全文获取类型
收费全文 | 151篇 |
免费 | 0篇 |
国内免费 | 12篇 |
专业分类
安全科学 | 4篇 |
废物处理 | 5篇 |
环保管理 | 14篇 |
综合类 | 66篇 |
基础理论 | 26篇 |
污染及防治 | 33篇 |
评价与监测 | 15篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2015年 | 4篇 |
2014年 | 3篇 |
2013年 | 14篇 |
2012年 | 5篇 |
2011年 | 8篇 |
2010年 | 4篇 |
2009年 | 10篇 |
2008年 | 12篇 |
2007年 | 6篇 |
2006年 | 9篇 |
2005年 | 5篇 |
2004年 | 7篇 |
2003年 | 4篇 |
2002年 | 9篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有163条查询结果,搜索用时 31 毫秒
21.
This study evaluated the potential toxicological risk posed to human health due to the exposure to heavy metals by water ingestion
in an area affected by tanneries – the Cadeia-Feitoria hydrographic basin (Brazil). River water was collected at 10 sites,
every 3 months, from July 1999 to April 2000. After acid digestion, total metal concentration was determined by inductively
coupled plasma optical emission spectrometry (Cd, Cu, Cr, Ni, Zn), flame atomic absorption (Al, Fe, Pb, Mn), or cold vapor
atomic absorption spectrometry (Hg). Cr(VI) was complexed with diphenyl-carbazide and detected by UV–vis spectrometry. In
order to quantify the risk of exposure, the risk assessment methodology employed by the Environmental Protection Agency of
the United States was applied at a screening level. The assumed scenarios included extreme exposure patterns (ingestion of
untreated water, conversion of Cr(III) to Cr(VI), temporal peaks of pollution). Fe, Al, Cd, Hg, and Pb were not included in
the risk analysis, since they showed a low toxicity potential or were undetected in the samples. The selected metals presented
Hazard Quotients < 1, in the following order of increasing risk: Cu < Cr(III) < Zn < Ni < Mn < Cr(VI). Hazard indexes, representing
the additive effect of contaminants, were also low in the basin (< 1), but comparatively increased in the lower reach of Feitoria
and Cadeia Rivers. Although noncarcinogenic risk levels did not suggest possible adverse toxicological effects to the human
population, a considerable deviation from background conditions was observed downstream the area where tanneries are mainly
located. 相似文献
22.
Marc?Le Lann Catherine?ElleouetEmail author Fran?ois?Quentel Christian?Louis?Madec 《Environmental Chemistry Letters》2003,1(1):98-102
Cathodic adsorptive stripping voltammetry is one of the most sensitive analytical methods for ultratrace analysis. The detection
limit is usually lower than 10−9 mol/L. Most adsorptive stripping procedures have been focused on the one ligand/one analyte approach. In order to reduce
analysis time and sample volume, the possibility of simultaneously determining several metals by cathodic stripping voltammetry
using a mixture of ligands was explored, e.g., by Colombo and van den Berg (1997). Here, we describe a new procedure for quantifying
chromium and copper using 2,2′-bipyridine and 8-hydroxyquinoline (oxine). The effect of various operational parameters such
as buffer type, ligand concentration, potential and time collection were assessed and optimized. Possible interferences by
trace metals and organic matter were also investigated. Applicability for fresh water is illustrated.
Electronic Publication 相似文献
23.
24.
25.
以浸出毒性、表面浸出率、抗日晒能力和抗压强度为指标考察了纤维改性硫酸亚铁还原铬渣水泥固化体的性能。实验结果表明:纤维改性硫酸亚铁还原铬渣水泥固化体养护7d和28d后的浸出毒性均低于国家标准、抗压强度均大于10MPa,可以做最终处置或进行综合利用;与普通铬渣水泥固化体相比,纤维改性硫酸亚铁还原铬渣水泥固化体在加入植物纤维为0.8g时的处理效果最好,浸出毒性、表面浸出率分别降低了76.I%和76.8%;抗日晒能力、抗压强度分别提高了36.4%和52.1%。 相似文献
26.
27.
以铬渣污染土壤为供试土壤,采用土柱淋洗法研究柠檬酸、草酸和盐酸单一淋洗以及复合淋洗对铬去除动态和修复效果的影响,并对淋洗前后土壤中铬形态进行分析,探讨修复机理。结果表明,各淋洗方案中,以10体积0.5 mol/L草酸溶液为淋洗剂时的修复效果最好,总Cr累计淋出量为2 304 mg/kg,上层、中层和下层土壤总Cr去除率分别为79.6%、78.1%和69.6%,Cr(VI)去除率为87.8%、86.2%和75%,且土壤Cr(VI)和总Cr随着土壤深度的增加而升高,有在底部积累的可能;淋洗后土壤明显酸化,p H值从10.5降至3左右;以酸作为淋洗剂能有效降低土壤可氧化态铬含量,将其转化为移动性较强的酸可提取态,这有助于达到预期修复效果。 相似文献
28.
Fanling Meng Yunxue Xia Jianshuai Zhang Dong Qiu Yaozhu Chu Yuanyuan Tang 《Frontiers of Environmental Science & Engineering》2021,15(6):116
29.
Chromate uptake, reduction, cytotoxicity and mutagenicity were studied with human red blood cells, Chinese hamster ovary (CHO) cells and/or Salmonella typhimurium mutant cells. All cell types rapidly took up chromates whereas chromium(III) salts were excluded under the experimental conditions. Red blood cells reduced and accumulated chromium from chromate. At concentrations above 0.1 mM, chromate inactivated the red cell chromate carrier. Chromate above 0.01 mM inhibited CHO cell proliferation irrespective of the cations present. Chromate and two chromium(III) complexes were mutagenic with Salmonella mutants in the Ames’ assay. A model for chromate metabolism and genotoxicity is proposed. 相似文献
30.
Bryan Butter Paola Santander Guadalupe del C. Pizarro Diego P. Oyarzún Federico Tasc Julio Sánchez 《环境科学学报(英文版)》2021,33(3):304-312
Chromium (Cr) is used in many manufacturing processes, and its release into natural waters is a major environmental problem today. Low concentrations of Cr(VI) are toxic to human health and living organisms due to the carcinogenic and mutagenic nature of this mineral. This work examined the conversion of Cr(VI) to Cr(III) via electrochemical reduction using gold electrode in an acidic sodium alginate (SA) solution and subsequent removal of the produced Cr(III)-SA by the polymer-enhanced ultrafiltration (PEUF) technique. A solution of SA in nitric acid was used both as an electrolytic medium during the voltammetric measurements and bulk electrolysis and as an extracting agent during the PEUF technique. The electroanalysis of Cr(VI) was performed by linear sweep voltammetry in the presence of acidic SA solution to study its voltammetric behavior as a function of the Cr(VI) concentration, pH, presence of Cr(III), SA concentration and scan rate. In addition, the quantitative reduction of Cr(VI) to Cr(III) was studied through the bulk electrolysis technique.The results showed efficient reduction with well-defined peaks at approximately 0.3 V vs. Ag/AgCl, using a gold working electrode. As the pH increased, the reduction signal strongly decreased until its disappearance. The optimum SA concentration was 10 mmol/L, and it was observed that the presence of Cr(III) did not interfere in the Cr(VI) electroanalysis. Through the quantitative reduction by bulk electrolysis in the presence of acidic SA solution, it was possible to reduce all Cr(VI) to Cr(III) followed by its removal via PEUF. 相似文献