统计分析方法在大气环境监测数据符合性分析中的应用探讨

通过汇总分析气井的试气环境监测数据,选择AERMOD模式,运用EIAProA软件模拟预测试气SO2浓度,对实测和预测数据进行F检验和t检验,验证其方差是否符合显著性要求,同时检验其相关系数、系统均方差和非系统均方差,结果表明符合指数,满足论文预设的70%的要求。     

Soil attenuation of As(III,V) and Se(IV,VI) seepage potential at ash disposal facilities

Leachate from ash landfills is frequently enriched with As and Se but their off-site movement is not well understood. The attenuation potential of As and Se by soils surrounding selected landfills during leachate seepage was investigated in laboratory column studies using simulated ash leachate. As(III, V) and Se(IV, VI) concentrations as well as pH, flow rate, and a tracer were monitored in influent and effluent for up to 800 pore volumes followed by sequential desorption, extraction, and digestion of column segments. Column breakthrough curves (BTCs) were compared to predictions based on previously measured sorption isotherms. Early As(V) breakthrough and retarded As(III) breakthrough relative to predicted BTCs are indicative of oxidative transformation during seepage. For Se(VI), which exhibits linear sorption and the lowest sorption propensity, measured BTCs were predicted fairly well by equilibrium sorption isotherms, except for the early arrival of Se(IV) in one site soil, which in part, may be due to higher column pH values compared to batch isotherms. Most of the As and Se retained by soils during leaching was found to be strongly sorbed (60–90%) or irreversibly bound (10–40%) with <5% readily desorbable. Redox potential favoring transformation to the more sorptive valence states of As(V) and Se(IV) will invoke additional attenuation beyond equilibrium sorption-based predictions. With the exception of Se(IV) on one site soil, results indicate that attenuation by down-gradient soils of As and Se in ash landfill seepage will often be no less than what is predicted by equilibrium sorption capacity with further attenuation expected due to favorable redox transformation processes, thus mitigating contaminant plumes and associated risks.     

Carbaryl, 2,4-D,and Triclopyr Adsorption in Thatch-Soil Ecosystems

Thatch development in intensively managed turf sites may cause environmental concerns for greater sorption or leaching of applied chemicals in terrestrial ecosystems. To determine the adsorption potential of Carbaryl (1-Napthyl N-methylcarbamate), 2,4-D (2,4-dichloro-phenoxyacetic acid), and Triclopyr (3,5,6-trichloro-2-pyridinyloxyacetic acid) in turf ecosystems, composite thatch and underlying soil samples from three- and six-year-old stands of cool-season Southshore creeping bentgrass (Agrostis palustris Huds.) and warm-season Meyer zoysiagrass (Zoysia japonica Steud.) were collected. The samples were processed and analyzed for total organic carbon (C_Org); extractable (C_Ext), humic (C_HA) and fulvic acid (C_FA); anthrone reactive nonhumic carbon (ARC) fractions; and C_HA and C_FA associated iron (Fe) contents. Pesticide adsorption capacity (K _f ) and intensity (1/n), organic carbon partition coefficient (K _OC ) and Gibbs free energy change (Δ G) were calculated for thatch materials and the underlying soils using a modified batch/flow technique. Both bentgrass (BT) and zoysiagrass thatch (ZT) contained a greater concentration of C_Ext, C_FA, C_HA, and ARC than the respective soils (BS and ZS). The C_Ext, C_FA, C_HA, and ARC concentration was higher in BT compared with ZT. The BT contained a greater concentration of bound Fe in both C_FA and C_HA fractions than in BS, whereas ZT had more bound Fe in C_HA fraction than in ZS. On average, the BT had a greater concentration of bound Fe in C_Ext, C_FA, and C_HA fractions than in the ZT. Among the pesticides, Carbaryl had higher K _f and 1/n values than 2,4-D and Triclopyr for both thatch and soil. Although the K _OC and Δ G values of Carbaryl were higher in both BT and ZT than in the underlying soils, the K _OC and Δ G values of 2,4-D were significantly higher in BS and ZS than in the overlying thatch materials. The 2,4-D and Triclopyr had higher leaching indices (LI) than Carbaryl for both BT and ZT materials than the respective soils. The Carbaryl, however, had a higher LI for soils than for thatch materials. Averaged across thatch materials and soils, C_Org accounted for 96, 85, and 84% variations in Carbaryl, 2,4-D, and Triclopyr adsorption, respectively. Among the C_Org fractions, lignin followed by C_FA and C_HA accounted for greater adsorption of pesticides, especially Carbaryl. The concentration of C_HA and C_FA bound Fe did not correlate with K _f and 1/n values of pesticides.     

