scotland, Wales and NorthernIreland (DETR, 2000a). Emerging from this first phasework is an anticipated suite of over 110 Air QualityManagement Areas (AQMAs). These areas are identifiedlocations where one or more of the national air qualityobjectives are predicted to exceed by specific target dates,and their spatial extent and shape is emerging as highlyvariable. Local authorities are guided to use a variety ofscientific tools to underpin the scientific assessments, anda consideration of uncertainty in both the tools used andsubsequent delineation of AQMAs is likely to affect theemerging management areas significantly. With subsidiarity underpinning the process of local air qualitymanagement (LAQM), local decision-making is anticipated toinfluence the outcome of the LAQM process in its entirety,with the declaration of AQMAs necessitating the preparationand implementation of air quality action plans. UKexperience of the effective management of local air quality,through the designation of AQMAs, demonstrates a valuableframework for other European countries developing mechanismsto manage air quality locally.     

彭州市环境空气质量变化趋势及规律分析

“九五”期间 ,彭州市环境空气监测主要因子有二氧化硫、二氧化氮、总悬浮颗粒物、降尘和降水。市区空气中主要污染物排序依次为降尘、总悬浮颗粒物、二氧化硫、二氧化氮。其季节变化规律一般为第一季度 >第二季度 >第四季度 >第三季度。主要污染物年变化依次为降尘、总悬浮颗粒物、二氧化硫、二氧化氮 ,在“九五”期间除降尘量出现缓慢下降趋势外 ,其余 3项均不明显。     

The connecticut indirect source review: A methodology and model for evaluating CO concentrations

The body of information presented in this paper is directed to air pollution engineers who are concerned with the effect of indirect sources on ambient concentrations of carbon monoxide (CO). Data taken under controlled conditions are used to empirically derive and calibrate a model for predicting CO concentrations in the vicinity of roadway intersections and other points of possible vehicular congestion. Since the predicted free flow CO contribution of vehicles traveling at normal road speeds is relatively low, it is concluded that idling vehicles at points of congestion are the major cause of CO violations, and that state and federal programs should place more emphasis on relieving congestion and reducing idling emission rates in new vehicles.     

Air pollution in California: Manufacturing vs. services

Relative to manufacturing, service activities are often considered by planners and officials to generate considerably less environmental pollution. This hypothesis is tested by means of an examination of the economic linkages of both manufacturing and service activities and of the resulting direct and indirect emissions of five air pollutants per dollar of output in the California statewide air basin and in four regional basins within the state. Overall acceptance or rejection of the hypothesis depends in part on the particular pollutant and air basin considered but, most importantly, on the judgement as to what activities are to be considered as service activities.This paper is based on research sponsored by the California Air Resources Board under Agreement A7-143-30.     

Monitoring environmental pollution in Erzurum by chemical analysis of Scots pine (Pinus sylvestris L.) needles

Pollution distribution maps of copper (Cu), zinc (Zn) and lead (Pb) for Erzurum province were developed on the basis of chemical analysis of Scots pine (Pinus sylvestris L.) needles collected from randomly selected sampling points during 2 years. The maps show deposition zones for the studied elements and could help in identification of sources and directions of air pollution dispersion. This study indicated that vegetation in Erzurum was greatly endangered by sulphur dioxide (SO(2)), whereas Zn does not pose an immediate threat to vegetation in most of the country's territory. However, in the city center, main and secondary road agglomeration, very high pollution with Pb and Cu could limit growth. Higher levels of SO(2) measured in some areas of Erzurum might be harmful for human and animal health. Results of this study indicated that Scots pine needles were not contaminated by Zn.