Photodegradation of acetochlor in water and UV photoproducts identified by mass spectrometry

The sunlight photodegradation half-lives of 20 mg/L acetochlor were 151, 154 and 169 days in de-ionized water, river water and paddy water, respectively. When exposed to ultraviolet (UV) light, acetochlor in aqueous solution was rapidly degraded. The half-lives were7.1, 10.1, and 11.5 min in de-ionized water, river water and paddy water, respectively. Photopreduets of acetochlor were identified by gas chromatography/mass spectrometry(GC/MS) and found at least twelve photoproducts resulted from dechlorination with subsequent hydrtrxylation and cyclization processes. The chemical structures of ten photoproducts were presumed on the basis of mass spectrum interpretation and literature data. Photoproducts are identified as 2-ethyl-6-methylaniline; N, N-diethylaniline ; 4, 8-dimethyl-2-oxo- 1,2,3,4- tetrahydroquino-line; 2-oxo-N-(2-ethyl-6-methylphenyl)-N-(ethoxymethyl) acetamide; N-(ethoxymethyl)-2‘-ethyl-6‘-methylformanilide; 1-hydroxyaeetyl-2-ethoxyl-7-ethylind ole; 8-ethyl-l-ethoxymethyl-2-oxo-1, 2, 3, 4-tetrahydroquinoline; 4, 8-dimethyl-l-ethoxymethyl-2-oxo-1, 2, 3, 4-tetrahydroquinoline; 2-hydroxy-2‘-ethyl-6‘-methyl-N-(ethoxymethyl) acetanilide and a compound related to acetochlor. The other two photoproducts were detected by GC/MS although their chemical structure was unknown.     

基于三维一体的区域可持续发展指标体系构建理论

提出了基于三维一体的区域可持续发展指标体系模型。该指标体系反映了经济、环境、社会的整个过程 ,同时包含了压力、状态、响应模型。该区域可持续发展指标体系的建立为区域可持续发展评估指标的确立提供了依据     

柴油发电机噪声治理改造工程一例

介绍一例窄小空间的大功率柴油发电机噪声改造工程。通过对原机房的改造 ,增加隔声、吸声、通风等措施 ,使发电机噪声排放达标     

生产固化剂A废水的COD_(Mn)与COD_(cr)相关性的探讨

分别用重铬酸钾法和高锰酸钾法测定了生产固化剂Ａ废水的化学需氧量ＣＯＤｃｒ和ＣＯＤＭｎ，得到了ＣＯＤｃｒ和ＣＯＤＭｎ的相关性方程，线性相关较好     

Quantitative structure activity relationships for carp kidney ATPase endpoint

ＩｎｔｒｏｄｕｃｔｉｏｎＭｏｓｔｏｆｎｉｔｒｏａｒｏｍａｔｉｃｓａｒｅｉｍｐｏｒｔａｎｔｅｎｖｉｒｏｎｍｅｎｔａｌｐｏｌｌｕｔａｎｔｓ.ＴｈｅｃａｒｐｉｓｔｈｅｍａｊｏｒｅｃｏｎｏｍｉｃｆｉｓｈｉｎＣｈｉｎａａｎｄｉｓｏｎｅｏｆｔｈｅｆｉｖｅｓｔａｎ?..     

废渣──Al(OH)_3凝胶再利用研究

研究了对处理铝材加工含Al3＋的酸性废液过程中产生的二次污染物Al（OH）3凝胶废渣的应用。含水分约90％、80％左右的Al（OH）3凝胶200g分别与14～16mL、22～24mL95％的工业浓硫酸酸反应，可制得浓度为20％～23％的Al（SO4）3溶液，经稀释可用作造纸原料。     

Origin of raised maternal serum alpha-fetoprotein levels in second-trimester oligohydramnios

Concanavalin A (Con A) subtyping of alpha-fetoprotein (AFP) revealed higher concentrations of AFP non-reactive with Con A in sera of 12 pregnant women with second-trimester oligohydramnios and raised total serum AFP levels than in sera of 42 pregnant women with raised total serum AFP levels and a normal amniotic fluid volume. This suggests that in oligohydramnios the origin of excess AFP in the maternal compartment is amniotic fluid. It is proposed that oligohydramnios and the associated raised maternal serum AFP levels are caused by damage of the fetal membranes prior to 16 weeks of gestation resulting in leakage of amniotic fluid to the decidual tissue and resorption in the maternal circulation.     

45,X/46,XY chromosome mosaicism detected by midtrimester amniocentesis in amniocyte clones

Amniocyte clones from a mid-trimester pregnancy disclosed 45,X/46,XY sex chromosome mosaicism. Because of the uncertainty concerning the phenotype of the fetus, the parents elected to terminate the pregnancy. Mixed (asymmetrical) gonadal dysgenesis was not found. The fetus appeared to have a normal male uro-genital system. No malformations of any type were detected, although as expected, the fetus did have 45,X/46,XY mosaicism.     

MFC在UG二次开发CAD系统中的应用

针对UG开发中的困难,目前还没有在UG/OPENAPI中调用MicrosoftFundamentClass(MFC)的方法,着重介绍了如何应用MFC开发UG的方法以及辅助开发模块UG/Open MenuScript的使用。并用一个完整的例子来说明如何利用UG/OPENAPI,MFC,及MenuScript进行联合开发CAD系统。     

垃圾焚烧中PCDD/Fs的检测

ＰＣＤＤ／Ｆｓ的产生和排放是人们所关注的问题，垃圾焚烧是ＰＣＤＤ／Ｆｓ的一个重要来源。从其生成的反应机理看，ＰＣＤＤ／Ｆｓ主要是由于垃夫中存在氯源和不完全燃烧产生的。对垃圾焚烧后的烟气中的ＰＣＤＤ／Ｆｓ进行检验具有现实的意义。从国内外的分析方法及分析设备的现状比较，建议引起有关部门的足够重视，广泛开发检测工作，以保障人民的生活健康。