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81.
This paper deals with the incident of the excessive use of chlorine and leakage of unused chlorine from an industrial chlorination
cistern and the lesson learned. 相似文献
82.
用二氧化氯降解废水中的苯胺类化合物(1)COD去除规律的研究 总被引:3,自引:0,他引:3
用二氧化氯氧化降解8种苯胺类化合物,测定了COD去除率与时间及COD去除率与ClO2用量之间的关系;结果表明最终的COD去除率多数都在70%以上,羟基类苯胺化合物可达90%以上.反应符合lnCOD=K1WClO2+A1及lnCODt=K2t+A关系式.COD去除率还与pH值的大小有一定的相关性. 相似文献
83.
二氧化氯的稳定性研究 总被引:4,自引:0,他引:4
分别讨论了在一定条件下,通常意义的二氧化氯水溶液与稳定的二氧化氯水溶液的降解速率,同时,研究了pH值对二氧化氯水溶液稳定性的影响. 相似文献
84.
To solve the problem of shortened backwashing intervals in groundwater plants, several disinfectants including ozone (O3), hydrogen peroxide (H2O2) and chlorine dioxide (ClO2) were examined to peel off the film from the quartz sand surface in four pilot-scale columns. An optimized oxidant dosage and oxidation time were determined by batch tests. Subsequently, the optimized conditions were tested in the four pilot-scale columns. The results demonstrated that the backwashing intervals increased from 35.17 to 54.33 (H2O2) and to 53.67 hr (ClO2) after the oxidation treatments, and the increase of backwashing interval after treatment by O3 was much less than for the other two treatments. Interestingly, the treatment efficiency of filters was not affected by O3 or H2O2 oxidation; but after oxidation by ClO2, the treatment efficiency was deteriorated, especially the ammonia removal (from 96.96% to 24.95%). The filter sands before and after the oxidation were characterized by scanning electron microscopy and X-ray photoelectron spectroscopy. Compared with the oxidation by O3 and H2O2, the structures on the surface of filter sands were seriously damaged after oxidation by ClO2. The chemical states of manganese on the surfaces of those treated sands were only changed by ClO2. The damage of the structures and the change of the chemical states of manganese might have a negative effect on the ammonia removal. In summary, H2O2 is a suitable agent for film peeling. 相似文献
85.
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87.
Assessment of water pollution in different bleaching based paper manufacturing and textile dyeing industries in India 总被引:3,自引:0,他引:3
Paper industries using different raw materials such as hard wood, bamboo, baggase, rice-straw and waste papers and bleaching
chemicals like chlorine, hypochlorite, chlorine dioxide, hydrogen peroxide, sulphite and oxygen were studied to estimate organic
pollution load and Adsorbable Organic Halides (AOX) per ton of production. The hard wood based paper industries generate higher
Chemical Oxygen Demand (COD) loads (105–182 kg t−1) and Biochemical Oxygen Demand (BOD) loads (32.0–72 kg t−1) compared to the agro and waste paper based industrial effluents. The bleaching sequences such as C–EP–H–H, C–E–H–H, C–E–Do–D1
and O–Do–EOP–D1 are adopted in the paper industries and the molecular elemental chlorine free bleaching sequence discharges
low AOX in the effluent. The range of AOX concentration in the final effluent from the paper industries was 0.08–0.99 kg t−1 of production. Water consumption was in the range of 100–130 m3 t−1 of paper production for wood based industries and 30–50 m3 for the waste paper based industries. Paper machine effluents are partially recycled after treatment and pulp mill black
liquor are subject to chemical recovery after evaporation to reduce the water consumption and the total pollution loads. Hypochlorite
bleaching units of textile bleaching processes generate more AOX (17.2–18.3 mg l−1) and are consuming more water (45–80 l kg−1) whereas alkali peroxide bleaching hardly generates the AOX in the effluents and water consumption was also comparatively
less (40 l kg−1 of yarn/cloth). 相似文献
88.
Farooq S Hashmi I Qazi IA Qaiser S Rasheed S 《Environmental monitoring and assessment》2008,140(1-3):339-347
The present study was undertaken to examine the drinking water quality of Rawal Treatment Plant, Rawalpindi and its distribution
network by collecting samples from eight different locations. The aim was to determine potential relationship between the
presence of microorganisms and chlorine residual in the distribution network. Quantification of chlorine residual, turbidity,
standard plate count (SPC), fecal and total coliforms by Most Probable Number (MPN) was performed. Three different forms of chlorine were measured at each sampling station such
as free chlorine, residual chlorine, chloramines and total chlorine residual. A critical evaluation of data presented indicated
that pH generally ranged from 7.02–7.30; turbidity varied from 0.34–2.79 NTU; conductivity fluctuated from 359–374 μS/cm;
and TDS values were found to be ranging between 180–187 mg/l. Station # 7 was found to be most contaminated. The value of total chlorine was found to be 0.86 to1.7 mg/l at Station # 3 and 6, respectively. Highest standard plate count was 62 CFU/ml at Station # 7. Total
coliforms were less than 1.1 MPN/100 ml at almost most of the stations except at Station # 3 where it was found to be greater than 23.0 MPN /100 ml. Overall aim of this study is to create awareness about contamination
of drinking water in the water distribution networks and to make recommendations to provincial agencies such as EPA, CDA and
WASA that regular monitoring should be carried out to ensure that the chlorine residual is available at consumer end. 相似文献
89.
R. Paul Philp 《Environmental Chemistry Letters》2007,5(2):57-66
In the past decade, environmental forensics has emerged as a discipline directed toward determining parties liable for causing spills of contaminants into the environment. Such investigations, while geared toward determining the guilty parties in order to recover costs of the cleanup and remediation, require various questions to be addressed. These include determination of the nature of the product; Where did it come from?; Extent of weathering, if any; How long has it been there?; and Is it degrading naturally? Traditionally, these studies have been addressed through utilization of techniques such as gas chromatography (GC) and gas chromatography–mass spectrometry (GCMS). However, in recent years, stable isotopes, primarily determined through the use of combined gas chromatography–isotope ratio mass spectrometry (GCIRMS), have emerged as an equally important tool in environmental forensics. For relatively low molecular, volatile compounds such as MTBE, BTEX, or chlorinated solvents, the isotopes, primarily carbon and hydrogen, have been used extensively for evaluating the onset of natural attenuation. For larger molecules such as PCBs or PAHs, in which the effects of biodegradation on the isotope composition of these molecules is minimal, the isotopic fingerprints of the individual compounds can be used for correlation purposes. In this paper, a brief introduction to isotope geochemistry will be given, followed by a review of applications of stable isotopes to a variety of environmental problems. While the review may not necessarily be exhaustive, it will provide a comprehensive overview of areas where isotopes have been used and potential applications for the future. Most of the review is concerned with carbon and hydrogen isotopes, although a brief overview of the emerging area of chlorine isotopes will also be discussed. 相似文献
90.