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11.
Aluminum formate (AF), a degradable and non-corrosive coagulant, was synthesized from aluminum hydroxide and formic acid. Polyamidine (PA), as a coagulation aid, was combined with AF for dye wastewater treatment. AF was characterized by XPS, FT-IR, viscosity, zeta potential, mass spectrum and XRD, and the flocculation properties of the dual-coagulation system were characterized by FT-IR and SEM. The results showed that COOH, Al2O3-Al and O2-Al bonds were formed in the AF synthesis process, and AF had a higher molecular weight and higher charge neutralization ability than PAC. The hydrolysates of AF were determined to contain Al13 Al11 and Al2, and the components of AF were confirmed to comprise a mixture including aluminum formate (C3H3AlO6) and its hydrate. When the color removal efficiency reached 100% in jar tests, the optimized dosage of AF/PA was 18.91/0.71 mg/L, while the optimized dosage of PAC/PA was 21.19/0.91 mg/L. According to the variance analysis, the interaction between AF/PA and PAC/PA were insignificant in macroscopic view. FT-IR spectrum indicated AF captured pollutant by means of CCO bond, PAC captured pollutant by δ CH, CC and δ CH. Overall, although the coagulation mechanism of AF was different from that of PAC, AF/PA showed better coagulation efficiency than PAC/PA in dye wastewater treatment. 相似文献
12.
Many substances react with water in such a way that flammable gases are formed. For transport issues this reaction may possess a considerable hazard especially if the cargo is wetted by rain or by water from other sources. In the UN Recommendations on the Transport of Dangerous Goods these kinds of problems are addressed. The UN test N.5 “Test method for substances which in contact with water emit flammable gases” corresponds to this hazard. Classification according to the test method is done by measurement of the gas evolution rate of the flammable gas by any suitable procedure. At BAM a gravimetric approach is used to measure the gas evolution rate. In this paper we present the evaluation of the apparatus by means of an absolute calibration routine utilizing a reaction where a known amount of gas is produced as well as the evaluation of important parameters influencing the gas evolution rate using different substances. It can be shown that the apparatus is capable of measuring absolute gas volumes as low as 6 mL with an acceptable error of about 17% as determined from the reaction of Mg with demineralized water. 相似文献
13.
A continuously expanding group of commodities are being priced on commodity exchanges. This paper explains the causes to the increasing preference of exchanges as pricing instruments. It also provides the detail of the shift in the 1970s and 1980s from producer determined prices to prices set by commodity exchanges for three major commodities—aluminum, nickel and petroleum. 相似文献
14.
针对具体工件对根限变形程度下纯铝反挤压的变形力进行研究,分析了各种计算方法的适用范围,并与工艺试验的实测值进行了比较. 相似文献
15.
介绍了对处理铝材加工含Al^3+的酸性废液过程中产生的二次污染物Al(OH)3凝胶废渣的应用。 相似文献
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A.H. El‐Sebae M.E. Abdel‐Ghanv D. Shalloway M.M. Abou Zeid J. Blancato M.A. Saleh 《Journal of environmental science and health. Part. B》2013,48(6):763-777
Abstract Phosphorylation is an indispensable process for energy and signal transduction in biological systems. AlCl3 at 10 nM to 10 uM range activated in‐vitro [γ‐32P)ATP phosphorylation of the brain (tau) T protein in both normal human or E.coli expressed T forms; in the presence of the kinases P34, PKP, and PKC. However, higher concentrations of ALCl3 inhibited the T phosphorylation with P34, PKP, and PKC to a maximum at 1 mM level. AlCl3 at 100 uM to 500 uM range induced non‐enzymatic phosphorylation of T with γ‐ATP, γ‐GTP, and α‐GTP. AlCl3 activated histone phosphorylation by P34 in a similar pattern. The hyperphosphorylation of T by Al3+ was accompanied by molecular shift and mobility retardation in SDS‐PAGE. This may demonstrate the mechanism of the longterm neurological effect of Al3+ in human brain leading to the formation of the neurofibrillary tangles related to Alzeheimer's disease. 相似文献
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Luciane Almeri Tabaldi Denise Cargnelutti Jamile Fabbrin Gonalves Luciane Belmonte Pereira Gabriel Y Castro Joseila Maldaner Renata Rauber Liana Vernica Rossato Dilson Antnio Bisognin Maria Rosa Chitolina Schetinger Fernando Teixeira Nicoloso 《Chemosphere》2009,76(10):1402-1409
The objective of this study was to evaluate whether the oxidative stress caused by aluminum (Al) toxicity is an early symptom that can trigger root growth inhibition in Macaca (Al-sensitive) and SMIC148-A (Al-tolerant) potato clones. Plantlets were grown in a nutrient solution (pH 4.00) with 0, 100 and 200 mg Al L−1. At 24, 72, 120 and 168 h after Al addition, root length and biochemical parameters were determined. Regardless of exposure time, root length of the Macaca clone was significantly lower at 200 mg Al L−1. For the SMIC148-A clone, root length did not decrease with any Al treatments. Al supply caused lipid peroxidation only in Macaca, in both roots (at 24, 72, 120 and 168 h) and shoot (at 120 and 168 h). In roots of the Macaca, catalase (CAT) and ascorbate peroxidase (APX) activity decreased at 72 and 120 h, and at 24, 72 and 120 h, respectively. At 168 h, both activities increased upon addition of Al. In roots of the SMIC148-A, CAT activity increased at 72 and 168 h, whereas APX activity decreased at 72 h and increased at 24, 12 and 168 h. The Macaca showed lower root non-protein thiol group (NPSH) concentration at 200 mg Al L−1 in all evaluations, but the SMIC148-A either did not demonstrate any alterations at 24 and 72 h or presented higher levels at 120 h. This pattern was also observed in root ascorbic acid (AsA) concentration at 24 and 120 h. The cellular redox status of these potato clones seems to be affected by Al. Therefore, oxidative stress may be an important mechanism for Al toxicity, mainly in the Al-sensitive Macaca clone. 相似文献
20.
Ali Asghar Tofigh Mohammad Reza Rahimipour Mohsen Ostad Shabani Mehdi Alizadeh Fatemeh Heydari Ali Mazahery Mansour Razavi 《Journal of Manufacturing Processes》2013,15(4):518-523
In this research, an experimental study of reinforcing alumina nano-particles into the aluminum alloy matrix was implemented to verify the accuracy of modeling results obtained by feed forward neural networks. Artificial neural network combined with numerical technique were used to predict the various parameters of mechanical properties such as hardness, tensile and compressive yield stress, UTS and elongation percentage. Much experimentation were taken to discover a suitable number of hidden neurons, avoid detraction from the trainability and enable feed forward neural networks to solve more complex problems. The predictions were found to be consistent with experimental measurements. 相似文献