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941.
建立了一种直接进样-气相色谱质谱法同时分离和测定固定污染源排气中三氟甲烷、四氟甲烷、六氟乙烷和六氟化硫等含氟温室气体的方法。使用CP-Sillica PLOT毛细管填充柱可使上述4种目标化合物实现基线分离。分别用全扫描模式和选择离子扫描模式进行定量分析,方法检出限分别为0.12,0.19,0.10,0.08 mg/m~3和2.8,3.4,1.7,3.1μg/m~3。探讨了样品保存容器与保存时间对样品浓度衰减的影响,指出Tedlar采样袋或铝塑复合膜采样袋可以较长时间保存样品,在常温下,样品可保存至少7 d。实际样品测定结果表明方法快速、简便,适用于固定污染源排气中含氟温室气体的测定。 相似文献
942.
943.
944.
水中的VOCs经吹扫富集、解吸后,用HP-VOC色谱柱分离,采用全扫描和选择离子监测模式分析,内标法定量。最佳富集条件为:吹扫流速为40 m L/min,吹扫温度为40℃,吹扫时间为15 min,解吸温度为200℃,解吸时间为2 min。该法27种VOCs在一定的质量浓度范围内与其峰面积呈线性关系,相关系数r0.995,检出限为0.02~1.18μg/L。以空白样品为基体进行加标回收试验,测得回收率为79.8%~114%,相对标准偏差为0.3%~12%。 相似文献
945.
快速固相萃取法测定食品中多种有机磷农药残留 总被引:5,自引:0,他引:5
报道了一种简便、快速的石墨碳固相萃取(SPE)食品中多种有机磷农药残留及测定的方法.采用丙酮浸泡、超声提取食品中的有机磷农药,经石墨碳固相小柱净化萃取后,用气相色谱-火焰光度检测法直接测定,加标回收率在72.0%~107%之间,RSD为6.2%~12.7%,最低检出限可达0.001 mg/kg. 相似文献
946.
Intercalated montmorillonite clays with different amounts of organic hexadecyltrimethylammonium (HDTMA) cations were studied to analyse their CO, CH(4), and SO(2) gas retentions. Equilibrium adsorption was measured by using a standard volumetric apparatus at 25 degrees C and 0.1 MPa. The solids were characterised by X-ray diffraction. The levels of adsorption of SO(2) by organo-montmorillonites (0.3595-1.6403 mmol/g) were higher than those of CO (up to 0.0202 mmol/g) and CH(4) (up to 0.0273 mmol/g) gases. HDTMA montmorillonites may be effective adsorbents for removing SO(2) and for its potential separation in the presence of CO and/or CH(4) molecules, which can be present in contaminated air. 相似文献
947.
Old-growth forests have declined significantly across the world. Decisions related to old growth are often mired in challenges
of value diversity, conflict, data gaps, and resource pressures. This article describes old-growth values of citizens and
groups in Nova Scotia, Canada, for integration in sustainable forest management (SFM) decision-making. The study is based
on data from 76 research subjects who participated in nine field trips to forest stands. Research subjects were drawn from
Aboriginal groups, environmental organizations, forestry professionals, and rural and urban publics. Diaries, group discussions,
and rating sheets were used to elicit information during the field trips. Findings show that different elicitation techniques
can influence the articulation of intensity with which some values are held. In addition, certain values are more often associated
with old-growth than with other forest-age classes. Some values associated with old-growth are considered more important than
others, and some silvicultural treatments are perceived to compromise old-growth values more than others. Demographic characteristics,
such as constituency group, gender, and age, are shown to influence value priorities. Ideas on how to incorporate old-growth
values into SFM decision-making are highlighted. 相似文献
948.
The importance of riparian vegetation to support stream function and provide riparian bird habitat in semiarid landscapes
suggests that standardized assessment tools that include vegetation criteria to evaluate stream health could also be used
to assess habitat conditions for riparian-dependent birds. We first evaluated the ability of two visual assessments of woody
vegetation in the riparian zone (corridor width and height) to describe variation in the obligate riparian bird ensemble along
19 streams in eastern Oregon. Overall species richness and the abundances of three species all correlated significantly with
both, but width was more important than height. We then examined the utility of the riparian zone criteria in three standardized
and commonly used rapid visual riparian assessment protocols—the USDI BLM Proper Functioning Condition (PFC) assessment, the
USDA NRCS Stream Visual Assessment Protocol (SVAP), and the U.S. EPA Habitat Assessment Field Data Sheet (HAFDS)—to assess
potential riparian bird habitat. Based on the degree of correlation of bird species richness with assessment ratings, we found
that PFC does not assess obligate riparian bird habitat condition, SVAP provides a coarse estimate, and HAFDS provides the
best assessment. We recommend quantitative measures of woody vegetation for all assessments and that all protocols incorporate
woody vegetation height. Given that rapid assessments may be the only source of information for thousands of kilometers of
streams in the western United States, incorporating simple vegetation measurements is a critical step in evaluating the status
of riparian bird habitat and provides a tool for tracking changes in vegetation condition resulting from management decisions. 相似文献
949.
950.
The partitioning of non-aqueous phase liquid (NAPL) compounds to a discontinuous gas phase results in the repeated spontaneous expansion, snap-off, and vertical mobilization of the gas phase. This mechanism has the potential to significantly affect the mass transfer processes that control the dissolution of NAPL pools by increasing the vertical transport of NAPL mass and increasing the total mass transfer rate from the surface of the pool. The extent to which this mechanism affects mass transfer from a NAPL pool depends on the rate of expansion and the mass of NAPL compound in the gas phase. This study used well-controlled bench-scale experiments under no-flow conditions to quantify for the first time the expansion of a discontinuous gas phase in the presence of NAPL. Air bubbles placed in glass vials containing NAPL increased significantly in volume, from a radius of 1.0 mm to 2.0 mm over 215 days in the presence of tetrachloroethene (PCE), and from a radius of 1.2 mm to 2.3 mm over 22 days in the presence of trans-1,2-dichloroethene (tDCE). A one-dimensional mass transfer model, fit to the experimental data, showed that this expansion could result in a mass flux from the NAPL pool that was similar in magnitude to the mass flux expected for the dissolution of a NAPL pool in a two-fluid (NAPL and water) system. Conditions favouring the significant effect of a discontinuous gas phase on mass transfer were identified as groundwater velocities less than ~0.01 m/day, and a gas phase that covers greater than ~10% of the pool surface area and is located within ~0.01 m of the pool surface. Under these conditions the mass transfer via a discontinuous gas phase is expected to affect, for example, efforts to locate NAPL source zones using aqueous concentration data, and predict the lifetime and risk associated with NAPL source zones in a way that is not currently included in the common conceptual models used to assess NAPL-contaminated sites. 相似文献