The effects of sinusoidal leading edge of turbine blades on the power coefficient of horizontal-axis wind turbine (HAWT)

In order to improve the aerodynamic performance of horizontal-axis wind turbine (HAWT), a sinusoidal shape is applied to turbine blade. In this study, four types of modified blades were chosen based on variations in amplitude and wavelength of protuberance along the leading edge. Compared with the baseline model, the power coefficients (C_p) of HAWT with modified blades were improved, especially at low tip speed ratios. At low wind speed (V = 6 m/s), blades with short wavelength obtain significant improvement in C_p compared with the baseline model. As wind speed increases, this improvement decreases. In addition, turbine blade with large amplitude and long wavelength obtains better C_p values at higher wind speeds than lower ones, which have a great potential to be more superior at relatively higher wind speeds.     

工业火炬气NOx排放的模拟实验

为准确核定石化企业火炬气NO_x的排放情况,采用模拟火炬燃烧装置对现场采集的不同种类火炬气进行燃烧,取得了燃烧温度及NO_x排放数据。实验结果表明：火炬气的燃烧温度及燃烧烟气中的NO_x质量浓度与火炬气组分中H₂的体积分数呈正相关;兰炭荒煤气、煤甲醇合成驰放气、合成氨变换气和合成氨合成解析气的燃烧温度分别为410,430,560,650℃。通过计算得到4种火炬气的NO_x排放系数分别为：合成氨合成解析气0.3154~0.5406kg/t,煤甲醇合成驰放气0.1245~0.2263kg/t,合成氨变换气0.0591~0.0813kg/t,兰炭荒煤气0.0801~0.1762kg/t。     

Numerical Modeling of Particulate Matter Dispersion from Kerman Cement Plant, Iran

A three dimensional diffusion model has been developed for computing the concentration of PM10 from Kerman Cement Plant, Iran. This model incorporates source-related factors, meteorological factors, surface roughness, and settling particles to estimate pollutant concentration from continuous sources. The study focused on the local environmental impact of Kerman Cement Plant. The performance of the model was found to be in good agreement with measured data; the average absolute percent deviation is 25.53%. In addition, the result of this modeling shows that the PM10 concentration in the ambient air at distances of about 600–1,400 m from the stacks is higher than the WHO guidelines of an annual average of 260 μg/m³.     

ESP粉尘二维输运方程中紊流掺混系数及边界条件的确定

求解电除尘器ESP(Electrostatic Precipitator)电场粉尘输运方程中粉尘浓度分布时,确定紊流掺混系数及边界条件至关重要.根据紊流传质原理,推导出紊流掺混系数; 通过雷诺数将电风影响引入紊流掺混系数,推导出紊流掺混系数随电晕线到极板距离的增大而增大.极板附近存在具有一定厚度的层流边层.分析层流边层中荷电粒子迁移输运行为,得到极板处粉尘浓度变化规律,这可作为求解输运方程时极板处的边界条件.用Matlab程序求解输运方程.经验证,理论计算的数值结果与试验结果一致,这表明本文所推导的紊流掺混系数和边界条件是正确的.本文使ESP收尘过程的理论研究更加深入,对提高ESP的收尘效率也具有重要意义.     

城市发展与水环境污染的研究

本文研究了城市发展与水环境污染的关系。运用灰色关联分析表明,对水污染排放的影响程度大小依次为:人口密度(γ1=0.4456)工业发展(γ3=0.3498)环保投入(γ2=0.2656)。通过弹性系数预测法分析了上海废水排放与人均GDP的发展趋势。     

基于逐月退水系数的三江源枯季径流特征分析

利用1960~2009年三江源区枯季月径流数据,分析了退水过程中月径流和退水系数的变化趋势,并利用逐月退水系数重建了枯季径流过程。结果表明:(1)黄河源区和澜沧江源区枯季月径流呈减少的趋势,长江源区呈微弱的增加趋势,枯季径流受控于夏季径流,二者保持一致的变化趋势;(2)黄河和长江源区逐月退水系数的变化趋势在整个退水期是增加的,意味着地下水退水过程减缓,这可能是长期的气候变暖导致江河源区地下水库容增加的结果,在澜沧江源区退水系数的变化没有明显的趋势;(3)可以利用多年平均退水系数和10月径流来重建冬季(11月到来年2月)月径流量,计算值与实测值误差控制在8%以内,拟合精度较高。该研究对认识气候变化背景下三江源区枯季径流特征和水文预报方面具有一定参考价值。     

旅陕入境旅游流与三大口岸相互关系研究

引入变异系数和相关性分析,结合入境游客的群体特征与时空差异,详细分析了旅陕入境旅游流与三大口岸的空间差异及关联度大小。研究表明,入陕外国人、港澳台游客流和三大口岸入境旅游流在空间分布上存在显著差异,但最终趋于稳定;旅陕不同类别、国别入境旅游者与三大口岸关联度大小迥异。